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Lamellar or smectic phases often have an intricate intralamellar structure that remains scarcely understood from a microscopic viewpoint. In this work, we use molecular dynamics simulations to study the effect of volume exclusion and…

Soft Condensed Matter · Physics 2025-01-22 Jaydeep Mandal , Henricus H. Wensink , Prabal K. Maiti

The dynamics of active smectic liquid crystals confined on a spherical surface is explored through an active phase field crystal model. Starting from an initially randomly perturbed isotropic phase, several types of topological defects are…

Soft Condensed Matter · Physics 2025-03-11 Michael Nestler , Simon Praetorius , Zhi-Feng Huang , Hartmut Löwen , Axel Voigt

In equilibrium hard-rod fluids, and in effective hard-rod descriptions of anisotropic soft-particle systems, the transition from the isotropic (I) phase to the nematic phase (N) is observed above the rod aspect ratio L/D = 3.70 as predicted…

Soft Condensed Matter · Physics 2023-02-22 Jayeeta Chattopadhyay , Sriram Ramaswamy , Chandan Dasgupta , Prabal K. Maiti

We report on a comprehensive computer simulation study of the liquid-crystal phase behaviour of purely repulsive, semi-flexible rod-like particles. For the four aspect ratios we consider, the particles form five distinct phases depending on…

Soft Condensed Matter · Physics 2018-01-17 Bart de Braaf , Mariana Oshima Menegon , Stefan Paquay , Paul van der Schoot

Using agent-based simulations of self-propelled particles subject to short-range repulsion and nematic alignment we explore the dynamical phases of a dense active material confined to the surface of a sphere. We map the dynamical phase…

Soft Condensed Matter · Physics 2018-04-25 Silke Henkes , M. Cristina Marchetti , Rastko Sknepnek

By employing Molecular Dynamics computer simulations, the phase behavior of systems of rodlike particles with varying degree of internal flexibility has been traced from the perfectly rigid rod limit till very flexible particles, and from…

Soft Condensed Matter · Physics 2009-11-13 Giorgio Cinacchi , Luca De Gaetani

We numerically investigate two-dimensional systems of hard rectangles at constant pressure through extensive hard-particle Monte Carlo simulations. We determine the complete phase diagram as a function of packing fraction and aspect ratio,…

Soft Condensed Matter · Physics 2025-05-15 Denis Dertli , Thomas Speck

We study the organization of topological defects in a system of nematogens confined to the two-dimensional sphere (S^2). We first perform Monte Carlo simulations of a fluid system of hard rods (spherocylinders) living in the tangent plane…

Soft Condensed Matter · Physics 2009-11-13 Homin Shin , Mark J. Bowick , Xiangjun Xing

In this article we consider systems of parallel hard {\it superellipsoids}, which can be viewed as a possible interpolation between ellipsoids of revolution and cylinders. Superellipsoids are characterized by an aspect ratio and an exponent…

Soft Condensed Matter · Physics 2009-11-13 Yuri Martinez-Raton , Enrique Velasco

We have studied, using molecular dynamics simulations, the pressure-induced melting in a monolayer of soft repulsive spherocylinders whose centers of mass are constrained to move on the surface of a sphere. We show that the orientational…

Soft Condensed Matter · Physics 2025-03-13 Jaydeep Mandal , Chandan Dasgupta , Prabal K. Maiti

We present the phase diagram of a system of mesogenic top-shaped molecules based on the Parsons- Lee density functional theory and Monte Carlo simulation. The molecules are modeled as a hard spherocylinder with a hard sphere embedded in its…

Soft Condensed Matter · Physics 2011-06-13 D. de las Heras , S. Varga , F. J. Vesely

A nematic liquid crystal confined to the surface of a sphere exhibits topological defects of total charge $+2$ due to the topological constraint. In equilibrium, the nematic field forms four $+1/2$ defects, located at the corners of a…

Soft Condensed Matter · Physics 2020-07-22 Yi-Heng Zhang , Markus Deserno , Zhan-Chun Tu

Within the framework of Landau-de Gennes theory for nematic liquid crystals, we study the temperature-induced isotropic-nematic phase transition on a spherical shell. Below a critical temperature, a thin layer of nematic coating a…

Soft Condensed Matter · Physics 2021-08-11 Gaetano Napoli , Luigi Vergori

We investigate the phase behaviour of a two-dimensional colloidal model system of ultra-soft particles on a substrate which varies periodically along one spatial direction. Our calculations are based on mean-field density functional theory…

Soft Condensed Matter · Physics 2021-03-17 Alexander Kraft , Sabine H. L. Klapp

The surface phase behavior of binary mixtures of colloidal hard rods in contact with a solid substrate (hard wall) is studied, with special emphasis on the region of the phase diagram that includes the smectic A phase. The colloidal rods…

Soft Condensed Matter · Physics 2010-12-17 Daniel de las Heras , Yuri Martínez-Ratón , Enrique Velasco

Semiflexible polymers in concentrated lyotropic solution are studied within a bead-spring model by molecular dynamics simulations, focusing on the emergence of a smectic A phase and its properties. We systematically vary the density of the…

Soft Condensed Matter · Physics 2019-01-28 Andrey Milchev , Arash Nikoubashman , Kurt Binder

Recently, a new class of smectic liquid crystal phases (SmCP phases) characterized by the spontaneous formation of macroscopic chiral domains from achiral bent-core molecules has been discovered. We have carried out Monte Carlo simulations…

Statistical Mechanics · Physics 2009-11-07 Yves Lansac , Prabal K. Maiti , Noel A. Clark , Matthew A. Glaser

A coupled phase-field and hydrodynamic model is introduced to describe a two-phase, weakly compressible smectic (layered phase) in contact with an isotropic fluid of different density. A non-conserved smectic order parameter is coupled to a…

Soft Condensed Matter · Physics 2022-02-02 Eduardo Vitral , Perry H. Leo , Jorge Viñals

Using computer simulations we investigate the microscopic structure of the singular director field within a nematic droplet. As a theoretical model for nematic liquid crystals we take hard spherocylinders. To induce an overall topological…

Soft Condensed Matter · Physics 2009-10-31 J. Dzubiella , M. Schmidt , H. Loewen

We study the phase behaviour of cholesteric liquid crystal shells with different geometries. We compare the cases of tangential and no anchoring at the surface, focussing on the former case, which leads to a competition between the…

Soft Condensed Matter · Physics 2023-03-01 Giuseppe Negro , Livio Nicola Carenza , Giuseppe Gonnella , Davide Marenduzzo , Enzo Orlandini
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