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X-ray absorption spectroscopy measurements in Pr0.5Ca0.5CoO3 were performed at the Pr M4,5, Pr L3, and Ca L2,3 absorption edges as a function of temperature below 300 K. Ca spectra show no changes down to 10 K while a noticeable thermally…

High-pressure can transform the structures and compositions of materials either by changing the relative strengths of bonds or by altering the oxidation states of atoms. Both effects cause unconventional compositions in novel compounds that…

The electronic structure of (group-III) metal-monochalcogenide monolayers exhibits many unusual features. Some, such as the unusually distorted upper valence band dispersion we describe as a 'caldera', are primarily the result of purely…

Materials Science · Physics 2015-11-20 Pengke Li , Ian Appelbaum

The dielectric behavior of the single crystals of the spin-chain system Ca3Co2O6, undergoing geometrically frustrated antiferromagnetic ordering below 25 K, has been investigated as a function of temperature and magnetic field (H) and…

Materials Science · Physics 2016-03-17 Tathamay Basu , Kartik K. Iyer , P. L. Paulose , E. V. Sampathkumaran

Our previous studies [J. Phys. B 53, 125101 (2020); Euro. Phys. J. D 74, 191 (2020)] have predicted that the atom-fullerene hybrid photoionization properties for X = Cl, Br and I endohedrally confined in C60 are different before and after…

Atomic and Molecular Clusters · Physics 2022-03-14 Esam Ali , Taylor O'Brien , Andrew Dennis , Mohamed El-Amine Madjet , Steven T. Manson , Himadri S. Chakraborty

Cerium-based ternary compounds CeNi$_2$Cd$_{20}$ and CePd$_2$Cd$_{20}$ do not exhibit long-range order down to millikelvin temperature range. Given the large separation between cerium ions which significantly reduces the superexchange…

Superconductivity · Physics 2023-08-15 Suman Raj Panday , Maxim Dzero

We present a comprehensive study of electron collisions with calcium atoms by using the convergent \emph{B}-spline \emph{R}-matrix method. Elastic, excitation, and ionization cross sections were obtained for all transitions between the…

Atomic Physics · Physics 2019-01-16 Oleg Zatsarinny , Henry Parker , Klaus Bartschat

We have studied properties of the one-3d-electron cation (Ti 3+, V 4+ ions) under the action of the low-symmetry crystal field in the presence of the spin- orbit coupling. Very anomalous temperature dependences of the magnetic…

Strongly Correlated Electrons · Physics 2008-10-08 Z. Ropka , Michalski , R. J. Radwanski

With the advent of optical clocks featuring fractional frequency uncertainties on the order of $10^{-17}$ and below, new applications such as chronometric levelling with few-cm height resolution emerge. We are developing a transportable…

We report a first-principles study of hydrogen storage media consisting of calcium atoms and graphene-based nanostructures. We find that Ca atoms prefer to be individually adsorbed on the zigzag edge of graphene with a Ca-Ca distance of 10…

Materials Science · Physics 2010-02-09 Hoonkyung Lee , Jisoon Ihm , Marvin L. Cohen , Steven G. Louie

We report a single-ion optical clock based on the 4S_1/2-3D_5/2 transition of the 40Ca+ ion, operated in a liquid nitrogen cryogenic environment,achieving a total systematic uncertainty of 4.4E-19. We employ a refined temperature evaluation…

The structural, electronic, and optical properties of twelve multicomponent oxides with layered structure, RAMO$_4$, where R$^{3+}$=In or Sc; A$^{3+}$=Al or Ga; and M$^{2+}$=Ca, Cd, Mg, or Zn, are investigated using first-principles density…

Materials Science · Physics 2015-06-03 A. Murat , J. E. Medvedeva

Data from recent laser-shock experiments, density-functional theory (DFT) with molecular-dynamics (MD), and path-integral Monte Carlo (PIMC) simulations on carbon are compared with predictions from the neutral-pseudo-atom (NPA)+…

Statistical Mechanics · Physics 2017-05-30 M. W. C. Dharma-wardana

We formulate a multi-physics model to describe the nonlinear propagation of a femtosecond, near-infrared, tightly focused laser pulse in a transparent dielectric. The application of our model to the case of bulk sapphire shows that even…

Optics · Physics 2023-07-11 Anton Rudenko , Jerome V. Moloney , Pavel Polynkin

The formation of $^{40}$Ca$_2^+$ molecular ions is observed in a hybrid $^{40}$Ca magneto-optical and ion trap system. The molecular ion formation process is determined to be two-photon photo-associative ionization of ultracold $^{40}$Ca…

Though several theoretical models have been proposed to design electronic flat-bands, the definite experimental realization in two-dimensional atomic crystal is still lacking. Here we propose a novel and realistic flat-band model based on…

Materials Science · Physics 2021-02-04 Jiang Zeng , Ming Lu , Haiwen Liu , Hua Jiang , X. C. Xie

A theory is presented which quantitatively accounts for the cooperative adsorption of cationic surfactants to anionic polyelectrolytes. For high salt concentration we find that the critical adsorption concentration (CAC) is a bilinear…

Soft Condensed Matter · Physics 2009-11-13 Paulo S. Kuhn , Yan Levin , Marcia C. Barbosa , Ana Paula Ravazzolo

In this study, the structural, electronic and vibrational properties of thinnest possible Cadmium crystal are investigated by performing first-principle calculations. Total energy optimization and dynamic stability calculations reveal that…

Materials Science · Physics 2024-01-25 Arda Gulucu , Hasan Sahin

The phase behavior of ionic fluids on simple cubic and tetragonal (anisotropic) lattices has been studied by grand canonical Monte Carlo simulations. Systems with both the true lattice Coulombic potential and continuous-space $1/r$…

Statistical Mechanics · Physics 2016-08-31 Vladimir Kobelev , Anatoly B. Kolomeisky , Athanassios Z. Panagiotopoulos

Motivated by recent interest in low dimensional arrays of atoms, we experimentally investigated the way cold collisional processes are affected by the geometry of the considered atomic sample. More specifically, we studied the case of…