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It is known that solid-state reaction in high-pressure oxygen can stabilize high-oxidation phases of Y-Ba-Cu-O superconductors in powder form. We extend this superoxygenation concept of synthesis to thin films which, due to their large…

Superconductivity · Physics 2018-04-04 H. Zhang , N. Gauquelin , C. McMahon , D. G. Hawthorn , G. A. Botton , J. Y. T. Wei

The interaction of atomic orbitals at the interface of perovskite oxide heterostructures has been investigated for its profound impact on the band structures and electronic properties, giving rise to unique electronic states and a variety…

We report the first combined study of the low-energy electronic band structure of epitaxial Sr$_3$Ru$_2$O$_7$ films using angle-resolved photoemission spectroscopy and density functional theory. The complete Fermi-surface topography of the…

Transition metal oxide heterostructures and interfaces host a variety of exciting quantum phases and can be grown with atomic-scale precision by utilising the intensity oscillations of $in$ $situ$ reflection high-energy electron diffraction…

Materials Science · Physics 2017-08-02 T. W. Zhang , Z. W. Mao , Z. B. Gu , Y. F. Nie , X. Q. Pan

The presence of oxygen vacancy, as well as ordering of vacancies plays an important role in determining the electronic, ionic and thermal transport properties of many transition metal oxide materials. Controlling the concentration of oxygen…

Mesoscale and Nanoscale Physics · Physics 2018-12-05 Xue Rui , Robert Klie

Nanoscale electrostatic control of oxide interfaces enables physical phenomena and exotic functionalities beyond the realm of the bulk material. In technologically-relevant ferroelectric thin films, the interface-mediated polarization…

A uniform one-unit-cell-high step on the SrTiO3 substrate is a prerequisite for growing high-quality epitaxial oxide heterostructures. However, it is inevitable that defects induced by mixed substrate surface termination exist at the…

Reversible topotactic transitions between oxygen-vacancy-ordered structures in transition metal oxides provide a promising strategy for active manipulation of material properties. While transformations between various oxygen-deficient…

Materials Science · Physics 2020-05-06 Sampo Inkinen , Lide Yao , Sebastiaan van Dijken

Artificial PbTiO$_{3}$/SrTiO$_{3}$ superlattices were constructed using off-axis RF magnetron sputtering. X-ray diffraction and piezoelectric atomic force microscopy were used to study the evolution of the ferroelectric polarization as the…

Materials Science · Physics 2009-11-11 M. Dawber , C. Lichtensteiger , M. Cantoni , M. Veithen , P. Ghosez , K. Johnston , K. M. Rabe , J. -M. Triscone

We show that a ferromagnetic (FM) order in the orthorhombic CaRuO3, which is a non-magnetic and iso-structural analog of FM system SrRuO3, can be established and stabilized by the means of tensile epitaxial strain. Investigations on the…

Materials Science · Physics 2013-01-15 Shivendra Tripathi , Rakesh Rana , Parul Pandey , R. S. Singh , D. S. Rana

We highlight recent advances in the theory, materials fabrication, and experimental characterization of strongly correlated and topological states in [111] oriented transition metal oxide thin films and heterostructures, which are…

Strongly Correlated Electrons · Physics 2020-05-19 Jak Chakhalian , Xiaoran Liu , Gregory A. Fiete

Layered oxides have been intensively studied due to their high degree of freedom in designing various electromagnetic properties and functionalities. While Bi-based layered supercell (LSC) compounds [Bi$_n$O$_{n+\delta}$]-[$M$O$_2$] ($M$ =…

Materials Science · Physics 2024-03-15 M. Ohno , T. C. Fujita , Y. Masutake , H. Kumigashira , M. Kawasaki

In orthorhombic perovskite oxides (RMO$_3$), substituting R$^{3+}$ rare-earth cations tailors the spin, orbital, and charge degrees of freedom of the central M$^{3+}$ transition metal cations through lattice distortions. In turn, these…

Ultra-thin oxide (UTO) films were grown on Si(111) in ultrahigh vacuum at room temperature and characterized by scanning tunneling microscopy. The ultra-thin oxide films were then used as substrates for room temperature growth of pentacene.…

Materials Science · Physics 2015-05-13 B. R. Conrad , W. G. Cullen , B. C. Riddick , E. D. Williams

We describe a novel approach for the rational design and synthesis of self-assembled periodic nanostructures using martensitic phase transformations. We demonstrate this approach in a thin film of perovskite SrSnO3 with reconfigurable…

Nanocrystals of indium oxide (In$_2$O$_3$) with sizes below 10 nm were prepared in alumina matrixes by using a co-pulverization method. The used substrates such as borosilicate glasses or (100) silicon as well as the substrate temperatures…

We report about the fabrication and characterization of iron oxide nanoparticle thin film superlattices. The formation into different film morphologies is controlled by tuning the particle plus solvent-to-substrate interaction. It turns out…

Mesoscale and Nanoscale Physics · Physics 2015-06-16 D. Mishra , D. Greving , G. A. Badini Confalonieri , J. Perlich , B. P. Toperverg , H. Zabel , O. Petracic

Transition metal oxides have long been an area of interest for water electrocatalysis through the oxygen evolution and oxygen reduction reactions. Iron oxides, such as LaFeO$_{3}$, are particularly promising due to the favorable energy…

The two-dimensional nature of engineered transition-metal ultra-thin oxide films offers a large playground of yet to be fully understood physics. Here, we study pristine SrVO$_3$ monolayers that have recently been predicted to display a…

Strongly Correlated Electrons · Physics 2022-01-19 Matthias Pickem , Jan M. Tomczak , Karsten Held