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Stepped well-ordered semiconductor surfaces are important as nanotemplates for the fabrication of one-dimensional nanostructures which are candidates of intriguing electronic properties. Therefore a detailed understanding of the underlying…

Mesoscale and Nanoscale Physics · Physics 2017-11-08 Carmen P érez León , Holger Drees , Stefan Martin Wippermann , Michael Marz , Regina Hoffmann-Vogel

We present a computational approach for electronically correlated metallic surfaces and interfaces, which combines Density Functional and Dynamical Mean Field Theory using a multi-orbital perturbative solver for the many-body problem. Our…

Strongly Correlated Electrons · Physics 2022-04-06 Andrea Droghetti , Miloš M. Radonjić , Anita Halder , Ivan Rungger , Liviu Chioncel

Kohn-Sham density functional theory and plane wave basis set based ab initio molecular dynamics (AIMD) simulation is a powerful tool for studying complex reactions in solutions, such as electron transfer (ET) reactions involving…

Chemical Physics · Physics 2022-09-07 Sagarmoy Mandal , Ritama Kar , Bernd Meyer , Nisanth N. Nair

Battery electrode surfaces are generally coated with electronically insulating solid films of thickness 1-50 nm. Both electrons and Li+ can move at the electrode-surface film interface in response to the voltage, which adds complexity to…

Materials Science · Physics 2015-07-10 Kevin Leung , Andrew Leenheer

Sodium, magnesium and aluminum adatoms, which, respectively, possess one, two and three valence electrons in terms of 3s, $3s^2$, and ($3s^2$, 3p) orbitals, are very suitable for helping us understand the adsorption-induced diverse…

Materials Science · Physics 2020-03-06 Ngoc Thanh Thuy Tran , Godfrey Gumbs , Duy Khanh Nguyen , Ming-Fa Lin

The adsorption of atomic oxygen and its inclusion into subsurface sites on Ag(210) and Ag(410) surfaces have been investigated using density functional theory. We find that--in the absence of adatoms on the first metal layer--subsurface…

Condensed Matter · Physics 2009-11-10 A. Kokalj , N. Bonini , A. Dal Corso , S. de Gironcoli , S. Baroni

A series of density functional theory (DFT) simulations was performed to investigate the approach, contact, and subsequent separation of two atomically flat surfaces consisting of different materials. Aluminum (Al) and titanium nitride…

Materials Science · Physics 2015-04-24 Gregor Feldbauer , Michael Wolloch , Pedro O. Bedolla , Peter Mohn , Josef Redinger , András Vernes

Alumina (Al$_{2}$O$_{3}$) is a key material for thin-film growth and heterogeneous catalysis, where the atomic surface structure critically impacts performance. Using noncontact atomic force microscopy (nc-AFM) combined with density…

Site density functional theory (SDFT) provides a rigorous framework for statistical mechanics analysis of inhomogeneous molecular liquids. The key defining feature of these systems is the presence of two very distinct interactions scales…

Statistical Mechanics · Physics 2020-11-24 Gennady N. Chuev , Marina V. Fedotova , Marat Valiev

Molecular-level understanding of the interactions between the constituents of an atomic structure is essential for designing novel materials in various applications. This need goes beyond the basic knowledge of the number and types of…

A long-standing controversy related to the dimer pattern formed by S atoms in methanethiol ($CH_{3}SH$) on the Au(111) surface has been resolved using density functional theory. For the first time, dimerization of methanethiol adsorbates on…

Materials Science · Physics 2009-11-13 Jian-Ge Zhou , Quinton L. Williams , Frank Hagelberg

The interaction of silicene with Si, C, H, O, Ti atoms along with H$_2$, H$_2$O and O$_2$ molecules are investigated and the induced functionalities thereof are analyzed using first principles density functional theory. Si adatom initially…

Materials Science · Physics 2013-11-27 V. Ongun Özçelik , S. Ciraci

Developing efficient hydrogen storage and conversion technologies is essential for sustainable energy. This study investigates the catalytic potential of a dicalcium nitride (Ca2N) monolayer for hydrogen dissociation using density…

Mesoscale and Nanoscale Physics · Physics 2025-01-28 Gwan Woo Kim , Soonmin Jang , Gunn Kim

Atomic Layer Deposition (ALD) is a promising technique for producing Josephson junctions (JJs) with lower defect densities for qubit applications. A key problem with using ALD for JJs is the interfacial layer (IL) that develops underneath…

Superconductivity · Physics 2014-08-14 Alan J. Elliot , Chunrui Ma , Rongtao Lu , Melisa Xin , Siyuan Han , Judy Z. Wu , Ridwan Sakidja , Haifeng Yu

First-principles simulations of electronic properties of hybrid inorganic/organic interfaces are challenging, as common density-functional theory (DFT) approximations target specific material classes like bulk semiconductors or gas-phase…

Materials Science · Physics 2023-02-13 Jannis Krumland , Caterina Cocchi

Using an ab initio density functional theory (DFT) based electronic structure method, we study the effects of adatoms on the electronic properties of monolayer transition metal dichalcogenide (TMD) Molybdenum-disulfide (MoS2). We consider…

Mesoscale and Nanoscale Physics · Physics 2014-04-08 Jiwon Chang , Stefano Larentis , Emanuel Tutuc , Leonard F. Register , Sanjay K. Banerjee

Atomic layer deposition (ALD), a layer-by-layer controlled method to synthesize ultrathin materials, provides various merits over other techniques such as precise thickness control, large area scalability and excellent conformality. Here we…

Understanding the reactivity of carbon surfaces is crucial for the development of advanced functional materials. In this study, we systematically investigate the reactivity of graphene surfaces with the Stone-Wales (SW) defect using Density…

Materials Science · Physics 2023-08-11 Aleksandar Z. Jovanović , Ana S. Dobrota , Natalia V. Skorodumova , Igor A. Pašti

Area-selective atomic layer deposition is a key technology for modern microelectronics as it eliminates alignment errors inherent to conventional approaches by enabling material deposition only in specific areas. Typically, the selectivity…

Catalysis has entered everyday life through a number of technological processes relying on different catalytic systems. The increasing demand for such systems requires rationalization of the use of their expensive components, like noble…

Materials Science · Physics 2019-10-29 A. S. Dobrota , I. A. Pašti , A. Z. Jovanović , B. Johansson , N. V. Skorodumova