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An overview is given of the chemical processes that occur in primordial systems under the influence of radiation, metal abundances and dust surface reactions. It is found that radiative feedback effects differ for UV and X-ray photons at…

Astrophysics · Physics 2009-11-13 M. Spaans

The atomic-to-molecular hydrogen (H/H2) transition has been extensively studied as it controls the fraction of gas in a molecular state in an interstellar cloud. This fraction is linked to star-formation by the Schmidt-Kennicutt law. While…

Astrophysics of Galaxies · Physics 2021-12-08 Vincent Maillard , Emeric Bron , Franck Le Petit

Molecular hydrogen is the most abundant molecule in the Universe. It is thought that a large portion of H2 forms by association of hydrogen atoms to polycyclic aromatic hydrocarbons (PAHs). We model the influence of PAHs on total H2…

Astrophysics of Galaxies · Physics 2015-07-01 Leon Boschman , Stéphanie Cazaux , Marco Spaans , Ronnie Hoekstra , Thomas Schlathölter

The formation of compact dusty clouds in diffuse interstellar medium (ISM) has been recently proposed and studied by Tsytovich et al. (2014). In the present paper, an effect of the clouds on the rate of H$\to$H$_2$ transition in the ISM is…

Astrophysics of Galaxies · Physics 2018-07-11 A. V. Ivlev , A. Burkert , A. Vasyunin , P. Caselli

How does turbulence contribute to the formation and structure of the dense interstellar medium (ISM)? Molecular clouds are dense, high-pressure objects. It is usually argued that gravitational confinement causes the high pressures, and that…

Astrophysics · Physics 2017-01-18 Mordecai-Mark Mac Low

Molecular clouds, the birthplaces of stars in galaxies, form dynamically from the diffuse atomic gas of the interstellar medium (ISM). The ISM is also threaded by magnetic fields which have a large impact on its dynamics. In particular,…

Astrophysics of Galaxies · Physics 2015-09-14 Robi Banerjee , Bastian Körtgen

Molecular outflows contributing to the matter cycle of star forming galaxies are now observed in small and large systems at low and high redshift. Their physical origin is still unclear. In most theoretical studies only warm ionised/neutral…

Astrophysics of Galaxies · Physics 2021-05-28 Philipp Girichidis , Thorsten Naab , Stefanie Walch , Thomas Berlok

We investigate the chemical evolution of a forming molecular cloud behind an interstellar shock wave. We conduct three-dimensional magnetohydrodynamics simulations of the converging flow of atomic gas, including a simple chemical network…

Astrophysics of Galaxies · Physics 2026-01-08 Yuto Komichi , Yuri Aikawa , Kazunari Iwasaki , Kenji Furuya

There has always been a great deal of interest in the formation of H2 as well as in the binding energy released upon its formation on the surface of dust grains. The present work aims at collecting experimental evidence for how the bond…

Many theoretical and laboratory studies predict H2 to be formed in highly excited ro-vibrational states. The consequent relaxation of excited levels via a cascade of infrared transitions might be observable in emission from suitable…

Astrophysics of Galaxies · Physics 2015-05-20 Farahjabeen Islam , Cesare Cecchi-Pestellini , Serena Viti , Silvia Casu

Ultra-luminous infrared galaxies are among the most luminous objects in the local universe and are thought to be powered by intense star formation. It has been shown that in these objects the rotational spectral lines of molecular hydrogen…

Cosmology and Nongalactic Astrophysics · Physics 2015-05-19 Nadia L. Zakamska

The formation of interstellar water has been commonly accepted to occur on the surfaces of icy dust grains in dark molecular clouds at low temperatures (10-20 K), involving hydrogenation reactions of oxygen allotropes. As a result of the…

Astrophysics of Galaxies · Physics 2014-10-22 Thanja Lamberts , Herma Cuppen , Gleb Fedoseev , Sergio Ioppolo , Ko-Ju Chuang , Harold Linnartz

The results of experiments on the formation of molecular hydrogen on low density and high density amorphous ice surfaces are analyzed using a rate equation model. The activation energy barriers for the relevant diffusion and desorption…

We present numerical computations and analysis of atomic to molecular (HI-to-H$_2$) transitions in cool ($\sim$100 K) low-metallicity dust-free (primordial) gas, in which molecule formation occurs via cosmic-ray driven negative ion…

Astrophysics of Galaxies · Physics 2021-10-27 Amiel Sternberg , Alon Gurman , Shmuel Bialy

FIR and submm observations have established the fundamental role of dust-obscured star formation in the assembly of stellar mass over the past 12 billion years. At z between 2 and 4, the bulk of star formation is enshrouded in dust, and…

Astrophysics of Galaxies · Physics 2024-04-16 Francesca Perrotta , Martina Torsello , Marika Giulietti , Andrea Lapi

Although still poorly understood, the chemistry that occurs on the surfaces of interstellar dust particles profoundly affects the growth of molecules in the interstellar medium. An important set of surface reactions produces icy mantles of…

Astrophysics · Physics 2009-11-13 H. M. Cuppen , Eric Herbst

A possible formation mechanism of hydrogen molecules on a galactic scale is examined. We are interested especially in the role of hydrogen molecules for formation and evolution of primordial galaxies. Then, formation process of hydrogen…

Astrophysics · Physics 2015-06-24 Hideyuki Kamaya , Hiroyuki Hirashita

Observations of spiral galaxies show a strong linear correlation between the ratio of molecular to atomic hydrogen surface density R_mol and midplane pressure. To explain this, we simulate three-dimensional, magnetized turbulence, including…

Astrophysics of Galaxies · Physics 2015-05-20 Mordecai-Mark Mac Low , Simon C. O. Glover

Star formation is inefficient. Recent advances in numerical simulations and theoretical models of molecular clouds show that the combined effects of interstellar turbulence, magnetic fields and stellar feedback can explain the low…

Solar and Stellar Astrophysics · Physics 2020-02-12 Christoph Federrath

CO2 is one of the dominant components of the interstellar ice. Recent observations show CO2 exists more abundantly in polar (H2O-dominated) ice than in apolar (H2O-poor) ice. CO2 ice formation is primarily attributed to the reaction between…

Astrophysics of Galaxies · Physics 2023-09-06 Germán Molpeceres , Joan Enrique-Romero , Yuri Aikawa