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This review outlines several linear optical effects featured by molecular polaritons arising in the collective strong light-matter coupling regime. Under weak laser irradiation and when the single-molecule light-matter coupling can be…

Strong coupling between electronic excitations in materials and photon modes results in the formation of polaritons, which display larger nonlinearities than their photonic counterparts due to their material component. We theoretically…

Chemical Physics · Physics 2023-08-29 Sindhana Pannir-Sivajothi , Nathaniel P. Stern , Joel Yuen-Zhou

We show that a system of polaritons - combined atom and photon excitations - in an array of coupled cavities, under an experimental set-up usually considered in electromagnetically induced transparency, is described by the Bose-Hubbard…

Quantum Physics · Physics 2007-05-23 Fernando G. S. L. Brandao , Michael J. Hartmann , Martin B. Plenio

Fabry-Perot microcavities can strongly enhance interactions between light and molecules, leading to the formation of hybrid light-matter states known as polaritons. Polaritons possess much smaller effective masses and much larger group…

Chemical Physics · Physics 2023-10-18 Zeyu Zhou , Hsing-Ta Chen , Maxim Sukharev , Joseph E. Subotnik , Abraham Nitzan

The way molecules absorb, transfer, and emit light can be modified by coupling them to optical cavities. The extent of the modification is often defined by the cavity-molecule coupling strength, which depends on the number of coupled…

Optics · Physics 2021-06-11 Adarsh B Vasista , Kishan S Menghrajani , William L Barnes

Under vibrational strong coupling (VSC), the formation of molecular polaritons may significantly modify the photo-induced or thermal properties of molecules. In an effort to understand these intriguing modifications, both experimental and…

Chemical Physics · Physics 2022-04-07 Tao E. Li , Abraham Nitzan , Joseph E. Subotnik

Recently, condensed matter and atomic experiments have reached a length-scale and temperature regime where new quantum collective phenomena emerge. Finding such physics in systems of photons, however, is problematic, as photons typically do…

Other Condensed Matter · Physics 2007-08-01 Andrew D. Greentree , Charles Tahan , Jared H. Cole , L. C. L. Hollenberg

It is widely assumed that photons cannot be manipulated using electric or magnetic fields. Even though hybridization of photons with electronic polarization to form exciton-polaritons has paved the way to a number of ground-breaking…

Ordinarily, photons do not interact with one another. However, atoms can be used to mediate photonic interactions, raising the prospect of forming synthetic materials and quantum information systems from photons. One promising approach uses…

We use the polarized Fock states to describe the coupled molecule-cavity hybrid system in quantum electrodynamics. The molecular permanent dipoles polarize the photon field by displacing its vector potential, leading to non-orthogonality…

Quantum Physics · Physics 2020-05-04 Arkajit Mandal , Sebastian Montillo Vega , Pengfei Huo

We propose collective nuclear polaritons formed by hybridizing a 229Th nuclear ensemble with a vacuum-ultraviolet cavity mode generated via four-wave mixing, achieving a collective light-matter coupling that scales as $\sqrt{N}$. In the…

Quantum Physics · Physics 2026-03-17 Liufeng Yang , Jinling Wang , Huijun Li , Junhui Cao , Alexey Kavokin , Congjun Wu

The quantum photodynamics of a simple diatomic molecule with a permanent dipole immersed within an optical cavity containing a quantized radiation field is studied in detail. The chosen molecule under study, lithium fluoride (LiF), is…

Chemical Physics · Physics 2018-01-24 Johan F. Triana , Daniel Peláez , José Luis Sanz-Vicario

A model designed to mimic the implications of the collective optical response of molecular ensembles in optical cavities on molecular vibronic dynamics is investigated. Strong molecule-radiation field coupling is often reached when a large…

Chemical Physics · Physics 2022-10-05 Bingyu Cui , Abraham Nitzan

This is a tutorial-style introduction to the field of molecular polaritons. We describe the basic physical principles and consequences of strong light-matter coupling common to molecular ensembles embedded in UV-visible or infrared…

Chemical Physics · Physics 2020-03-18 Felipe Herrera , Jeffrey Owrutsky

We analyze the properties of strongly coupled excitons and photons in systems made of semiconducting two-dimensional transition-metal dichalcogenides embedded in optical cavities. Through a detailed microscopic analysis of the coupling we…

Mesoscale and Nanoscale Physics · Physics 2018-10-03 Á. Gutiérrez-Rubio , L. Chirolli , L. Martín-Moreno , F. J. García-Vidal , F. Guinea

BEC of exciton-polaritons and related effects such as superfluidity1,2, spontaneous symmetry breaking3,4 and quantised vortices5,6 open way to creation of novel light sources7 and optical logic elements8. Remarkable observations of…

Quantum Gases · Physics 2012-08-24 Elena Kammann , Hamid Ohadi , Maria Maragkou , Alexey V. Kavokin , Pavlos G. Lagoudakis

The transformation of electromagnetic energy into matter represents a fascinating prediction of relativistic quantum electrodynamics that is paradigmatically exemplified by the creation of electron-positron pairs out of light. However, this…

Optics · Physics 2025-09-23 Valerio Di Giulio , F. Javier García de Abajo

Strong light-matter coupling gives rise to polaritons - hybrid excitations whose mixed photonic and matter character enables control over optical, electronic and chemical properties. This Feature Article surveys the main architectures…

We investigate the influence of exciton-phonon coupling on the dynamics of a strongly coupled quantum dot-photonic crystal cavity system and explore the effects of this interaction on different schemes for non-classical light generation. By…

The formation of the composite photonic-excitonic particle, known as a polariton, is a phenomenon emerging in materials possessing strong coupling to light. The organic-based materials besides the strong light-matter coupling also…

Chemical Physics · Physics 2023-01-19 Vladimir Al. Osipov , Boris Fainberg