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The manipulation of exciton-polaritons and their condensates is of great interest due to their applications in polariton simulators and high-speed, all-optical logic devices. Until now, methods of trapping and manipulating such condensates…

We employ the exact factorization of a multi-component wavefunction to analyze the dynamics of interacting photons, electrons and nuclei. We consider physical situations emerging in the regime of strong coupling between light excitations…

Chemical Physics · Physics 2026-04-24 Claudia Magi , Peter Schuerger , David Lauvergnat , Federica Agostini

The observation that materials can change their properties when placed inside or near an optical resonator, has sparked a fervid interest in understanding the effects of strong light-matter coupling on molecular dynamics, and several…

Chemical Physics · Physics 2024-03-20 Ilia Sokolovskii , Gerrit Groenhof

Following our recent numerical study [arXiv:2601.16299 (2026)], we investigate vibrational excitation induced by transient optical driving in molecular ensembles strongly coupled to a cavity mode using the field-driven…

We investigate optical nonlinear interactions in a dynamic environment by studying generation of photons in spontaneous parametric down conversion inside a nonlinear cavity where the optical path length is periodically modulated in time. We…

Optics · Physics 2019-10-16 Usman A. Javid , Qiang Lin

Polaritons - hybrid light-matter states formed in cavity - strongly change the properties of the underlying matter. In optical or plasmonic nanocavities, polaritons decay by radiative emission of the cavity, which is accessible…

Chemical Physics · Physics 2022-10-19 Csaba Fábri , Gábor J. Halász , Lorenz S. Cederbaum , Ágnes Vibók

Vibrational polaritons, hybrid light-matter states formed between molecular vibrations and infrared (IR) cavity modes, provide a novel approach for modifying chemical reaction pathways and energy transfer processes. For vibrational…

Chemical Physics · Physics 2025-05-16 Xinwei Ji , Tao E. Li

Polaritons are an emerging platform for exploration of synthetic materials [1] and quantum information processing [2] that draw properties from two disparate particles: a photon and an atom. Cavity polaritons are particularly promising, as…

Strong light-matter coupling is a quantum process in which light and matter are coupled together, generating hybridized states. This is similar to the notion of molecular hybridization, but one of the components is light. Here, we utilized…

Applied Physics · Physics 2024-02-20 Jhuma Dutta , Pooja Bhatt , Kuljeet Kaur , Daniel E. Gómez , Jino George

We consider an ensemble of homonuclear diatomic molecules coupled to the two polarization directions of a Fabry-P\'erot cavity via fully quantum simulations. Accompanied by analytical results, we identify a coupling mechanism mediated…

Chemical Physics · Physics 2024-01-22 Niclas Krupp , Oriol Vendrell

Vibrational polaritons are formed by strong coupling of molecular vibrations and photon modes in an optical cavity. Experiments have demonstrated that vibrational strong coupling can change molecular properties and even affect chemical…

Quantum Physics · Physics 2025-01-14 Thomas Schnappinger , Cyril Falvo , Markus Kowalewski

A remote energy transfer pathway from electronic to vibrational degrees of freedom is identified inside an infrared optical cavity under vibrational strong coupling conditions. This mechanism relies on the dynamical Casimir effect, whereby…

Quantum Physics · Physics 2024-03-19 Tao E. Li

Optical microcavities and metallic nanostructures have been shown to significantly modulate the dynamics and spectroscopic response of molecular systems. We present a study of the nonlinear optics of a model consisting of $N$ anharmonic…

Polaritons have gained significant attention for the tantalizing possibility of modifying chemical properties and dynamics by coupling molecules to resonant cavity modes to create hybrid light-matter quantum states. Herein, we implement the…

Chemical Physics · Physics 2025-06-24 Scott M. Garner , Xiaosong Li , Sharon Hammes-Schiffer

The interaction between molecular (atomic) electron(s) and the vacuum field of a reflective cavity generates a significant interest thanks to the rapid developments in nanophotonics. Such interaction which lies within the realm of cavity…

Chemical Physics · Physics 2019-05-22 Alexander Semenov , Abraham Nitzan

Recent experiments have demonstrated that molecular polaritons, hybrid states of light and matter formed by the strong coupling between molecular electronic or vibrational excitations and an optical cavity, can substantially modify the…

Chemical Physics · Physics 2021-07-08 Nguyen Thanh Phuc

Reversible exchange of photons between a material and an optical cavity can lead to the formation of hybrid light--matter states where material properties such as the work function\cite{Hutchison_AM2013a}, chemical…

We experimentally probe the non-resonant feeding of photons into the optical mode of a two dimensional photonic crystal nanocavity from the discrete emission from a quantum dot. For a strongly coupled system of a single exciton and the…

Mesoscale and Nanoscale Physics · Physics 2011-06-02 A. Laucht , N. Hauke , A. Neumann , T. Günthner , F. Hofbauer , A. Mohtashami , K. Müller , G. Böhm , M. Bichler , M. -C. Amann , M. Kaniber , J. J. Finley

Strong light-matter coupling within an optical cavity leverages the collective interactions of molecules and confined electromagnetic fields, giving rise to the possibilities of modifying chemical reactivity and molecular properties. While…

Chemical Physics · Physics 2025-05-29 Shravan Kumar Sharma , Hsing-Ta Chen

We analyze the real-time electron-photon dynamics in long-range polariton-mediated energy transfer using a real-time quantum electrodynamics coupled cluster (RT-QED-CC) model, which allows for spatial and temporal visualization of transport…

Chemical Physics · Physics 2024-04-16 Matteo Castagnola , Marcus T. Lexander , Enrico Ronca , Henrik Koch