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We present a microscopic model for surface-enhanced Raman scattering (SERS) from molecules adsorbed on small noble-metal nanoparticles. In the absence of direct overlap of molecular orbitals and electronic states in the metal, the main…

Mesoscale and Nanoscale Physics · Physics 2009-11-11 Vitaliy N. Pustovit , Tigran V. Shahbazyan

The review is devoted to explanation of SERS in terms of the dipole and quadrupole light-molecule interactions arising in surface fields strongly varying in space in the region of the strongly irregular surface roughness. The main SERS…

Chemical Physics · Physics 2013-10-01 A. M. Polubotko

Tetragonal Mn$_x$Ga$_{1-x}$ (x=0.70, 0.75) thin films grown on SrTiO$_3$ substrates at different temperatures and thicknesses exhibit perpendicular magnetic anisotropy with coercive fields between 1-2 T. Transmission electron microscopy…

Materials Science · Physics 2015-04-14 J. Karel , F. Casoli , P. Lupo , L. Nasi , S. Fabbrici , L. Righi , F. Albertini , C. Felser

Chiral nanophotonic platforms provide a means of creating near fields with both enhanced asymmetric properties and intensities. They can be exploited for optical measurements that allow enantiomeric discrimination at detection levels…

We present a general framework for inverse design of nanopatterned surfaces that maximize spatially averaged surface-enhanced Raman (SERS) spectra from molecules distributed randomly throughout a material or fluid, building upon a recently…

Twisted van der Waals heterostructures unravel a new platform to study strongly correlated quantum phases. The interlayer coupling in these heterostructures is sensitive to twist angles ($\theta$) and key to controllably tune several exotic…

Materials Science · Physics 2019-12-03 Rahul Debnath , Indrajit Maity , Manish Jain , Arindam Ghosh

A theoretical study describing the coherence properties of near-field Raman scattering in two- and one-dimensional systems is presented. The model is applied to the Raman modes of pristine graphene and graphene edges. Our analysis is based…

Mesoscale and Nanoscale Physics · Physics 2014-03-31 Luiz Gustavo Cançado , Ryan Beams , Ado Jorio , Lukas Novotny

Thermal mode spectroscopy (TMS) has been recently proposed for accurately measuring thermal diffusivity of solids from a temperature decay rate of a specific thermal mode selected by three- dimensional (anti)nodal information [Phys. Rev.…

Materials Science · Physics 2018-06-29 Hideshi Ishida , Hirotsugu Ogi

Intelligent reflecting surfaces (IRSs) have emerged as a cost-effective technology for terahertz (THz) communications by enabling programmable control of the wireless environment. This paper provides a comprehensive overview of IRSs-aided…

Signal Processing · Electrical Eng. & Systems 2025-06-23 Qingqing Wu , Yanze Zhu , Qiaoyan Peng , Wanming Hao , Yanzhao Hou , Fengyuan Yang , Wencai Yan , Guoning Wang , Wen Chen , Chi Qiu

Rigorous electromagnetic field simulations are an essential part for scatterometry and mask pattern design. Today mainly periodic structures are considered in simulations. Non-periodic structures are typically modeled by large, artificially…

Optics · Physics 2009-11-13 L. Zschiedrich , F. Schmidt

Hydrogenated amorphous carbon thin films (a:C-H) are very promising materials for numerous applications. The growing of relevance of a:C-H is mainly due to the long-term stability of their outstanding properties. For improving their…

Materials Science · Physics 2025-01-22 L. Lajaunie , C. Pardanaud , C. Martin , P. Puech , C. Hu , M. J. Biggs , R. Arenal

Recent developments in surface-enhanced Raman scattering (SERS) enable observation of single-bond vibrations in real-time at room temperature. By contrast, mid-infrared (MIR) vibrational spectroscopy is limited to inefficient slow…

Using a combination of first-principles theory and experiments, we provide a quantitative explanation for chemical contributions to surface-enhanced Raman spectroscopy for a well-studied organic molecule, benzene thiol, chemisorbed on…

Materials Science · Physics 2015-05-20 A. T. Zayak , Y. S. Hu , H. Choo , J. Bokor , S. Cabrini , P. J. Schuck , J. B. Neaton

We demonstrate a high-performance apertureless near-field probe made of a tapered metal tip with a set of periodic shallow grooves near the apex. The spontaneous emission from a single emitter near the tip is investigated systematically for…

Layered materials (LMs) such as graphene or MoS$_2$ have recently attracted a great deal of interest. These materials offer unique functionalities due to their structural anisotropy characterized by weak van der Waals bonds along the…

Applied Physics · Physics 2019-12-13 M. O. Cichocka , M. Bolhuis , S. E. van Heijst , S. Conesa-Boj

Contaminations in the formation of two-dimensional heterostructures can hinder or generate desired properties. Recent advancements have highlighted the potential of tip-enhanced Raman spectroscopy (TERS) for studying materials in the 2D…

Strain at surfaces and interfaces play an important role in the optical and electronic properties of materials. MeV ion-induced strain determination in single crystal silicon substrates and in Ag (nanoisland)/Si(111) at surface and…

Materials Science · Physics 2015-06-25 J. Ghatak , B. Satpati , M. Umananda , P. V. Satyam , K. Akimoto , K. Ito , T. Emoto

The interaction between molecules is commonly ignored in surface-enhanced Raman scattering (SERS). Under this assumption, the total SERS signal is described as the sum of the individual contributions of each molecule treated independently.…

Optics · Physics 2020-01-08 Yuan Zhang , Javier Aizpurua , Ruben Esteban

Angle-resolved photoemission spectroscopy (ARPES), an experimental technique based on the photoelectric effect, is arguably the most powerful method for probing the electronic structure of solids. The past decade has witnessed notable…

Materials Science · Physics 2021-06-21 Baiqing Lv , Tian Qian , Hong Ding
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