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Geometrical confinement effect in exfoliated sheets of layered materials leads to significant evolution of energy dispersion with decreasing layer thickness. Molybdenum disulphide (MoS2) was recently found to exhibit indirect to direct gap…

Materials Science · Physics 2014-03-13 Weijie Zhao , Zohreh Ghorannevis , Leiqiang Chua , Minglin Toh , Christian Kloc , Ping-Heng Tan , Goki Eda

Due to its high carrier mobility, broadband absorption, and fast response time, graphene is attractive for optoelectronics and photodetection applications. However, the extraction of photoelectrons in conventional metal-graphene junction…

We have performed an {\it ab initio} theoretical investigation of graphene sheet adsorbed on amorphous SiO$_2$ surface (G/a-SiO$_2$). We find that graphene adsorbs on the a-SiO$_2$ surface through van der Waals interactions. The…

Materials Science · Physics 2015-05-28 R. H. Miwa , T. M. Schmidt , A. Fazzio

2D ferroelectric \{beta}-InSe/graphene heterostructure was fabricated by mechanical exfoliation, and the carrier dynamics crossing the heterostructure interface has been systematically investigated by Raman, photoluminescence and transient…

Mesoscale and Nanoscale Physics · Physics 2023-05-17 Jialin Li , Yuzhong Chen , Yujie Li , Haiming Zhu , Linjun Li

Near-field optical microscopy can be used as a viable route to understand the nanoscale material properties below the diffraction limit. On the other hand, atomically thin two-dimensional (2D) transition metal dichalcogenides (TMDs) are the…

Atomically thin vanadium diselenide (VSe2 ) is a two-dimensional transition metal dichalcogenide exhibiting attractive properties due to its metallic 1T-phase. With the recent development of methods to manufacture high-quality monolayer VSe…

Strongly Correlated Electrons · Physics 2021-05-14 Tae Gwan Park , Byoung Ki Choi , Junho Park , Jungdae Kim , Young Jun Chang , Fabian Rotermund

The ultimate surface exposure provided by graphene monolayer makes it the ideal sensor platform but also exposes its intrinsic properties to any environmental perturbations. In this work, we demonstrate that the charge carrier density of…

We report on spectroscopy results from the mid- to far-infrared on wafer-scale graphene, grown either epitaxially on silicon carbide, or by chemical vapor deposition. The free carrier absorption (Drude peak) is simultaneously obtained with…

Mesoscale and Nanoscale Physics · Physics 2011-11-17 Hugen Yan , Fengnian Xia , Wenjuan Zhu , Marcus Freitag , Christos Dimitrakopoulos , Ageeth A. Bol , George Tulevski , Phaedon Avouris

We report on the mechanism of energy transfer in van der Waals heterostructures of the two-dimensional semiconductor WS$_2$ and graphene with varying interlayer distances, achieved through spacer layers of hexagonal boron nitride (hBN). We…

Mesoscale and Nanoscale Physics · Physics 2024-06-13 David Tebbe , Marc Schütte , K. Watanabe , T. Taniguchi , Christoph Stampfer , Bernd Beschoten , Lutz Waldecker

Understanding charge transfer (CT) between two chemical entities and subsequent change in their charge densities is essential not only for molecular species but also for various low-dimensional materials. Because of their extremely high…

Materials Science · Physics 2021-08-04 Haneul Kang , Kwanghee Park , Sunmin Ryu

This article discusses the behavior of submonolayer quantum films (He and H2) on graphene and newly discovered surfaces that are derived from graphene. Among these substrates are graphane (abbreviated GH), which has an H atom bonded to each…

Mesoscale and Nanoscale Physics · Physics 2015-06-17 Luciano Reatto , Davide E. Galli , Marco Nava , Milton W. Cole

Transition metal dichalcogenide (TMDC) heterostructures have unique properties that depend on the twisting angle and stacking order of two or more monolayers. However, their practical applications are limited by the low photoluminescence…

The temperature-induced shift of the Raman G line in epitaxial graphene on SiC and Ni surfaces, as well as in graphene supported on SiO2, is investigated with Raman spectroscopy. The thermal shift rate of epitaxial graphene on 6H-SiC(0001)…

Mesoscale and Nanoscale Physics · Physics 2011-02-18 Nicola Ferralis , Roya Maboudian , Carlo Carraro

We use a van-der-Waals pickup technique to fabricate different heterostructures containing WSe$_2$(WS$_2$) and graphene. The heterostructures were structured by plasma etching, contacted by one-dimensional edge contacts and a topgate was…

Mesoscale and Nanoscale Physics · Physics 2017-09-14 Tobias Völkl , Tobias Rockinger , Martin Drienovsky , Kenji Watanabe , Takashi Taniguchi , Dieter Weiss , Jonathan Eroms

Monolayers of transition-metal dichalcogenides such as WSe2 have become increasingly attractive due to their potential in electrical and optical applications. Because the properties of these 2D systems are known to be affected by their…

We present the effect of oxidative etching in FLG/TiO$_2$ hybrids on FLG edges chemistry/morphology addressing also the catalytic activity of TiO$_2$ NPs. According to the XPS and TGA analysis the oxidation degree strongly depends on…

Materials Science · Physics 2022-12-14 Hamza El Marouazi , Valérie Keller , Izabela Janowska

Transition metal dichalcogenides like MoS2 can exist many phases like the semiconducting 2H and the metallic 1T phases which have shown intriguing properties for energy and electrocatalytic applications. However, the 2H and 1T phases…

Applied Physics · Physics 2019-10-10 Qingqing Ke , Xiao Zhang , Abdelnaby M. Elshahawy , Yating Hu , Qiyuan He , Yongqing Cai , John Wang

Two-dimensional (2D) materials have recently been the focus of extensive research. By following a similar trend as graphene, other 2D materials including transition metal dichalcogenides (MX2) and metal mono-chalcogenides (MX) show great…

The vibrational and electronic properties of 2-dimensinal (2D) materials can be efficiently tuned by external strain due to their good stretchability. Resonant Raman spectroscopy is a versatile tool to study the physics of phonons,…

Mesoscale and Nanoscale Physics · Physics 2019-06-05 Chaoyu Song , Fengren Fan , Ningning Xuan , Shenyang Huang , Chong Wang , Guowei Zhang , Fanjie Wang , Qiaoxia Xing , Yuchen Lei , Zhengzong Sun , Hua Wu , Hugen Yan

Magneto Raman scattering study of the E$_{2g}$ optical phonons in multi-layer epitaxial graphene grown on a carbon face of SiC are presented. At 4.2K in magnetic field up to 33 T, we observe a series of well pronounced avoided crossings…

Materials Science · Physics 2015-05-13 C. Faugeras , M. Amado , P. Kossacki , M. Orlita , M. Sprinkle , C. Berger , W. A. de Heer , M. Potemski