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The electron pair approximation offers a resource efficient variational quantum eigensolver (VQE) approach for quantum chemistry simulations on quantum computers. With the number of entangling gates scaling quadratically with system size…

The periodic standing wave method studies circular orbits of compact objects coupled to helically symmetric standing wave gravitational fields. From this solution an approximation is extracted for the strong field, slowly inspiralling…

General Relativity and Quantum Cosmology · Physics 2008-11-26 Christopher Beetle , Benjamin Bromley , Napoleón Hernández , Richard H. Price

The search for new materials, based on computational screening, relies on methods that accurately predict, in an automatic manner, total energy, atomic-scale geometries, and other fundamental characteristics of materials. Many…

Materials Science · Physics 2017-10-25 M. J. van Setten , M. Giantomassi , X. Gonze , G. -M. Rignanese , G. Hautier

Ab initio quantum chemistry calculations for systems with large active spaces are notoriously difficult and cannot be successfully tackled by standard methods. In this letter, we generalize a Green's function QM/QM embedding method called…

Chemical Physics · Physics 2018-06-07 Tran Nguyen Lan , Dominika Zgid

We present a new approach to real-space multiple-scattering theory for molecules and clusters, based on the two-potential (distorted-wave) Lippmann-Schwinger equation formalism. Our approach uses a recently developed form [D. L. Foulis,…

Mathematical Physics · Physics 2008-06-04 D. L. Foulis

Calculations of ground-state and excited-state properties of materials have been one of the major goals of condensed matter physics. Ground-state properties of solids have been extensively investigated for several decades within the…

Strongly Correlated Electrons · Physics 2009-10-30 F. Aryasetiawan , O. Gunnarsson

We propose an alternative formulation of Many-Body Perturbation Theory that uses the density-functional concept. Instead of the usual four-point integral equation for the polarizability, we obtain a two-point one, that leads to excellent…

Other Condensed Matter · Physics 2010-07-01 Fabien Bruneval , Francesco Sottile , Valerio Olevano , Rodolfo Del Sole , Lucia Reining

We report an implementation of self-consistent Green's function many-body theory within a second-order approximation (GF2) for application with molecular systems. This is done by iterative solution of the Dyson equation expressed in matrix…

Chemical Physics · Physics 2016-11-15 Jordan J. Phillips , Dominika Zgid

GW approximation is one of the most popular parameter-free many-body methods that goes beyond the limitations of the standard density functional theory (DFT) to determine the excitation spectra for moderately correlated materials and in…

Materials Science · Physics 2023-12-12 Kristjan Haule , Subhasish Mandal

Organic electronics is a rapidly developing technology. Typically, the molecules involved in organic electronics are made up of hundreds of atoms, prohibiting a theoretical description by wavefunction-based ab-initio methods.…

Materials Science · Physics 2011-05-18 Peter Koval , Dietrich Foerster , Daniel Sanchez-Portal

Perturbation theory (PT) might be one of the most powerful and fruitful tools for both physicists and chemists, which has led to a wide variety of applications. Over the past decades, advances in quantum computing provide opportunities for…

Quantum Physics · Physics 2024-04-09 Junxu Li , Xingyu Gao

The accuracy of the many-body perturbation theory GW formalism to calculate electron-phonon coupling matrix elements has been recently demonstrated in the case of a few important systems. However, the related computational costs are high…

Computational Physics · Physics 2015-06-23 C. Faber , P. Boulanger , C. Attaccalite , E. Cannuccia , I. Duchemin , T. Deutsch , X. Blase

The cumulant expansion is a powerful approach for including correlation effects in electronic structure calculations beyond the GW approximation. However, current implementations are incomplete since they ignore terms that lead to partial…

Strongly Correlated Electrons · Physics 2014-02-04 J. J. Kas , J. J. Rehr , L. Reining

Let G be a finite subgroup of unitary matrices acting on the space of $N$-qubits. We associate with G a uniform quantum channel QU from the space on $N$-qubits to itself. We give a quantum algorithm to approximate this channel by…

Quantum Physics · Physics 2014-03-28 Shmuel Friedland

Computing many-body ground state energies and resolving electronic structure calculations are fundamental problems for fields such as quantum chemistry or condensed matter. Several quantum computing algorithms that address these problems…

Quantum Physics · Physics 2023-01-12 Karen J. Morenz Korol , Kenny Choo , Antonio Mezzacapo

Semiclassical approximations for tunneling processes usually involve complex trajectories or complex times. In this paper we use a previously derived approximation involving only real trajectories propagating in real time to describe the…

Quantum Physics · Physics 2007-05-23 L. Jaubert , M. A. M. de Aguiar

Quadratic assignment problems are a fundamental class of combinatorial optimization problems which are ubiquitous in applications, yet their exact resolution is NP-hard. To circumvent this impasse, it was proposed to regularize such…

Optimization and Control · Mathematics 2025-09-25 Venkatkrishna Karumanchi , Gabriel Rioux , Ziv Goldfeld

We present GW calculations of molecules, ordered and disordered solids and interfaces, which employ an efficient contour deformation technique for frequency integration, and do not require the explicit evaluation of virtual electronic…

Materials Science · Physics 2015-01-14 Marco Govoni , Giulia Galli

Quantum walks (QW) are of crucial importance in the development of quantum information processing algorithms. Recently, several quantum algorithms have been proposed to implement network analysis, in particular to rank the centrality of…

Quantum Physics · Physics 2021-01-04 Tong Wu , J. A. Izaac , Zi-Xi Li , Kai Wang , Zhao-Zhong Chen , Shining Zhu , J. B. Wang , Xiao-Song Ma

We apply the quasiparticle self-consistent GW method (QSGW) to slab models of ionic materials, LiF, KF, NaCl, MgO, and CaO, under electric field. Then we obtain the optical dielectric constants E(Slab) from the differences of the slopes of…

Strongly Correlated Electrons · Physics 2020-05-20 Hirofumi Sakakibara , Takao Kotani , Masao Obata , Tatsuki Oda