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In parallel to the unified construction of relativistic Hamiltonians based solely on physical arguments [J. Chem. Phys. 160, 084111 (2024)], a unified implementation of relativistic wave function methods is achieved here via programming…

Chemical Physics · Physics 2024-07-26 Ning Zhang , Wenjian Liu

We present a perturbative triples correction to the relativistic quadratic unitary coupled cluster singles and doubles (qUCCSD) method, denoted as qUCCSD[T]. The method builds upon the Hermitian structure of the unitary ansatz and employs a…

Chemical Physics · Physics 2025-10-08 Kamal Majee , Ján Šimunek , Jozef Noga , Achintya Kumar Dutta

Machine learning potentials (MLPs) are becoming powerful tools for performing accurate atomistic simulations and crystal structure optimizations. An approach to developing MLPs employs a systematic set of polynomial invariants including…

Computational Physics · Physics 2020-11-18 Atsuto Seko

We demonstrate how to build a simulation of two dimensional physical theories describing topologically ordered systems whose excitations are in one to one correspondence with irreducible representations of a Hopf algebra, D(G), the quantum…

Quantum Physics · Physics 2009-05-25 G. K. Brennen , M. Aguado , J. I. Cirac

In this work we use algebraic dual representations in conjunction with domain decomposition methods for Darcy equations. We define the broken Sobolev spaces and their finite dimensional counterparts. In addition, a global trace space is…

Numerical Analysis · Mathematics 2023-01-04 V. Jain , A. Palha , M. Gerritsma

We demonstrate a method that merges the quantum filter diagonalization (QFD) approach for hybrid quantum/classical solution of the time-independent electronic Schr\"odinger equation with a low-rank double factorization (DF) approach for the…

Quantum Physics · Physics 2022-03-21 Jeffrey Cohn , Mario Motta , Robert M. Parrish

This paper introduces the hierarchical interpolative factorization for elliptic partial differential equations (HIF-DE) in two (2D) and three dimensions (3D). This factorization takes the form of an approximate generalized LU/LDL…

Numerical Analysis · Mathematics 2015-04-21 Kenneth L. Ho , Lexing Ying

The open-shell reference relativistic equation-of-motion coupled-cluster method within its four-component description is successfully implemented with the consideration of single- and double- excitation approximation. The one-body and…

Atomic Physics · Physics 2016-09-21 Himadri Pathak , Sudip Sasmal , Malaya K. Nayak , Nayana Vaval , Sourav Pal

We present an implementation of the B term of Magnetic Circular Dichroism within the Algebraic Diagrammatic Construction (ADC) scheme of the polarization propagator and its Intermediate State Representation. As illustrative results, the MCD…

We consider a superintegrable Hamiltonian system in a two-dimensional space with a scalar potential that allows one quadratic and one cubic integral of motion. We construct the most general associative cubic algebra and we present specific…

Mathematical Physics · Physics 2009-11-13 Ian Marquette

Deep learning has been widely used for solving image reconstruction tasks but its deployability has been held back due to the shortage of high-quality training data. Unsupervised learning methods, such as the deep image prior (DIP),…

Computer Vision and Pattern Recognition · Computer Science 2023-06-06 Riccardo Barbano , Javier Antorán , Johannes Leuschner , José Miguel Hernández-Lobato , Bangti Jin , Željko Kereta

We present a semi-anisotropic interfacial potential (SAIP) designed to classically describe the interaction between gold and two-dimensional (2D) carbon allotropes such as graphene, fullerenes, or hydrocarbon molecules. The potential is…

Materials Science · Physics 2021-09-30 Wengen Ouyang , Oded Hod , Roberto Guerra

We present a theoretical framework which describes multiply-charged atomic ions, their stability within super-intense laser fields,also lay corrections to the systems due to relativistic effects. Dimensional scaling calculations with…

Quantum Physics · Physics 2015-05-30 Ross D. Hoehn , Jiaxiang Wang , Sabre Kais

We present a few ways of using conformal maps in the reconstruction of two-dimensional conductivities in electrical impedance tomography. First, by utilizing the Riemann mapping theorem, we can transform any simply connected domain of…

Numerical Analysis · Mathematics 2017-02-27 Nuutti Hyvönen , Lassi Päivärinta , Janne P. Tamminen

We present three schemes to go beyond the electric-dipole approximation in X-ray absorption spectroscopy calculations within a four-component relativistic framework. The first is based on the full semi-classical light-matter interaction…

Chemical Physics · Physics 2021-07-02 Nanna Holmgaard List , Timothé Romain Léo Melin , Martin van Horn , Trond Saue

A key objective of computational solid state physics is to predict electronic properties of periodic materials. However, electronic structure simulations based on density functional theory fail to predict experimental results if…

We report in this paper an implementation of 4-component relativistic Hamiltonian based Equation-of-Motion Coupled-Cluster with singles and doubles (EOM-CCSD) theory for the calculation of ionization potential (IP), electron affinity (EA)…

Chemical Physics · Physics 2018-11-09 Avijit Shee , Trond Saue , Lucas Visscher , Andre Severo Pereira Gomes

A new computational framework for spinor-based relativistic exact two-component (X2C) calculations is developed using contracted basis sets with a spin-orbit contraction scheme. Generally contracted j-adapted basis sets using primitive…

Chemical Physics · Physics 2024-05-08 Chaoqun Zhang , Kirk A. Peterson , Kenneth G. Dyall , Lan Cheng

We present a general solution-generating result within the bidifferential calculus approach to integrable partial differential and difference equations, based on a binary Darboux-type transformation. This is then applied to the…

Exactly Solvable and Integrable Systems · Physics 2013-02-05 Aristophanes Dimakis , Folkert Müller-Hoissen

The analysis of fields in periodic dielectric structures arise in numerous applications of recent interest, ranging from photonic bandgap (PBG) structures and plasmonically active nanostructures to metamaterials. To achieve an accurate…

Computational Physics · Physics 2012-11-22 Andrew D. Baczewski , Nicholas C. Miller , Balasubramaniam Shanker
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