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The development of relativistic exact two-component (X2C) theory is briefly reviewed, with an emphasis on cost-effective treatments of relativistic two-electron contributions by means of model potential (MP) techniques and closely related…

Chemical Physics · Physics 2025-04-29 Xubo Wang , Chaoqun Zhang , Junzi Liu , Lan Cheng

Density functional theory (DFT) calculations of charged molecules and surfaces are critical to applications in electro-catalysis, energy materials and related fields of materials science. DFT implementations such as the Vienna ab-initio…

Over the last two decades, several fast, robust, and high-order accurate methods have been developed for solving the Poisson equation in complicated geometry using potential theory. In this approach, rather than discretizing the partial…

Numerical Analysis · Mathematics 2024-09-19 Fredrik Fryklund , Leslie Greengard , Shidong Jiang , Samuel Potter

We construct a tridiagonal matrix representation for the three dimensions Dirac-Coulomb Hamiltonian that provides for a simple and straightforward relativistic extension of the complex scaling method. Besides the Coulomb interaction,…

Quantum Physics · Physics 2008-11-26 A. D. Alhaidari

Creating accurate, analytic atom--atom potentials for small organic molecules from first principles can be a time-consuming and computationally intensive task, particularly if we also require them to include explicit polarization terms,…

Atomic Physics · Physics 2016-06-02 Alston J. Misquitta , Anthony J. Stone

Fully relativistic calculations are presented for the double $K$-shell photoionization cross section for several neutral medium-$Z$ atoms, from magnesium ($Z = 10$) up to silver ($Z = 47$). The calculations take into account all multipoles…

Atomic Physics · Physics 2015-06-23 V. A. Yerokhin , A. Surzhykov , S. Fritzsche

We have developed an efficient scheme for the calculation of transition properties within the four-component relativistic equation-of-motion coupled-cluster (EOM-CC) method using the expectation value approach. The calculation of transition…

We present a comprehensive theoretical study of the ionization potentials of the MF (M= Ca, Sr, Ba) molecules using the state-of-the-art relativistic coupled cluster approach with single, double, and perturbative triple excitations…

This paper is focused on the double-grid integration with interpolation-projection (DoGIP), which is a novel matrix-free discretisation method of variational formulations introduced for Fourier--Galerkin approximation. Here, it is described…

Numerical Analysis · Mathematics 2019-11-19 Jaroslav Vondřejc

A fully relativistic calculation of the double photoionization of helium-like atoms is presented. The approach is based on the partial-wave representation of the Dirac continuum states and accounts for the retardation in the…

Atomic Physics · Physics 2015-05-30 V. A. Yerokhin , A. Surzhykov

We present a relativistic time-dependent density functional theory (TDDFT) approach for the simulation of resonant inelastic X-ray scattering (RIXS) spectra, based on both a full four-component (4c) Dirac-Coulomb Hamiltonian and a modern…

Chemical Physics · Physics 2026-04-17 Lukas Konecny , Muhammed A. Dada , Daniel R. Nascimento , Michal Repisky

We present a new computational framework for the Galerkin-collocation method for double domain in the context of ADM 3+1 approach in numerical relativity. This work enables us to perform high resolution calculations for initial sets of two…

General Relativity and Quantum Cosmology · Physics 2018-05-24 W. Barreto , P. C. M. Clemente , H. P. de Oliveira , B. Rodriguez-Mueller

We explore the potential of double core hole electron spectroscopy for chemical analysis in terms of x-ray two-photon photoelectron spectroscopy (XTPPS). The creation of deep single and double core vacancies induces significant…

Ionization potentials, excitation energies, transition properties, and hyperfine structure constants of the low-lying $3p^6 3d^{9} \ ^2D_{5/2}$, $3p^6 3d^{9} \ ^2D_{3/2}$, $3p^5 3d^{10} \ ^2P_{3/2}$ and $3p^5 3d^{10} \ ^2P_{1/2}$ atomic…

Atomic Physics · Physics 2021-12-01 Dillip K. Nandy , B. K. Sahoo

A two-dimensional (2D) hydrogen-like atom with a relativistic Dirac electron, placed in a weak, static, uniform magnetic field perpendicular to the atomic plane, is considered. Closed forms of the first- and second-order Zeeman corrections…

Quantum Physics · Physics 2019-01-29 Radosław Szmytkowski

Over the past decade, decision diagrams (DDs) have been used to model and solve integer programming and combinatorial optimization problems. Despite successful performance of DDs in solving various discrete optimization problems, their…

Optimization and Control · Mathematics 2024-03-27 Hosseinali Salemi , Danial Davarnia

We calculate electrostatic potential landscapes for an external probe charge in the presence of a set of metallic islands. Our numerical calculation in three dimensions (3D)uses an efficient grid relaxation technique. The well-known…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 A. Weichselbaum , S. E. Ulloa

In the study of alternative or extended theories of gravity, Dirac's Hamiltonian constraint algorithm is invaluable for enumerating the propagating modes and gauge symmetries. For gravity, this canonical approach is frequently applied as a…

Computational Physics · Physics 2026-01-01 Will Barker

A new relativistic method based on the Dirac equation for calculating fully differential cross sections for ionization in ion-atom collisions is developed. The method is applied to ionization of the atomic hydrogen by antiproton impact, as…

Atomic Physics · Physics 2017-06-07 A. I. Bondarev , Y. S. Kozhedub , I. I. Tupitsyn , V. M. Shabaev , G. Plunien

We propose a parallel algorithm for the numerical solution of a class of second order semi-linear equations coming from stochastic optimal control problems, by means of a dynamic domain decomposition technique. The new method is an…

Numerical Analysis · Mathematics 2016-02-11 Simone Cacace , Maurizio Falcone