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Accurate parameter dependent electro-chemical numerical models for lithium-ion batteries are essential in industrial application. The exact parameters of each battery cell are unknown and a process of estimation is necessary to infer them.…

Statistics Theory · Mathematics 2024-04-25 Andrea Petrocchi , Matthias K. Scharrer , Franz Pichler , Stefan Volkwein

An isothermal porous-electrode model of a discharging lead-acid battery is presented, which includes an extension of concentrated-solution theory that accounts for excluded-volume effects, local pressure variation, and a detailed…

Chemical Physics · Physics 2020-06-05 Valentin Sulzer , S. Jon Chapman , Colin P. Please , David A. Howey , Charles W. Monroe

Understanding battery degradation in electric vehicles (EVs) under real-world conditions remains a critical yet under-explored area of research. Central to this investigation is the challenge of estimating the specific degradation modes in…

Optimization and Control · Mathematics 2024-05-20 Raja Abhishek Appana , Faissal El Idrissi , Prashanth Ramesh , Marcello Canova , Chun Yong Kang , Kimoon Um

Lithium-ion batteries are increasingly being deployed in liberalised electricity systems, where their use is driven by economic optimisation in a specific market context. However, battery degradation depends strongly on operational profile,…

Systems and Control · Electrical Eng. & Systems 2021-03-15 Jorn M. Reniers , Grietus Mulder , David A. Howey

Battery diagnosis, prognosis and health management models play a critical role in the integration of battery systems in energy and mobility fields. However, large-scale deployment of these models is hindered by a myriad of challenges…

Machine Learning · Computer Science 2023-10-17 Nur Banu Altinpulluk , Deniz Altinpulluk , Paritosh Ramanan , Noah Paulson , Feng Qiu , Susan Babinec , Murat Yildirim

A nonequilibrium thermodynamic model is presented for the nonisothermal lithium-ion battery cell. Coupling coefficients, all significant for transport of heat, mass, charge and chemical reaction, were used to model profiles of temperature,…

Chemical Physics · Physics 2024-11-25 Felix Schloms , Øystein Gullbrekken , Signe Kjelstrup

Modeling lithium-ion battery (LIB) degradation offers significant cost savings and enhances the safety and reliability of electric vehicles (EVs) and battery energy storage systems (BESS). Whilst data-driven methods have received great…

Machine Learning · Computer Science 2025-01-22 James Sadler , Rizwaan Mohammed , Michael Castle , Kotub Uddin

A recently suggested reciprocity relation states that the current transport efficiency from the junction to the cell terminal can be determined by differentiating luminescence images with respect to the terminal voltage. The validity of…

Understanding and controlling coupled ionic-polaronic dynamics is crucial for optimizing electrochemical performance in battery materials. However, studying such coupled dynamics remains challenging due to the intricate interplay between…

Materials Science · Physics 2025-07-09 Fengyu Xie , Yuxiang Gao , Ruoyu Wang , Zhicheng Zhong

We consider basic and easily extendible transport formulations for lithium batteries consisting of an anode (Li-foil), a separator (polymer electrolyte), and a composite cathode (composed of electrolyte and intercalation particles). Our…

Applied Physics · Physics 2018-12-06 Jeta Molla , Markus Schmuck

In Li-ion batteries the electrochemical potential drives the redox reactions occurring at the interface between electrolyte and storage material, typically active particles for porous electrodes, allowing Li ions intercalation/extraction…

Applied Physics · Physics 2022-03-15 M. Magri , B. Boz , L. Cabras , A. Salvadori

While the spatial arrangement of individual units is essential for the physical implementation of quantum batteries, geometry-dependent interactions are rarely explicitly incorporated into existing theoretical models. To address this, we…

Quantum Physics · Physics 2026-04-28 Yi-Fan Yang , Shun-Cai Zhao

The reconfiguration of electrical power distribution systems is a crucial optimization problem aimed at minimizing power losses by altering the system topology through the operation of interconnection switches. This problem, typically…

Systems and Control · Electrical Eng. & Systems 2026-05-08 Pablo Cortes , Alejandra Tabares , Fredy Franco , Astrid Xiomara Rodríguez , David Álvarez-Martínez

Effective management and just-in-time maintenance of lithium-ion batteries require the knowledge of unmeasured (internal) variables that need to be estimated. Observers are thus designed for this purpose using a mathematical model of the…

Systems and Control · Electrical Eng. & Systems 2023-04-20 E. Petri , T. Reynaudo , R. Postoyan , D. Astolfi , D. Nesic , S. Rael

Accurate estimation of the internal states of lithium-ion batteries is key towards improving their management for safety, efficiency and longevity purposes. Various approaches exist in the literature in this context, among which designing…

Systems and Control · Electrical Eng. & Systems 2023-08-21 Mira Khalil , Romain Postoyan , Stéphane Raël

Longevity and safety of lithium-ion batteries are facilitated by efficient monitoring and adjustment of the battery operating conditions. Hence, it is crucial to implement fast and accurate algorithms for State of Health (SoH) monitoring on…

Applications · Statistics 2021-11-30 Clara Bertinelli Salucci , Azzeddine Bakdi , Ingrid K. Glad , Erik Vanem , Riccardo De Bin

In this work we analyse the local nonlinear electrochemical impedance spectroscopy (NLEIS) response of a lithium-ion battery and estimate model parameters from measured NLEIS data. The analysis assumes a single-particle model including…

Chemical Physics · Physics 2023-04-24 T. L. Kirk , A. Lewis-Douglas , D. A. Howey , C. P. Please , S. J. Chapman

Accurate monitoring of lithium-ion battery (LIB) degradation is essential, yet it remains challenging due to the complex, nonlinear, and time-varying nature of electrochemical aging processes. Conventional equivalent circuit models (ECMs)…

Systems and Control · Electrical Eng. & Systems 2026-05-05 Khalid Mahmud Labib , Saad Waheed , Bakhtiar Nafis , Shabbir Ahmed

Understanding the evolution of the physicochemical bulk properties during the Li deintercalation (charging) process is critical for optimizing battery cathode materials. In this study, we combine X-ray photoelectron spectroscopy (XPS),…

We investigate the ability of a homogeneous collection of deferrable energy loads to behave as a battery; that is, to absorb and release energy in a controllable fashion up to fixed and predetermined limits on volume, charge rate and…

Systems and Control · Computer Science 2016-11-14 Daria Madjidian , Mardavij Roozbehani , Munther A. Dahleh