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All-solid-state batteries fail not only by bulk transport limits, but by a reactive interface that evolves during cycling. We show that degradation is governed by two coupled processes: interfacial breathing, the cycle-scale oscillation of…

Materials Science · Physics 2026-04-28 Changdeuck Bae

Energy storage is a basic physical process with many applications. When considering this task at the quantum scale, it becomes important to optimise the non-equilibrium dynamics of energy transfer to the storage device or battery. Here, we…

Quantum Physics · Physics 2022-02-02 Mark T. Mitchison , John Goold , Javier Prior

Reliable health assessment of retired lithium-ion batteries is essential for safe and economically viable second-life deployment, yet remains difficult due to sparse measurements, incomplete historical records, heterogeneous chemistries,…

Signal Processing · Electrical Eng. & Systems 2025-12-02 Song Zhang , Ruohan Guo , Xiaohua Ge , Perter Mahon , Weixiang Shen

Lithium-ion batteries are pivotal to technological advancements in transportation, electronics, and clean energy storage. The optimal operation and safety of these batteries require proper and reliable estimation of battery capacities to…

Machine Learning · Computer Science 2024-07-24 Gift Modekwe , Saif Al-Wahaibi , Qiugang Lu

Distributions of potential and lithium content inside lithium ion batteries highly affects their performance and durability. An increased heterogeneity of the lithium distribution is expected in thick electrodes with high energy densities…

By informing accurate performance (e.g., capacity), health state management plays a significant role in safeguarding battery and its powered system. While most current approaches are primarily based on data-driven methods, lacking in-depth…

Signal Processing · Electrical Eng. & Systems 2020-08-13 Yan Qin , Chau Yuen , Stefan Adams

The structure of lithium ion battery components, such as electrodes and separators, are commonly characterised in terms of their porosity and tortuosity. The ratio of these values gives the effective transport of lithium ions in the…

Applied Physics · Physics 2018-06-04 Marie Francine Lagadec , Raphael Zahn , Simon Müller , Vanessa Wood

This paper proposes a fully unsupervised methodology for the reliable extraction of latent variables representing the characteristics of lithium-ion batteries (LIBs) from electrochemical impedance spectroscopy (EIS) data using information…

Signal Processing · Electrical Eng. & Systems 2021-07-14 Seongyoon Kim , Yun Young Choi , Jung-Il Choi

Porous electrodes composed of multiphase active materials are widely used in Li-ion batteries, but their dynamics are poorly understood. Two-phase models are largely empirical, and no models exist for three or more phases. Using a modified…

Chemical Physics · Physics 2014-02-07 Todd R. Ferguson , Martin Z. Bazant

The rapid pace of replacing fossil fuel propelled transport by electric vehicles is critically dependent on high-performing, high energy density and efficient batteries. Optimal and safe use of existing battery cells and development of…

The paper provides a comprehensive battery storage modelling approach, which accounts for operation- and degradation-aware characteristics, i.e., variable efficiency, internal resistance growth, and capacity fade. Based on the available…

Systems and Control · Electrical Eng. & Systems 2022-03-16 T. Sayfutdinov , P. Vorobev

Large-scale grid-connected lithium-ion batteries are increasingly being deployed to support renewable energy roll-out on the power grid. These battery systems consist of thousands of individual cells and various ancillary systems for…

Systems and Control · Electrical Eng. & Systems 2023-04-24 Jorn M. Reniers , David A. Howey

A distributed control architecture is presented that is intended to make a collection of heterogeneous loads appear to the grid operator as a nearly perfect battery. Local control is based on randomized decision rules advocated in prior…

Systems and Control · Computer Science 2019-10-25 Joel Mathias , Ana Bušić , Sean Meyn

We present a continuum model for symmetry-breaking phase transformations in intercalation compounds, based on Ericksen's multi-well energy formulation. The model predicts the nucleation and growth of crystallographic microstructures in…

Materials Science · Physics 2025-05-29 Delin Zhang , Ananya Renuka Balakrishna

Lithium ion batteries have been a central part of consumer electronics for decades. More recently, they have also become critical components in the quickly arising technological fields of electric mobility and intermittent renewable energy…

Computational Physics · Physics 2021-11-15 Chiara Panosetti , Simon B. Anniés , Cristina Grosu , Stefan Seidlmayer , Christoph Scheurer

Mathematical modeling of lithium-ion batteries (LiBs) is a primary challenge in advanced battery management. This paper proposes two new frameworks to integrate physics-based models with machine learning to achieve high-precision modeling…

Computational Engineering, Finance, and Science · Computer Science 2024-08-23 Hao Tu , Scott Moura , Yebin Wang , Huazhen Fang

Further technological advancement of both lithium-ion and emerging battery technologies can be catalyzed by an improved understanding of the chemistry and working mechanisms of the solid electrolyte interphases (SEIs) that form at…

In this article, a novel implementation of a widely used pseudo-two-dimensional (P2D) model for lithium-ion battery simulation is presented with a transmission line circuit structure. This implementation represents an interplay between…

Chemical Physics · Physics 2021-11-03 Zeyang Geng , Siyang Wang , Matthew J. Lacey , Daniel Brandell , Torbjörn Thiringer

As an anode material for lithium-ion batteries, amorphous silicon offers a significantly higher energy density than the graphite anodes currently used. Alloying reactions of lithium and silicon, however, induce large deformation and lead to…

Numerical Analysis · Mathematics 2024-08-07 Raphael Schoof , Johannes Niermann , Alexander Dyck , Thomas Böhlke , Willy Dörfler

To develop a high-density and long-life lithium-ion battery, a technology is needed that allows non-destructive visualization of the spatial distribution of deteriorated parts after cycle test. In the present study, we measured the…

Chemical Physics · Physics 2021-05-26 Shogo Suzuki , Hideaki Okada , Kai Yabumoto , Seiju Matsuda , Yuki Mima , Noriaki Kimura , Kenjiro Kimura
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