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Excitonic insulator is a coherent electronic phase that results from the formation of a macroscopic population of bound particle-hole pairs - excitons. With only a few candidate materials known, the collective excitonic behavior is…

Strongly Correlated Electrons · Physics 2021-05-27 Pavel A. Volkov , Mai Ye , Himanshu Lohani , Irena Feldman , Amit Kanigel , Girsh Blumberg

Excitonic insulators host a condensate of electron-hole pairs at equilibrium, giving rise to collective many-body effects. Although several materials have emerged as excitonic insulator candidates, evidence of long-range coherence is…

We analyze the measured optical conductivity spectra using the density-functional-theory-based electronic structure calculation and density-matrix renormalization group calculation of an effective model. We show that, in contrast to a…

Strongly Correlated Electrons · Physics 2018-06-18 K. Sugimoto , S. Nishimoto , T. Kaneko , Y. Ohta

We investigate an interesting anisotropic van der Waals material, Ta$_{2}$NiSe$_{5}$, using optical spectroscopy. Ta$_{2}$NiSe$_{5}$ has been known as one of the few excitonic insulators proposed over 50 years ago. Ta$_{2}$NiSe$_{5}$ has…

Materials Science · Physics 2018-08-21 Yu-Seong Seo , Man Jin Eom , Jun Sung Kim , Chang-Jong Kang , Byung Il Min , Jungseek Hwang

The layered chalcogenide Ta2NiSe5 has recently attracted much interest as a strong candidate for the long sought excitonic insulator (EI). Since the physical properties of an EI are expected to depend sensitively on the external pressure,…

Strongly Correlated Electrons · Physics 2023-01-31 H. Okamura , T. Mizokawa , K. Miki , Y. Matsui , N. Noguchi , N. Katayama , H. Sawa , M. Nohara , Y. Lu , H. Takagi , Y. Ikemoto , T. Moriwaki

Excitonic insulators are long-sought-after quantum materials predicted to spontaneously open a gap by the Bose condensation of bound electron-hole pairs, namely, excitons, in their ground state. Since the theoretical conjecture, extensive…

The layered chalcogenide Ta$_{2}$NiSe$_{5}$ has been proposed to host an excitonic condensate in its ground state, a phase that could offer a unique platform to study and manipulate many-body states at room temperature. However, identifying…

Strongly Correlated Electrons · Physics 2021-03-30 Hope M. Bretscher , Paolo Andrich , Prachi Telang , Anupam Singh , Luminita Harnaga , Ajay K. Sood , Akshay Rao

We study the electronic phase diagram of the excitonic insulator candidates Ta$_2$Ni(Se$_{1-x}$S$_x$)$_5$ [x=0, ... ,1] using Raman spectroscopy. Critical excitonic fluctuations are observed, that diminish with $x$ and ultimately shift to…

Strongly Correlated Electrons · Physics 2021-12-30 Pavel A. Volkov , Mai Ye , Himanshu Lohani , Irena Feldman , Amit Kanigel , Girsh Blumberg

We utilized high-energy-resolution resonant inelastic X-ray scattering (RIXS) at both the Ta and Ni $L_3$-edges to map out element-specific particle-hole excitations in Ta$_2$NiSe$_5$ across the phase transition. Our results reveal a…

Renew interest in the charge density wave phase of TiSe$_2$ stems from the realization of its unique driving mechanism, the so called excitonic insulator phase. Existing claims are motivated by model calculations of the band structure. In…

Strongly Correlated Electrons · Physics 2024-08-13 Turgut Yilmaz , Anil Rajapitamahuni , Elio Vescovo

Excitonic insulators are electronically-driven phases of matter characterized by the spontaneous condensation of electron-hole pairs. Here we show that La$_3$Cd$_2$As$_6$ undergoes a transition at $T_{0}=278$ K to a highly insulating state…

Using light to manipulate materials into desired states is one of the goals in condensed matter physics, since light control can provide ultrafast and environmentally-friendly photonics devices. However, it is generally difficult to realise…

On cooling through a temperature $T_S$ of around 324 K, Ta$_2$NiSe$_5$ undergoes a transition from a semimetallic state to one with a gapped electronic spectrum which is suspected to be an excitonic insulator. However, at this transition…

Strongly Correlated Electrons · Physics 2025-04-16 Elliott Rosenberg , Joss Ayres-Sims , Andrew Millis , David Cobden , Jiun-Haw Chu

Exciton condensation indicating the spontaneous formation of electron-hole pair can cause the phase transition from a semimetal to an excitonic insulator by gap opening at the Fermi surface. While the idea of this excitonic insulator has…

Materials Science · Physics 2022-08-23 Hsiao-Yi Chen , Takuya Nomoto , Ryotaro Arita

Coulomb attraction between electrons and holes in a narrow-gap semiconductor or a semimetal is predicted to lead to an elusive phase of matter dubbed 'excitonic insulator'. However, direct observation of such electronic instability remains…

Strongly Correlated Electrons · Physics 2021-08-09 Kwangrae Kim , Hoon Kim , Jonghwan Kim , Changil Kwon , Jun Sung Kim , B. J. Kim

TiSe$_2$ is thought to be an insulator with a bandgap of ~0.1eV. It has attracted a much interest because, among of a rich array of unique properties, many have thought TiSe$_2$ is a rare realisation of an excitonic insulator. Below 200 K,…

Materials Science · Physics 2025-06-10 Ross E. Larsen , Dimitar Pashov , Matthew D. Watson , Swagata Acharya , Mark van Schilfgaarde

The excitonic insulator (EI) is an exotic ground state of narrow-gap semiconductors and semimetals arising from spontaneous condensation of electron-hole pairs bound by attractive Coulomb interaction. Despite research on EIs dating back to…

An excitonic insulator (EI) phase is a consequence of collective many-body effects where an optical band gap is formed by the condensation of electron-hole pairs or excitons. We report pressure-dependent optical pump optical probe…

Materials Science · Physics 2024-11-28 Vikas Arora , Victor S Muthu , Arijit Sinha , Luminita Harnagea , U V Waghmare , A K Sood

In this paper, first, we present a general formulation to investigate the ground-state and elementary excitations of an excitonic insulator (EI) in real materials. In addition, we discuss the out-of-equilibrium state induced (albeit…

Strongly Correlated Electrons · Physics 2023-02-03 Efstratios Manousakis

In this study, the optical response to a terahertz pulse was investigated in the transition metal chalcogenide Ta$_2$NiSe$_5$, a candidate excitonic insulator. First, by irradiating a terahertz pulse with a relatively weak electric field…