Related papers: Intermediate-valence behavior in U2Rh2Sb
We study the mixed valence transition ($T$$_{v}$ $\sim$80 K) in EuNi$_{2}$(Si$_{0.2}$Ge$_{0.8}$)$_{2}$ using Eu 3$d-4f$ X-ray absorption spectroscopy (XAS) and resonant photoemission spectroscopy (RESPES). The Eu$^{2+}$ and Eu$^{3+}$ main…
Despite several decades of both experimental and theoretical work the nature of the hidden order transition at THO = 17.5 K in URu2Si2 remains enigmatic. We report here low field DC magnetization as well as AC susceptibility measurements…
It has been proposed that there are two types of superconductivity in CeCu2Si2, mediated by spin fluctuations at ambient pressure, and by critical valence fluctuations around a charge instability at a pressure P_v \simeq 4.5 GPa. We present…
The superconductor Sr4V2O6Fe2As2 with transition temperature at 37.2 K has been fabricated. It has a layered structure with the space group of p4/nmm, and with the lattice constants a = 3.9296Aand c = 15.6732A. The observed large…
The valence state of Yb ions in beta-YbAlB4 and its polymorph alpha-YbAlB4 has been investigated by using X-ray absorption and emission spectroscopy in SPring-8 at temperatures from 2 to 280 K. The observed Yb valence is 2.78 +- 0.01 in…
Bulk superconductivity was discovered in BaRh2P2 (Tc = 1.0 K) and BaIr2P2 (Tc = 2.1 K), which are isostructural to (Ba,K)Fe2As2, indicative of the appearance of superconductivity over a wide variety of layered transition metal pnictides.…
The Ruthenium based perovskites exhibit a wide variety of interesting collective phenomena related to magnetism originating from the Ru 4d electrons. Much remains unknown concerning the nature of magnetic fluctuations and excitations in…
We report muon spin relaxation and inelastic neutron measurements on the Heusler system YbPd$_2$Sn. Localised anisotropic and quasi-elastic Yb magnetic fluctuations are observed below $T = 150$K. Both $\mu$SR and neutron data indicate a…
We have grown the new uranium compound URhIn$_5$ with the tetragonal HoCoGa$_5$-type by the In self flux method. In contrast to the nonmagnetic ground state of the isoelectronic analogue URhGa$_5$, URhIn$_5$ is an antiferromagnet with…
Magnetic susceptibility, heat capacity and electrical resistivity measurements have been carried out on a new ruthenate, La2RuO5 (monoclinic, space group P21/c) which reveal that this compound is a magnetic semiconductor with a high…
We have performed magnetization measurements at high magnetic fields of up to 53 T on single crystals of a uranium heavy-fermion compound U$_2$Zn$_{17}$ grown by the Bridgman method. In the antiferromagnetic state below the N\'{e}el…
We have synthesized a new quaternary borocarbide PrPd$_{2}$B$_{2}$C and measured its magnetization, electrical resistivity and specific heat. The compound crystallizes in the LuNi$_{2}$B$_{2}$C-type tetragonal structure (space group {\it…
Achieving high thermoelectric performance requires efficient manipulation of thermal conductivity and a fundamental understanding of the microscopic mechanisms of phonon transport in crystalline solids. One of the major challenges in…
We measure the resistivity and magnetic susceptibility in the temperature range from 5 K to 600 K for the single crystals $A$Fe$_{2-y}$Se$_2$ ($A$ = K$_{0.8}$, Rb$_{0.8}$, Cs$_{0.8}$, Tl$_{0.5}$K$_{0.3}$ and Tl$_{0.4}$Rb$_{0.4}$). A sharp…
There have been speculations about the need to find a new mechanism to explain the colossal magnetoresistance exhibited by this material, having pyrochlore structure and thus differing structurally and electronically from the manganites. We…
We investigate a two-channel Anderson impurity model with a $5f^1$ magnetic and a $5f^2$ quadrupolar ground doublet, and a $5f^2$ excited triplet. Using the numerical renormalization group method, we find a crossover to a non-Fermi liquid…
We discovered the enhancement of superconducting transition temperature, Tc, in yttrium sesquicarbide system with the maximum Tc of Tc=18K and their superconducting properties were discussed. The crystal structure of Y2C3 is the…
Valence band electronic structure of mixed uranium oxides (UO2, U4O9, U3O7, U3O8, UO3) has been studied by the resonant inelastic X-ray scattering (RIXS) technique at the U M5 edge and by computational methods. We show here that the RIXS…
The pseudo-one dimensional brannerite type compound CoV2O6 has been studied by magnetisation and heat capacity measurements in the temperature range 1.8 < T < 300 K and in applied fields of up to 9 T. Our measurements show an unusual…
Detailed $^{195}$Pt- and $^{171}$Yb nuclear magnetic resonance (NMR) studies on the heterogeneous mixed valence system YbPtGe$_2$ are reported. The temperature dependence of the $^{195}$Pt-NMR shift $^{195}K(T)$ indicates the opening of an…