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The complex absorbing potential (CAP) technique is one of the commonly used Non-Hermitian quantum mechanics approaches for characterizing electronic resonances. CAP combined with various electronic structure methods has shown promising…

Chemical Physics · Physics 2025-03-11 Soubhik Mondal , Ksenia B. Bravaya

We study the Complex Absorbing Potential (CAP) Method in computing quantum resonances of width $c(h) = O(h^N)$, $N\gg1$. We show that up to $h^{-M}\sqrt{c(h)} +\Oh$ error, $M\gg1$, resonances are perturbed eigenvalues of the CAP Hamiltonian…

Mathematical Physics · Physics 2007-05-23 Plamen Stefanov

Complex absorbing potentials (CAPs) are artificial potentials added to electronic Hamiltonians to make the wave function of metastable electronic states square-integrable. This makes electronic-structure theory of resonances comparable to…

Chemical Physics · Physics 2023-12-27 Jerryman A. Gyamfi , Thomas-C. Jagau

Electronic resonances are metastable states that can decay by electron loss. They are ubiquitous across various fields of science, such as chemistry, physics, and biology. However, current theoretical and computational models for resonances…

Chemical Physics · Physics 2025-04-15 Yann Damour , Anthony Scemama , Fábris Kossoski , Pierre-François Loos

Complex absorbing potentials (CAPs) are artificial potentials added to electronic Hamiltonians to make the wavefunction of metastable electronic states square-integrable. This makes the electronic structure problem of electronic resonances…

Chemical Physics · Physics 2022-11-29 Jerryman A. Gyamfi , Thomas -C. Jagau

Based on the complex absorbing potential (CAP) method, a Lorentzian expansion scheme is developed to express the self-energy. The CAP-based Lorentzian expansion of self-energy is employed to solve efficiently the Liouville-von Neumann…

Mesoscale and Nanoscale Physics · Physics 2015-06-22 Hang Xie , Yanho Kwok , Feng Jiang , Xiao Zheng , GuanHua Chen

A computationally efficient Green's function approach is developed to evaluate the optical properties of nanostructures using a GW formalism applied on top of a tight-binding and mean-field Hubbard model. The use of the GW approximation…

Mesoscale and Nanoscale Physics · Physics 2022-12-08 Antoine Honet , Luc Henrard , Vincent Meunier

Electronic resonances are metastable states with finite lifetimes, encountered in processes such as photodetachment, electron transmission, and Auger decay. Resonances appear in Hermitian quantum mechanics as increased density of states in…

Chemical Physics · Physics 2025-11-10 Cansu Utku , Garrette Pauley Paran , Thomas-C. Jagau

We show that the complex absorbing potential (CAP) method for computing scattering resonances applies to the case of exponentially decaying potentials. That means that the eigenvalues of $-\Delta + V - i\epsilon x^2$, $|V(x)|\leq C…

Spectral Theory · Mathematics 2021-03-17 Haoren Xiong

We present a real-space method for first-principles nano-scale electronic transport calculations. We use the non-equilibrium Green's function method with density functional theory and implement absorbing boundary conditions (ABCs, also…

Mesoscale and Nanoscale Physics · Physics 2014-07-29 Baruch Feldman , Tamar Seideman , Oded Hod , Leeor Kronik

Electron transport properties in nanostructures can be modeled, for example, by using the semiclassical Wigner formalism or the quantum mechanical Green's functions formalism. We compare the performance and the results of these methods in…

Mesoscale and Nanoscale Physics · Physics 2009-11-10 Paula Havu , Noora Tuomisto , Riikka Vaananen , Martti J. Puska , Risto M. Nieminen

The cumulant expansion of the Green's function is a computationally efficient beyond-$GW$ approach renowned for its significant enhancement of satellite features in materials. In contrast to the ubiquitous $GW$ approximation of many-body…

Chemical Physics · Physics 2024-02-27 Pierre-François Loos , Antoine Marie , Abdallah Ammar

We consider the cumulant expansion of the PAM employing the hybridization as perturbation (Phys. Rev. B 50, 17933 (1994)), and we obtain formally exact one-electron Green's functions (GF). These GF contain effective cumulants that are as…

Strongly Correlated Electrons · Physics 2010-07-13 M. E. Foglio , T. Lobo , M. S. Figueira

Accurate modeling of the electronic structure of warm dense matter is a challenging problem whose solution would allow a better understanding of material properties like equation of state, opacity, and conductivity, with resulting…

Plasma Physics · Physics 2021-07-14 M. Laraia , C. Hanson , N. R. Shaffer , D. Saumon , D. P. Kilcrease , C. E. Starrett

The $GW$ approximation is a widely used framework for studying correlated materials, but it struggles with certain limitations, such as its inability to explain pseudogap phenomena. To overcome these problems, we propose a systematic…

Strongly Correlated Electrons · Physics 2024-09-26 Hui Li , Yingze Su , Junnian Xiong , Haiqing Lin , Huaqing Huang , Dingping Li

We present the mathematical and numerical theory for evanescent waves in subwavelength band gap materials. We begin in the one-dimensional case, whereby fully explicit formulas for the complex band structure, in terms of the capacitance…

Analysis of PDEs · Mathematics 2024-09-24 Yannick De Bruijn , Erik Orvehed Hiltunen

The conditions for optimal reflection-free complex-absorbing potentials (CAPs) are discussed. It is shown that the CAPs as derived from the smooth-exterior-scaling transformation of the Hamiltonian,[J. Phys. B. 31, 1431 (1998)], serve as…

Quantum Physics · Physics 2009-11-11 Oded Shemer , Daria Brisker , Nimrod Moiseyev

The many-body $GW$ formalism, for the calculation of ionization potentials or electronic affinities, relies on the frequency-dependent dielectric function built from the electronic degrees of freedom. Considering the case of water as a…

Materials Science · Physics 2024-09-04 Ivan Duchemin , David Amblard , Xavier Blase

Green's function theory has emerged as a powerful many-body approach not only in condensed matter physics but also in quantum chemistry in recent years. We have developed a new all-electron implementation of the BSE@GW formalism using…

Chemical Physics · Physics 2024-10-15 Ruiyi Zhou , Yi Yao , Volker Blum , Xinguo Ren , Yosuke Kanai

The Wave Function Matching (WFM) technique has recently been developed for the calculation of electronic transport in quantum two-probe systems. In terms of efficiency it is comparable with the widely used Green's function approach. The WFM…

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