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Coupled electronic and nuclear motions govern chemical reactions, yet disentangling their interplay during bond rupture remains challenging. Here we follow the light-induced fragmentation of Br$_2$ using a coincidence-based multi-messenger…

We present a novel method to measure transient photovoltage at nanointerfaces using ultrafast electron diffraction. In particular, we report our results on the photoinduced electronic excitations and their ensuing relaxations in a…

Materials Science · Physics 2009-11-13 Ryan A. Murdick , Ramani K. Raman , Yoshie Murooka , Chong-Yu Ruan

The development of attosecond technology has enabled the real-time observation of coherent electron motion in atoms, molecules and condensed phases. Experimentally, it is now possible to generate laser pulses of durations of only a few tens…

Chemical Physics · Physics 2017-05-18 David Ayuso

Motivated by recent experiments we analyse the classical dynamics of a hydrogen atom in parallel static and microwave electric fields. Using an appropriate representation and averaging approximations we show that resonant ionisation is…

Quantum Physics · Physics 2009-11-10 D. Richards

We present a combined experimental and theoretical study of the self-diffusion of ammonia on exfoliated graphite. Using neutron time-of-flight spectroscopy we are able to resolve the ultrafast diffusion process of adsorbed ammonia, NH$_3$,…

The dissociation dynamics of the $\tilde{A}$-state of ammonia have been studied using a resonant multiphoton ionisation probe in a photoelectron spectroscopy experiment. The use of a resonant intermediate in the multiphoton ionisation…

Carrier transport in nanodevices plays a crucial role in determining their functionality. In the post-Moore era, the behavior of carriers near surface or interface domains the function of the whole devices. However, the femtosecond dynamics…

Mesoscale and Nanoscale Physics · Physics 2024-03-19 Yangguang Zhong , Shuai Yue , Huawei Liu , Yuexing Xia , Anlian Pan , Shula Chen , Xinfeng Liu

Imaging the structure of molecules in transient excited states remains a challenge due to the extreme requirements for spatial and temporal resolution. Ultrafast electron diffraction from aligned molecules (UEDAM) provides atomic resolution…

Atomic Physics · Physics 2015-10-23 Jie Yang , Joshua Beck , Cornelis J. Uiterwaal , Martin Centurion

We study the breakdown of diffusive hydrodynamics in holographic systems dual to neutral dilatonic black holes with extremal near horizon geometries conformal to AdS$_2\times\,$R$^2$. We find that at low temperatures by tuning the effective…

High Energy Physics - Theory · Physics 2022-01-28 Yan Liu , Xin-Meng Wu

Atmospheric-pressure microdischarges excited by nanosecond high-voltage pulses are investigated in helium-nitrogen mixtures by first-principles particle-based simulations that include VUV resonance radiation transport via tracing photon…

Plasma Physics · Physics 2018-07-04 Zoltan Donko , Satoshi Hamaguchi , Timo Gans

To use a 3D numerical MHD experiment representing magnetic flux emerging into an open field region as a background field for tracing charged particles. The interaction between the two flux systems generates a localised current sheet where…

Solar and Stellar Astrophysics · Physics 2015-05-18 Karl Joakim Rosdahl , Klaus Galsgaard

Time-resolved coincidence imaging of photoelectrons and photoions represents the most complete experimental measurement of ultrafast excited state dynamics, a multi-dimensional measurement for a multi-dimensional problem. Here we present…

Chemical Physics · Physics 2015-01-15 Paul Hockett , Enrico Ripani , Andrew Rytwinski , Albert Stolow

Most photocatalytic and photovoltaic devices operate under broadband, constant illumination. Electron and hole dynamics in these devices, however, are usually measured using ultrafast pulsed lasers in a narrow wavelength range. In this…

Chemical Physics · Physics 2024-04-26 Levi D. Palmer , Wonseok Lee , Chung Li Dong , Ru-Shi Liu , Nianqiang Wu , Scott K. Cushing

We propose an approach to probe coherent spin-state dynamics of molecules using circularly polarized hard x-ray pulses. For the dynamically aligned nitric oxide molecules in a coherent superposition spin-orbit coupled electronic state that…

Optics · Physics 2024-01-02 Xiaoyu Mi , Ming Zhang , Zheng Li

The ultrafast structure dynamics and surface transient electric field, which are concurrently induced by laser excited electrons of an aluminum nanofilm, have been investigated simultaneously by the same transmission electron diffraction…

Materials Science · Physics 2014-07-17 Run-Ze Li , Pengfei Zhu , Long Chen , Jie Chen , Jianming Cao , Zheng-Ming Sheng , Jie Zhang

The time-dependent Schr\"{o}dinger equation for the hydrogen atom and its interaction with coherent intense high-frequency short laser pulses is solved numerically exactly by propagating the single-electron wave packets. Thereby, the…

Atomic Physics · Physics 2013-09-11 Philipp V. Demekhin , David Hochstuhl , Lorenz S. Cederbaum

Ultrafast electron diffraction and time-resolved serial crystallography are the basis of the ongoing revolution in capturing at the atomic level of detail the structural dynamics of molecules. However, most experiments employ the classical…

The dynamics of photo-excited charge carriers, particularly their transport and interactions with defects and interfaces, play an essential role in determining the performance of a wide range of solar and optoelectronic devices. A thorough…

Materials Science · Physics 2017-08-07 Bolin Liao , Ebrahim Najafi

We investigate theoretically charge migration following prompt double ionization of a polyatomic molecule (C$_2$H$_4$BrI) and find that for double ionization, correlation-driven charge migration appears to be particularly prominent, i.e.,…

Chemical Physics · Physics 2016-05-24 Maximilian Hollstein , Robin Santra , Daniela Pfannkuche

Binary mixtures of water with lower alcohols display non-linear phase behaviour upon mixing which are attributed to potential cluster formation at molecular level. Unravelling such elusive structures requires the investigation of…

Soft Condensed Matter · Physics 2023-10-09 Riccardo Morbidini , Robert M. Edkins , Mark Devonport , Gøran Nilsen , Tilo Seydel , Katharina Edkins
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