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We experimentally investigate an optical frequency standard based on the 467 nm (642 THz) electric-octupole reference transition 2S1/2(F=0) -> F7/2(F=3) in a single trapped 171Yb+ ion. The extraordinary features of this transition result…

Atomic Physics · Physics 2012-03-02 N. Huntemann , M. Okhapkin , B. Lipphardt , S. Weyers , Chr. Tamm , E. Peik

We examine energy level-crossings of fine-structure (FS) levels in the heavier highly charged ions (HCIs) with $d^6$ and $d^8$ configurations. From the analysis, we find that some of these HCIs are tailor-made for atomic clocks with quality…

Atomic Physics · Physics 2023-07-28 Yan-mei Yu , B. K. Sahoo

A sharp resonance line that appears in three-photon transitions between the $^{1}S_{0}$ and $^{3}P_{0}$ states of alkaline earth and Yb atoms is proposed as an optical frequency standard. This proposal permits the use of the even isotopes,…

Optics · Physics 2007-05-23 Tao Hong , Claire Cramer , Warren Nagourney , E. N. Fortson

We present a SI-traceable temperature calibration apparatus utilizing optical lattice clocks for precision metrology. The system employs a dual-blackbody radiation shield chamber with independent temperature control, enabling synchronous…

Atomic Physics · Physics 2025-08-20 Jin Cao , Xiaotong Lu , Benquan Lu , Hong Chang

We propose that a nuclear clock based on the Th V ion can surpass the accuracy of clocks built with other thorium ions. The Th$^{4+}$ ion has a rigid closed-shell core with zero total electron angular momentum, suppressing frequency shifts…

Atomic Physics · Physics 2025-08-05 V. A. Dzuba , V. V. Flambaum , E. Peik

We measured the $g$-factor of the excited state $^3\text{P}_1$ in $\text{Ca}^{14+}$ ion to be $g = 1.499032(6)$ with a relative uncertainty of $4\times10^{-6}$. The magnetic field magnitude is derived from the Zeeman splitting of a…

We have developed a broadly-applicable approach that drastically increases the ability to accurately predict properties of complex atoms. We applied it to the case of Ir$^{17+}$, which is of particular interest for the development of novel…

Atomic Physics · Physics 2020-04-29 C. Cheung , M. S. Safronova , S. G. Porsev , M. G. Kozlov , I. I. Tupitsyn , A. I. Bondarev

The frequency comb created by a femtosecond mode-locked laser and a microstructured fiber is used to phase coherently measure the frequencies of both the Hg^+ and Ca optical standards with respect to the SI second as realized at NIST. We…

We report a comprehensive evaluation of all known sources of systematic uncertainty for two independent $^{176}$Lu$^+$ single-ion optical references, finding total systematic uncertainty of $1.1\times10^{-19}$ and $1.4\times10^{-19}$ for…

Atomic Physics · Physics 2025-12-09 K. J. Arnold , M. D. K. Lee , Zhao Qi , Qichen Qin , Zhang Zhao , N. Jayjong , M. D. Barrett

Over a two-year duration, we have compared the frequency of the 199Hg+ 5d106s 2S 1/2 (F=0)<-> 5d9 6s2 2D 5/2 (F=2) electric-quadrupole transition at 282 nm with the frequency of the ground-state hyperfine splitting in neutral 133Cs. These…

We describe experimental investigations on an optical frequency standard based on a laser cooled 171Yb+ ion confined in a radiofrequency Paul trap. The electric-quadrupole transition from the 2S1/2(F=0) ground state to the 2D3/2(F=2) state…

Atomic Physics · Physics 2017-08-23 Chr. Tamm , T. Schneider , E. Peik

Optical atomic clocks using highly-charged ions hold an intriguing promise of metrology at the 19th significant figure. Here we study transitions within the $4f^{12}$ ground-state electronic configuration of highly charged ions. We consider…

Atomic Physics · Physics 2015-06-11 V. A. Dzuba , A. Derevianko , V. V. Flambaum

In order to improve the short-term stability of trapped-ion optical clocks, we are developing a frequency standard based on ${}^{115}$In${}^+$ / ${}^{172}$Yb${}^+$ Coulomb crystals. For this purpose, we have developed scalable segmented…

Atomic Physics · Physics 2016-07-12 J. Keller , T. Burgermeister , D. Kalincev , J. Kiethe , T. E. Mehlstäubler

The highest performance atomic clocks are based on interrogation of ultra-narrow optical transitions. There is now significant interest in developing these systems as a source of GNSS-independent time in deployed, dynamic environments. We…

We report on a frequency measurement of the $(3s^2)^1S_0\to(3s3p)^3P_1$ clock transition of $^{24}$Mg on a thermal atomic beam. The intercombination transition has been referenced to a portable primary Cs frequency standard with the help of…

Iridium ions near $4f$-$5s$ level crossings are the leading candidates for a new type of atomic clocks with a high projected accuracy and a very high sensitivity to the temporal variation of the fine structure constant $\alpha$. To identify…

Atomic Physics · Physics 2015-08-12 U. I. Safronova , V. V. Flambaum , M. S. Safronova

In this letter, we discuss the possibility of non 0-0 atomic lines as the reference transitions to design a new atomic clock. The proposed clock operates in high C-field regime offering an interesting alternative to conventional clock based…

Atomic Physics · Physics 2019-10-24 Chao Li , Fuyu Sun , Jie Liu , Xiaofeng Li , Jie Ma , Guangkun Guo , Dong Hou , Shougang Zhang

The 7.8 eV nuclear isomer transition in 229 Thorium has been suggested as an etalon transition in a new type of optical frequency standard. Here we discuss the construction of a "solid-state nuclear clock" from Thorium nuclei implanted into…

Compact optical clocks with high stability are essential for next-generation frequency standard field applications, from navigation to geodesy, yet existing vapor cell clock systems have remained confined to fractional instabilities over…

We identify laser-accessible transitions in group 16-like highly charged ions as candidates for high-accuracy optical clocks, including S-, Se-, and Te-like systems. For this class of ions, the ground $^{3}P_{J}$ fine structure manifold…

Atomic Physics · Physics 2022-10-06 Saleh O. Allehabi , S. M. Brewer , V. A. Dzuba , V. V. Flambaum , K. Beloy