Optical clocks with accuracy validated at the 19th digit

We report a comprehensive evaluation of all known sources of systematic uncertainty for two independent $^{176}$Lu$^+$ single-ion optical references, finding total systematic uncertainty of $1.1\times10^{-19}$ and $1.4\times10^{-19}$ for the two individual systems and $9.6\times10^{-20}$ for the difference. Through direct comparison via correlation spectroscopy, we demonstrate a relative frequency agreement of $-2.4\pm(5.7)_\mathrm{stat}\pm(1.0)_\mathrm{sys}\times10^{-19}$, where `stat' and `sys' indicate the statistical and systematic uncertainty, respectively. The comparison uncertainty is statistically limited after approximately 200 hours of averaging with a measurement instability of $4.8\times10^{-16}(\tau/\mathrm{s})^{-1/2}$.