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Entropic contributions to the stability of solids are very well understood and the mixing entropy has been used for forming various solids, for instance such as inverse spinels. A particular development was related to high entropy alloys in…

Materials Science · Physics 2019-10-23 David Berardan , Sylvain Franger , Diana Dragoe , Arun Kumar Meena , Nita Dragoe

Temporal variations of Cu(In,Ga)Se$_2$ photovoltaic device properties during light exposure at various temperatures and voltage biases for times up to 100 h were analyzed using the kinetic theory of large lattice relaxations. Open-circuit…

To enhance the activity of photocatalysts for hydrogen production and CO2 conversion, noble metal cocatalysts as electron traps and/or acceptors such as platinum or gold are usually utilized. This study hypothesizes that mixing elements…

Materials Science · Physics 2025-01-17 Jacqueline Hidalgo-Jiménez , Taner Akbay , Xavier Sauvage , Tatsumi Ishihara , Kaveh Edalati

Complex oxides are well known to develop oxygen ordering patterns with well defined periodicities, but their interplay with electronic correlations remains largely unexplored. Here, we report resonant and non-resonant x-ray diffraction data…

Nanometric solid solution alloys are utilized in a broad range of fields, including catalysis, energy storage, medical application, and sensor technology. Unfortunately, the synthesis of these alloys becomes increasingly challenging as the…

Materials Science · Physics 2024-10-18 Yao Hu , Haihui Lan , Bo Hu , Jiaxuan Gong , Donghui Wang , Wen-Da Zhang , Mo Yan , Huicong Xia , Mingde Yao , Mingliang Du

High-entropy alloys (HEAs) combine compositional disorder with exceptional functional tunability, yet their inherently high-density limits use in lightweight systems. Here, we introduce entropy-architected nanowire metamaterials, a class of…

Medium or high-entropy alloys (MEAs-HEAs) and rhenium-based compounds with a non-centrosymmetric (NC) structure have received a lot of attention for offering a fertile soil in search for unconventional superconductivity. Here, five…

High entropy alloys (HEAs) are promising magnetocaloric materials with tunable operating temperature conditions using compositional modifications. Here, we combine experiments and first principles based spin modelling to engineer…

The successful synthesis of high entropy alloy (HEA) nanoparticles, a long-sought goal in materials science, opens a new frontier in materials science with applications across catalysis, electronics, structural alloys, and energetic…

Materials Science · Physics 2021-05-27 Wissam A. Saidi , Waseem Shadid , Götz Veser

High entropy alloys (HEAs) are multi-principal-element alloys designed for tailorable mechanical performance and have been attracting significant engineering interest, yet their fundamental behaviour under extreme dynamic conditions, such…

For the first time, this study shows that distortion in a crystal structure due to magnetic effect is possible in a lattice with extreme chemical disorder. The multicomponent equimolar transition metal oxide (ME TMO), (Co,Cu,Mg,Ni,Zn)O,…

High-entropy alloy (HEA) superconductors have garnered significant attention due to their unique characteristics, such as robust superconductivity under extremely high pressure and irradiation, the cocktail effect, and the enhancement of…

Superconductivity · Physics 2025-04-10 Jiro Kitagawa , Yoshikazu Mizuguchi , Terukazu Nishizaki

X-ray diffraction with synchrotron radiation has been used for the first time to study chemical interaction in the FeO-ZnO system at 4.8 GPa and temperatures up to 1300 K. Above 750 K, the chemical reaction between FeO and ZnO has been…

Materials Science · Physics 2011-02-09 P. S. Sokolov , A. N. Baranov , C. Lathe , V. L. Solozhenko

High-entropy oxides (HEOs) offer exceptional compositional flexibility and structural stability, making them promising materials for energy and catalytic applications. Here, we investigate Sr doping effects on B-site cation oxidation…

With first-principles theoretical analysis of the local structure using Bond Orientational Order parameters and Voronoi partitioning, we establish (a) HCP$\rightarrow$BCC structural transformation in high-entropy alloys (HEAs)…

Materials Science · Physics 2023-06-21 Narendra Kumar , Umesh V. Waghmare

The scarcity of viable electrode and electrolyte materials vastly hinders the advancement of magnesium and calcium batteries. This study utilises solid-state metathetical reactions involving chalcogen- and pnictogen-based honeycomb layered…

Refractory high-entropy alloys (RHEAs) have emerged as promising candidates for extreme high-temperature applications, for example, in next-generation turbines and nuclear reactors. In such applications, atomic diffusion critically governs…

High entropy materials are often entropy stabilized, meaning that the configurational entropy from multiple elements sharing a single lattice site stabilizes the structure. In this work, we study how high-pressure synthesis conditions can…

We synthesized a new high-entropy-alloy-type (HEA-type) superconductor (Fe,Co,Ni,Cu,Ga)Zr2 with a Tc of 2.9 K. The EDX analyses revealed that the actual composition of the transition-metal site (Tr-site) is Tr =…

Superconductivity · Physics 2022-09-22 Md. Riad Kasem , Hiroto Arima , Yoichi Ikeda , Aichi Yamashita , Yoshikazu Mizuguchi

We report a temperature-composition phase diagram for the chemically disordered and CeO2-LA2O3 high entropy oxides (HEOs), where LA denotes equimolar Y, La, Sm, and Pr, delineating stability regions for bixbyite, disordered fluorite, and…