Complex oxides are well known to develop oxygen ordering patterns with well defined periodicities, but their interplay with electronic correlations remains largely unexplored. Here, we report resonant and non-resonant x-ray diffraction data indicating a four-unit-cell periodic superstructure related to oxygen vacancy ordering in La2−xCaxCuO4 films with doping levels from the underdoped (x=0.15) to the extremely overdoped (x=0.50) regime. Whereas the lattice superstructure is temperature independent up to 300 K, a strongly temperature dependent electronic charge density wave (CDW) is observed in the underdoped and slightly overdoped regimes (x≤0.20). The periodicity, in-plane and out-of-plane correlation lengths of the CDW are locked in by the lattice superstructure. Our results highlight the necessity to consider lattice and electronic energetics on equal footing in the high-temperature oxygen-disordered phase to explain oxygen ordering phenomena in complex oxides.
@article{arxiv.2408.06774,
title = {Interplay between electronic and lattice superstructures in La$_{2-x}$Ca$_{x}$CuO$_{4}$},
author = {S. Hameed and Y. Liu and K. S. Rabinovich and G. Kim and P. Wochner and G. Christiani and G. Logvenov and K. Higuchi and N. B. Brookes and E. Weschke and F. Yakhou-Harris and A. V. Boris and B. Keimer and M. Minola},
journal= {arXiv preprint arXiv:2408.06774},
year = {2024}
}