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Low-buckled silicene, germanene, and stanene are group$-IV$ graphene allotropes. They form a honeycomb lattice out of two interpenetrating ($A$ and $B$) triangular sublattices that are vertically separated by a small distance $\Delta_z$.…

Materials Science · Physics 2023-06-02 John M. Davis , Gustavo S. Orozco-Galvan , Salvador Barraza-Lopez

A structurally stable carbon allotrope with plentiful topological properties is predicted by means of first-principles calculations. This novel carbon allotrope possesses the simple space group C2/m, and contains simultaneously sp, sp2 and…

Materials Science · Physics 2019-07-18 Jing-Yang You , Xing-Yu Ma , Zhen Zhang , Kuan-Rong Hao , Qing-Bo Yan , Xian-Lei Sheng , Gang Su

Finding appropriate interatomic potentials which can accurately describe the crystal structure of material is one of important topics in material science. In this paper, several interatomic potentials which comprise of Lennard-Jones (LJ)…

Materials Science · Physics 2018-07-03 Hui Zhang , Zhongwu Liu , Xichun Zhong , Dongling Jiao , Wanqi Qiu

Graphdiyne and graphyne are carbon-based two-dimensional (2D) porous atomic lattices, with outstanding physics and excellent application prospects for advanced technologies, like nanoelectronics and energy storage systems. During the last…

Computational Physics · Physics 2019-02-07 B. Mortazavi , M. Shahrokhi , M. E. Madjet , T. Hussain , X. Zhuang , T. Rabczuk

The discovery of novel carbon allotropes with tailored thermal and mechanical properties is critical for advanced thermal management. However, exploring the vast configurational space of carbon using \textit{ab initio} calculations remains…

Materials Science · Physics 2026-03-11 Yuzhou Hao , Yujie Liu , Xuejie Li , Turab Lookman , Xiangdong Ding , Jun Sun , Zhibin Gao

Van der Waals materials enable the construction of atomically sharp interfaces between compounds with distinct crystal and electronic properties. This is dramatically exploited in moir\'e systems, where a lattice mismatch or twist between…

Interactions between stacked two-dimensional (2D) atomic crystals can radically change their properties, leading to essentially new materials in terms of the electronic structure. Here we show that monolayers placed on an atomically flat…

Diamond-structure materials have been extensively studied for decades, which form the foundation for most semiconductors and their modern day electronic devices. Here, we discover a e$_g$-orbital ($d_{z^2}$,$d_{x^2-y^2}$ ) model within the…

Materials Science · Physics 2020-03-25 Wei Jiang , Huaqing Huang , Feng Liu , Jian-Ping Wang , Tony Low

The ability to construct 2D systems, beyond materials natural formation, enriches the search and control capability of new phenomena. For instance, the synthesis of topological lattices of vacancies on metal surfaces through scanning…

Materials Science · Physics 2020-04-07 F. Crasto de Lima , R. H. Miwa

The energy landscape of carbon is exceedingly complex, hosting diverse and important metastable phases, including diamond, fullerenes, nanotubes and graphene. Searching for structures, especially those with large unit cells, in this…

Materials Science · Physics 2018-11-14 Chaoyu He , Xizhi Shi , S. J. Clark , Jin Li , Chris J. Pickard , Tao Ouyang , Chunxiao Zhang , Chao Tang , Jianxin Zhong

Monte Carlo simulations, supplemented by ab initio calculations, shed light into the energetics and thermodynamic stability of nanostructured amorphous carbon. The interaction of the embedded nanocrystals with the host amorphous matrix is…

Materials Science · Physics 2009-11-11 Maria G. Fyta , Pantelis C. Kelires

A structurally stable crystalline carbon allotrope is predicted by means of the first-principles calculations. This allotrope can be derived by substituting each atom in diamond with a carbon tetrahedron, and possesses the same space group…

Materials Science · Physics 2015-05-28 Xian-Lei Sheng , Qing-Bo Yan , Fei Ye , Qing-Rong Zheng , Gang Su

In this work, we propose a new auxetic (negative Poisson's ratio values) structure, based on a $\gamma$-graphyne structure, here named $A\gamma G$ $structure$. Graphynes are 2D carbon allotropes with phenylic rings connected by acetylenic…

Due to the success achieved by graphene, several 2D carbon-based allotropes were theoretically predicted and experimentally synthesized. We used density functional theory and reactive molecular dynamics simulations to investigate the…

Graphdiynes (GDYs) represent a class of 2D carbon materials based on sp-sp$^2$ hybridization with appealing properties and potential applications. Recent advances have demonstrated the experimental self-assembly of GDYs on metal substrates.…

Quantum confinement endows two-dimensional (2D) layered materials with exceptional physics and novel properties compared to their bulk counterparts. Although certain two- and few-layer configurations of graphene have been realized and…

Graphdiyne, atomically-thin 2D carbon nanostructure based on sp-sp2 hybridization, is an appealing system potentially showing outstanding mechanical and optoelectronic properties. Surface-catalyzed coupling of halogenated sp-carbon-based…

Novel extended networks of C8, Si8 and silicon carbide Si4C4 are proposed based on crystal chemistry rationale and optimized structures to ground state energies and derived physical properties within the density functional theory (DFT). The…

Materials Science · Physics 2022-09-07 Samir F. Matar

We present a comprehensive characterization of Cyclo-graphyne (CGY), an emerging 2D carbon allotrope with a porous structure of sp/sp$^2$-hybridized carbon atoms. Using density functional theory, we systematically investigate its…

Materials Science · Physics 2026-01-26 Jhionathan de Lima , Cristiano Francisco Woellner

Hybrid two-dimensional (2D) materials have attracted increasing interest as platforms for tailoring electronic properties through interfacial design. Very recently, a novel hybrid 2D material termed glaphene, which combines monolayers of 2D…