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The high-temperature phase of Ta$_\mathrm{2}$NiSe$_\mathrm{5}$, a near-zero-gap semiconductor ($E_G$ = 0), is a promising candidate for an excitonic insulator. Given the dome-like evolution expected for an excitonic insulator around $E_G$,…

Realizing an excitonic insulator phase from narrow-gap semiconductors remains challenging, as unambiguous experimental signatures are difficult to establish. Ta$_2$NiSe$_5$ has been widely regarded as a leading candidate, yet the nature of…

Materials Science · Physics 2025-12-11 Keyu Wei , Yixuan Luo , Kenji Watanabe , Takashi Taniguchi , Yanfeng Guo , Xiaoxiang Xi

A new state of matter, an excitonic insulator (EI) state, was predicted to emerge from Bose-Einstein condensation of electron-hole pairs. Some candidate materials were suggested but it has been elusive to confirm its existence. Recent works…

Strongly Correlated Electrons · Physics 2021-05-12 Jin Mo Bok , Jungseek Hwang , Han-Yong Choi

Half a century ago, Mott noted that tuning the carrier density of a semimetal towards zero produces an insulating state in which electrons and holes form bound pairs. It was later argued that such pairing persists even if a semiconducting…

Materials Science · Physics 2017-05-23 Z. Zhu , R. D. McDonald , A. Shekhter , B. J. Ramshaw , K. A. Modic , F. F. Balakirev , N. Harrison

During a band-gap-tuned semimetal-to-semiconductor transition, Coulomb attraction between electrons and holes can cause spontaneously formed excitons near the zero-band-gap point, or the Lifshitz transition point. This has become an…

An excitonic insulator (EI) is a charge-neutral bosonic condensate of spontaneously formed electron-hole pairs. Exotic quantum phenomena such as dissipationless charge neutral transport and huge potential for optoelectronic applications…

Strongly Correlated Electrons · Physics 2025-12-03 Seokjin Bae , Arjun Raghavan , Irena Feldman , Amit Kanigel , Vidya Madhavan

The opening of an energy gap in the electronic structure generally indicates the presence of interactions. In materials with low carrier density and short screening length, long-range Coulomb interaction favors the spontaneous formation of…

We calculate the critical temperature below which an excitonic insulator exists at the pressure-induced semiconductor-semimetal transition. Our approach is based on an effective-mass model for valence and conduction band electrons…

Strongly Correlated Electrons · Physics 2009-11-11 Franz X. Bronold , Holger Fehske

The excitonic insulator is an intriguing electronic phase of quasi-condensed excitons. A prominent candidate is the small bandgap semiconductor Ta2NiSe5, in which excitons are believed to undergo a BEC-like transition. But experimental…

Using the projector-based renormalization method we investigate the formation of the excitonic insulator phase in the two-dimensional (2D) spinless Falicov-Kimball model with dispersive $f$ electrons and address the existence of excitonic…

Strongly Correlated Electrons · Physics 2015-05-27 Van-Nham Phan , Holger Fehske , Klaus W. Becker

We study the texture of the exciton condensate at low temperatures in an independently gated electron-hole bilayer system. A model Hamiltonian is solved in real space within a mean-field approximation. It is found that, with increased…

Strongly Correlated Electrons · Physics 2015-05-14 Jian-Xin Zhu , A. R. Bishop

Excitonic insulators (EI) arise from the formation of bound electron-hole pairs (excitons) in semiconductors and provide a solid-state platform for quantum many-boson physics. Strong exciton-exciton repulsion is expected to stabilize…

The fundamental idea of the excitonic insulator (EI) driven by electron-hole correlations in narrow-gap semiconductors or semimetals was originally proposed in the 1960s, and only theoretical studies had been advanced for a long time.…

Strongly Correlated Electrons · Physics 2024-12-25 Tatsuya Kaneko , Yukinori Ohta

In the framework of the two-band model of a doped semiconductor the self-consistent equations describing the transition into the excitonic insulator state are obtained for the 2D case. It is found that due to the exciton-electron…

Condensed Matter · Physics 2009-10-22 Michael N. Kiselev

In the 1960s, it was proposed that in small indirect band-gap materials, excitons can spontaneously form because the density of carriers is too low to screen the attractive Coulomb interaction between electrons and holes. The result is a…

Materials Science · Physics 2024-05-31 Zhi Li , Muhammad Nadeem , Zengji Yue , David Cortie , Michael Fuhrer , Xiaolin Wang

Excitons are spin integer particles that are predicted to condense into a coherent quantum state at sufficiently low temperature, and exciton condensates can be realized at much higher temperature than condensates of atoms because of strong…

Electron-hole pair excitations in semiconductors have been predicted to be able to give rise to a highly correlated many-body ground state, the excitonic insulator (EI). Under appropriate conditions below a critical temperature (Tc),…

Strongly Correlated Electrons · Physics 2023-01-18 Aidan Delgado , Carolin Dusold , Jingwei Jiang , Adam Cronin , Steven G. Louie , Felix R. Fischer

Excitonic insulators conduct neither electrons nor holes but bound electron-hole pairs, excitons. Unfortunately, it is not possible to inject and detect the electron and hole currents independently within a single semiconducting layer.…

Mesoscale and Nanoscale Physics · Physics 2022-09-30 Maxim Trushin

Excitonic insulators are insulating states formed by the coherent condensation of electron and hole pairs into BCS-like states. Isotropic spatial wave functions are commonly considered for excitonic condensates since the attractive…

Strongly Correlated Electrons · Physics 2019-01-15 Rui Wang , Onur Erten , Baigeng Wang , D. Y. Xing

The influence of phonons on the formation of the excitonic insulator has hardly been analyzed so far. Recent experiments on $\rm Ta_2NiSe_5$, 1$T$-$\rm TiSe_2$, and $\rm TmSe_{0.45}Te_{0.55}$, being candidates for realizing the…

Strongly Correlated Electrons · Physics 2015-06-22 B. Zenker , H. Fehske , H. Beck