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Exciton-polaritons in organic materials are hybrid states that result from the strong interaction of photons and the bound excitons that these materials host. Organic polaritons hold great interest for optoelectronic applications, however…

Few- and single-layer MoS2 host substantial densities of defects. They are thought to influence the doping level, the crystal structure, and the binding of electron-hole pairs. We disentangle the concomitant spectroscopic expression of all…

Optical absorption is one of fundamental light-matter interactions. In most materials, optical absorption is a weak perturbation to the light. In this regime, absorption and emission are irreversible, incoherent processes due to strong…

In this work, we present an atomistic first-principles framework for modeling the low-temperature electronic and transport properties of disordered two-dimensional (2D) materials with randomly distributed point defects (impurities). The…

Mesoscale and Nanoscale Physics · Physics 2020-02-11 Kristen Kaasbjerg

We utilize cavity-enhanced extinction spectroscopy to directly quantify the optical absorption of defects in MoS$_2$ generated by helium ion bombardment. We achieve hyperspectral imaging of specific defect patterns with a detection limit…

Exciton dynamics dictate the evolution of photoexcited carriers in photovoltaic and optoelectronic devices. However, interpreting their experimental signatures is a challenging theoretical problem due to the presence of both electron-phonon…

Associating the presence of atomic vacancies to excited-state transport phenomena in two dimensional semiconductors is of emerging interest, and demands detailed understanding of the involved exciton transitions. Here we study the effect of…

Mesoscale and Nanoscale Physics · Physics 2023-10-05 Daniel Hernangómez-Pérez , Amir Kleiner , Sivan Refaely-Abramson

In transition metal dichalcogenides layers of atomic scale thickness, the electron-hole Coulomb interaction potential is strongly influenced by the sharp discontinuity of the dielectric function across the layer plane. This feature results…

Atomically thin two-dimensional (2D) transition metal dichalcogenides (TMDCs) are attractive materials for next generation nanoscale optoelectronic applications. Understanding nanoscale optical behavior of the edges and grain boundaries of…

Mesoscale and Nanoscale Physics · Physics 2016-10-07 A. E. Yore , K. K. H. Smithe , W. Crumrine , A. Miller , J. A. Tuck , B. Redd , E. Pop , Bin Wang , A. K. M. Newaz

We investigate the excitonic spectrum of MoS$_2$ monolayers and calculate its optical absorption properties over a wide range of energies. Our approach takes into account the anomalous screening in two dimensions and the presence of a…

Mesoscale and Nanoscale Physics · Physics 2018-05-28 Emilia Ridolfi , Caio H. Lewenkopf , Vitor M. Pereira

Optical properties of heterostructures composed of layered 2D materials, such as transition metal dichalcogenides (TMDs) and graphene, are broadly explored. Of particular interest are light-induced energy transfer mechanisms in these…

Materials Science · Physics 2024-09-17 Amir Kleiner , Daniel Hernangómez-Pérez , Sivan Refaely-Abramson

Excitons are vital in the photophysics of materials, especially in low-dimensional systems. The conceptual and quantitative understanding of excitonic effects in nonlinear optical (NLO) processes is more challenging compared to linear ones.…

Materials Science · Physics 2026-02-26 Jiawei Ruan , Y. -H. Chan , Steven G. Louie

The photoluminescence spectrum of a single-layer boron nitride remains elusive, marked by enigmatic satellites that hint at a significant but unidentified exciton-phonon coupling.Here, by employing a first principles approach based on the…

Materials Science · Physics 2024-06-03 Giovanni Marini , Matteo Calandra , Pierluigi Cudazzo

Effects of coupling between an molecular exciton and a surface plasmon (exciton-plasmon coupling) on the luminescence properties of the molecule and the surface plasmons are investigated using nonequilibrium Green's function method.…

Materials Science · Physics 2013-11-12 Kuniyuki Miwa , Mamoru Sakaue , Hideaki Kasai

Achieving high performance in transition-metal-dichalcogenide-based optoelectronic devices is challenging -- the realization of an efficient electrical contacting scheme should not be obtained at the expense of their optical quality. Here…

Mesoscale and Nanoscale Physics · Physics 2025-04-28 Agata Zielińska , Mateusz Dyksik , Alessandro Surrente , Jonathan Eroms , Dieter Weiss , Paulina Płochocka , Mariusz Ciorga

We investigate phase-dependent electronic and excitonic phenomena in monolayer Y2TeO2 MOenes in the 1T and 2H polymorphs using first-principles theory and an effective many-body framework. Phonon spectra and elastic stability criteria…

We investigate an excitonic peak appearing in low-temperature photoluminescence of monolayer transition metal dichalcogenides (TMDCs), which is commonly associated with defects and disorder. First, to uncover the intrinsic origin of…

Mesoscale and Nanoscale Physics · Physics 2020-04-22 Kyrylo Greben , Sonakshi Arora , Moshe G. Harats , Kirill I. Bolotin

Excitons in monolayer transition-metal-dichalcogenides (TMDs) dominate their optical response and exhibit strong light-matter interactions with lifetime-limited emission. While various approaches have been applied to enhance light-exciton…

Temperature influences the performance of two-dimensional materials in optoelectronic devices. Indeed, the optical characterization of these materials is usually realized at room temperature. Nevertheless most {\it ab-initio} studies are…

Mesoscale and Nanoscale Physics · Physics 2016-06-06 Alejandro Molina-Sánchez , Maurizia Palummo , Andrea Marini , Ludger Wirtz

It is well-known that exciton effects are determinant to understand the optical absorption spectrum of low-dimensional materials. However, the role of excitons in nonlinear optical responses has been much less investigated at an…

Mesoscale and Nanoscale Physics · Physics 2024-06-21 J. J. Esteve-Paredes , M. A. García-Blázquez , A. J. Uría-Álvarez , M. Camarasa-Gómez , J. J. Palacios
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