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The ferroelectric nematic phase (NF) is a recently discovered phase of matter in which the orientational order of the conventional nematic liquid crystal state is augmented with polar order. Atomistic simulations suggest that the polar NF…

Soft Condensed Matter · Physics 2023-09-26 Charles Parton-Barr , Helen Gleeson , Richard Mandle

Ferroelectric nematic phase (NF) represents an attractive and foremost field of liquid crystals, combining fluidity with ferroelectricity. NF materials exhibit large polarization values and remarkable non-linear optical properties. We have…

Soft Condensed Matter · Physics 2026-03-06 Martin Cigl , Natalia Podoliak , Dalibor Repček , Pavlo Golub , Marta Lavrič , Vladimíra Novotná

The recent discovery of a new ferroelectric nematic (NF) liquid crystalline phase became of utmost interest for the liquid crystal (LC) and the whole soft and condensed matter fields. Contrary to the previously known ferroelectric LC…

Ferroelectric nematic (NF) liquid crystals combine liquid-like fluidity and orientational order of conventional nematics with macroscopic electric polarization comparable in magnitude to solid state ferroelectric materials. Here, we present…

Soft Condensed Matter · Physics 2025-02-04 Calum J. Gibb , Jordan Hobbs , Richard J. Mandle

We report the smectic $A_F$, a new liquid crystal phase of the ferroelectric nematic realm. The smectic $A_F$ is a phase of small polar, rod-shaped molecules which form two-dimensional fluid layers spaced by approximately the mean molecular…

A material showing a sequence of three ferroelectric liquid crystalline phases below the paraelectric nematic phase has been synthesized and studied. The polar order of molecules appearing due to the dipole-dipole interactions in the NF…

Soft Condensed Matter · Physics 2024-10-16 Grant J. Strachan , Ewa Górecka , Jadwiga Szydłowska , Anna Makal , Damian Pociecha

The combination of large spontaneous polarization and fluidity makes the newly discovered ferroelectric nematic liquid crystalline phase (NF) responsive to electric fields in ways that have no counterpart in other materials. We probe this…

Ferroelectric nematic (NF) phase and related polar liquid-crystalline phases form a new class of strongly polarized yet fluid soft matter. Well-recognized heliconical ferroelectric phases such as NTBF and SmC_P^H exist, but their…

Soft Condensed Matter · Physics 2026-05-01 Hiroya Nishikawa , Dennis Kwaria , Atsuko Nihonyanagi , Koki Sano , Hiroyuki Yoshida , Fumito Araoka

We report the experimental determination of the structure and response to applied electric field of the lower-temperature nematic phase of the previously reported calamitic compound 4-[(4-nitrophenoxy)carbonyl]phenyl2,4-dimethoxybenzoate…

Ferroelectric nematic liquid crystals represent not only interesting fundamental science, but they also hold promise for storage capacitors with high power density or new information display technology having sub-millisecond switching. In…

The ferroelectric nematic phase (N$_{\text{F}}$) has quickly become the most studied system in liquid crystal research. In this work, we investigate the origin of such polar structure by studying a compound for which the N$_{\text{F}}$…

Soft Condensed Matter · Physics 2024-11-14 Aitor Erkoreka , Nerea Sebastián , Alenka Mertelj , Josu Martinez-Perdiguero

We report the properties of two new series of compounds that show the ferroelectric nematic phase in which the length of a terminal chain is varied. The longer the terminal chain, the weaker the dipole-dipole interactions of the molecules…

Recently discovered ferroelectric nematic (NF) liquid crystals are fluids with a polar orientational order. The electric polarization vector can be aligned by an electric field and by surface anchoring. Here, we explore how the polarization…

Soft Condensed Matter · Physics 2026-02-27 Ashish Chandra Das , Sathyanarayana Paladugu , Oleg D. Lavrentovich

Since the recent discoveries, ferroelectric nematics became of upmost interest due to their outstanding ferroelectric properties. In this work, we prepared a series of polar molecules revealing a ferroelectric nematic phase (NF) with a very…

Following the groundbreaking discovery of the ferroelectric nematic liquid crystal phase (NF), a series of closely-related new polar phases have also been found. An especially interesting one is the ferroelectric smectic A phase (SmAF) with…

Soft Condensed Matter · Physics 2024-11-14 Aitor Erkoreka , Minjung Huang , Satoshi Aya , Josu Martinez-Perdiguero

Twist-bend (Ntb) and ferroelectric (NF) nematic liquid crystals exhibit several novel effects and new physical properties. The question of what happens in binary mixtures is interesting as a matter of curiosity and pure science. Here, we…

Soft Condensed Matter · Physics 2023-08-07 Abinash Barthakur , Jakub Karcz , Przemyslaw Kula , Surajit Dhara

Fluid molecular ferroelectrics are a new class of organic materials where ferroelectricity is found in conjunction with 3D fluidity whilst still retaining spontaneous polarization values comparable to their traditional solid state…

Soft Condensed Matter · Physics 2026-02-19 Calum J Gibb , Jordan Hobbs , William C Ogle , Richard J Mandle

Strongly dipolar mesogenic compounds with a chiral center located in a lateral alkyl chain were synthesized, and shown to form the ferroelectric nematic phase. The presence of molecular chirality induced a helical structure in both the N…

The discovery of the ferroelectric nematic phase has brought with it a plethora of new polar liquid crystalline phases. One in particular is the anti-ferroelectric smectic A SmA\textsubscript{AF} phase. In this letter we show via…

Liquid crystal materials exhibiting up to three nematic phases are reported. Dielectric response measurements show that while the lower temperature nematic phase has ferroelectric order and the highest temperature nematic phase is apolar,…

Soft Condensed Matter · Physics 2021-09-07 S. Brown , E. Cruickshank , J. M. D. Storey , C. T. Imrie , D. Pociecha , M. Majewska , A. Makal , E. Gorecka
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