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The recent discovery of ferroelectric nematics-genuine 3D ferroelectric fluids-has underscored the importance of electrostatic interactions in shaping the physical behaviour of soft matter systems. In this paper, we investigate the…

Ferroelectric nematics present properties promising for applications, which strongly depend on the confinement conditions and the presence of defects. In this work, we have observed and analysed textures in the cells with homogeneous…

Soft Condensed Matter · Physics 2024-01-04 Vladimira Novotna , Lubor Lejcek , Natalia Podoliak

The recently discovered heliconical ferroelectric nematic (NTBF) phase is a unique example of spontaneous chiral symmetry breaking in a proper ferroelectric fluid. In this study, we investigate four homologous series of mesogenic compounds,…

Soft Condensed Matter · Physics 2025-08-12 Grant J. Strachan , Ewa Górecka , Damian Pociecha

We have structurally characterized the liquid crystal phase that appears as an intermediate state when a dielectric nematic, having polar disorder of its molecular dipoles, transitions to the almost perfectly polar-ordered ferroelectric…

Non-chiral liquid crystals (LCs) exhibiting ferroelectricity, distinguished by their dynamic responsiveness to external stimuli and high spontaneous polarization, provide renewed impetus for research into this area of soft matter and open…

The recently discovered ferroelectric nematic liquid crystals have been reported to exhibit very large dielectric permittivity values. Here, we report a systematic investigation of the dielectric behavior of a prototypical ferroelectric…

Soft Condensed Matter · Physics 2024-02-05 Aitor Erkoreka , Josu Martinez-Perdiguero , Richard J. Mandle , Alenka Mertelj , Nerea Sebastián

Ferroelectric nematic liquid crystals (NFLCs) are distinguished by their remarkable polarization characteristics and diverse physical phenomena, sparking significant interest and excitement within the scientific community. To date, over 150…

Nematic liquid crystals have been known for more than a century, but it was not until the 60s-70s that, with the development of room temperature nematics, they became widely used in applications. Polar nematic phases have been long-time…

Soft Condensed Matter · Physics 2021-08-17 Richard J. Mandle , Nerea Sebastián , Josu Martinez-Perdiguero , Alenka Mertelj

In soft matter, the polar orientational order of molecules can facilitate the coexistence of structural chirality and ferroelectricity. The ferroelectric nematic (NF) state, exhibited by achiral calamitic molecules with large dipole…

Soft Condensed Matter · Physics 2025-03-13 Hiroya Nishikawa , Yasushi Okumura , Dennis Kwaria , Atsuko Nihonyanagi , Fumito Araoka

The isotropic to ferroelectric nematic liquid transition had been theoretically studied over one hundred years ago, but its experimental studies are rare. Here we present polarizing optical microscopy studies and theoretical considerations…

Ferroelectric nematic phases are a new class of polar fluids in which spontaneous polarization is directly coupled to the orientational order, providing unique opportunities for creating self-organized materils with spatially modulated…

The emergence of ferroelectric mesophases in non-chiral liquid crystal (LCs) has sparked fundamental interest in the molecular mechanisms governing polarity. In this study, we investigate how terminal molecular groups influence the…

Spontaneous electric polarization of solid ferroelectrics follows aligning directions of crystallographic axes. Domains of differently oriented polarization are separated by domain walls (DWs), which are predominantly flat and run along…

Soft Condensed Matter · Physics 2023-03-01 Priyanka Kumari , Bijaya Basnet , Hao Wang , Oleg D. Lavrentovich

We show that stable, freely suspended liquid crystal films can be made from the ferroelectric nematic ($\mathrm{N_F}$) phase and from the recently discovered polar, lamellar $\mathrm{SmZ_A}$ and $\mathrm{SmA_F}$ phases. The $\mathrm{N_F}$…

Herein we report the first examples of reactive mesogenic materials (RMs) which exhibit fluid ferroelectric order based on the recently discovered ferroelectric nematic (NF) phase. We term these materials NF RMs and they provide the first…

Materials Science · Physics 2025-04-25 Stuart R Berrow , Jordan Hobbs , Calum J Gibb

Nematics with a broken polar symmetry is one of the fascinating recent discoveries in the field of soft matter. High spontaneous polarisation and the fluidity of the ferroelectric nematic $N_{\mathrm{F}}$ phase make such materials…

Soft Condensed Matter · Physics 2023-01-05 Evangelia Zavvou , Melanie Klasen-Memmer , Atsutaka Manabe , Matthias Bremer , Alexey Eremin

The recent discovery of nematic liquid crystals with polar order (ferroelectric nematic) has created immense interest. Despite intensive research, several physical properties of this liquid crystal are yet to be investigated and understood.…

Soft Condensed Matter · Physics 2022-11-28 Abinash Barthakur , Jakub Karcz , Przemyslaw Kula , Surajit Dhara

We have carried out a spectroscopic study on a prototype ferroelectric nematic material (RM7343) doped with a non-polar chiral compound. The mixture presents two chiral nematic phases, one conventional (N*) and the other polar (NF*), whose…

Soft Condensed Matter · Physics 2022-06-13 J. Ortega , C. L. Folcia , J. Etxebarria , T. Sierra

We studied dielectric properties of a polar nematic phase (NF) sandwiched between two gold or ITO electrodes, serving as a cell surfaces. In bulk, NF is expected to exhibit a Goldstone mode (phason), because polarization can uniformly…

Polarization flutter, produced by an applied AC electric field drives an equilibrium ferroelectric nematic ($\mathrm{N_F}$) liquid crystal (LC) through a transition into a dissipative active ferroelectric nematic state exhibiting strong…