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Related papers: Orbital Entanglement and The Double $d$-Shell Effe…

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We perform ab initio calculations of the coupling between electrons and small-momentum polar-optical phonons in monolayer transition metal dichalcogenides of the 2H type: MoS2, MoSe2, MoTe2, WS2, and WSe2. The so-called Fr\"ohlich…

Materials Science · Physics 2016-11-07 Thibault Sohier , Matteo Calandra , Francesco Mauri

The low-energy properties of transition metal oxides (TMOs) are governed by the electrons occupying strongly correlated $d$-orbitals that are hybridized with surrounding ligand oxygen $p$ orbitals to varying degrees. Their physics is thus…

Strongly Correlated Electrons · Physics 2025-08-05 Samuel Milner , Steven Johnston , Adrian Feiguin

Oxygen packaging in transition metal oxides determines the metal-oxygen hybridization and electronic occupation at metal orbitals. Strontium vanadate (SrVO$_3$), having a single electron in a $3d$ orbital, is thought to be the simplest…

We compute the electronic structure of two-dimensional (2D) materials decorated with self-assembled organic monolayers using density functional theory. We find that 2D materials are strongly impacted by near-field electrostatic effects…

Materials Science · Physics 2021-09-22 Qunfei Zhou , Bukuru Anaclet , Trevor Steiner , Michele Kotiuga , Pierre Darancet

In recent decades, novel magnetism of $d$- and $f$-electron compounds has been discussed very intensively both in experimental and theoretical research fields of condensed matter physics. It has been recognized that those material groups…

Strongly Correlated Electrons · Physics 2009-11-11 Takashi Hotta

The rapid development of two-dimensional (2D) materials has reshaped modern nanoscience, offering properties that differ fundamentally from their bulk counterparts. As experimental discovery accelerates, the need for reliable computational…

Materials Science · Physics 2025-12-19 Ahsan Javed , Mahvish Shaheen , Muhammad Shahbaz , M. Sufyan Ramzan , Rafi Ullah , Wei Jiang

We study the Ruderman-Kittel-Kasuya-Yosida effective exchange interaction between magnetic impurities embedded on the edges of transition-metal dichalcogenide flakes, using a three-orbital tight-binding model. Electronic states lying midgap…

Mesoscale and Nanoscale Physics · Physics 2016-12-02 Oscar Ávalos-Ovando , Diego Mastrogiuseppe , Sergio E. Ulloa

Strong electronic correlations are often associated with the proximity of a Mott insulating state. In recent years however, it has become increasingly clear that the Hund's rule coupling (intra-atomic exchange) is responsible for strong…

Strongly Correlated Electrons · Physics 2013-03-20 Antoine Georges , Luca de' Medici , Jernej Mravlje

Low-energy instabilities in the hole doped cuprates include, besides short range antiferromagnetic fluctuations and superconductivity, also ubiquitous translational and rotational symmetry breakings. The overwhelming majority of…

Superconductivity · Physics 2015-10-06 Itai Panas

The electronic structure, when restricted to the d-band approximation, is a computational model that is both efficient and useful for describing transition metals. In the absence of considering delocalized sp-states, this approximation…

Materials Science · Physics 2025-08-05 Jacques R. Eone

In this paper a model for $3d$-subsystem of transition $3d$-metals has been proposed and used for calculation of the cohesive energy dependent on $3d$-band filling of particular metal, its bandwidth and effective intra-atomic interaction…

Strongly Correlated Electrons · Physics 2018-04-02 L. Didukh

X-ray absorption spectroscopy is a well established tool for obtaining information about orbital and spin degrees of freedom in transition metal- and rare earth-compounds. For this purpose usually the dipole transitions of the L- (2p to 3d)…

Strongly Correlated Electrons · Physics 2014-02-21 P. Hansmann , M. W. Haverkort , A. Toschi , G. Sangiovanni , F. Rodolakis , J. P. Rueff , M. Marsi , K. Held

We investigate a quarter-filled two-band Hubbard model involving a crystal-field splitting, which lifts the orbital degeneracy as well as an inter-orbital hopping (inter-band hybridization). Both terms are relevant to the realistic…

Strongly Correlated Electrons · Physics 2008-07-28 Alexander I. Poteryaev , Michel Ferrero , Antoine Georges , Olivier Parcollet

Transition metals with their densely confined and strongly coupled valence electrons are key constituents of many materials with unconventional properties, such as high-Tc superconductors, Mott insulators and transition-metal…

Atomic Physics · Physics 2020-01-08 M. Volkov , S. A. Sato , F. Schlaepfer , L. Kasmi , N. Hartmann , M. Lucchini , L. Gallmann , A. Rubio , U. Keller

The search for materials displaying a large magnetoelectric effect has occupied researchers for many decades. The rewards could include not only advanced electronics technologies, but also fundamental insights concerning the dielectric and…

We determine the structure and melting behavior of supported metallic clusters using an ab initio density-functional-based treatment of intracluster interactions and an approximate treatment of the surface as an idealized smooth plane…

Mesoscale and Nanoscale Physics · Physics 2012-10-02 S. A. Blundell , Soumyajyoti Haldar , D. G. Kanhere

The lecture introduces a reader to the relatively young field of physics of strongly interacting and disordered 2D electron system, in particular, to the phenomena of the metallic conduction and the apparent metal-insulator transition in…

Strongly Correlated Electrons · Physics 2014-03-27 V. M. Pudalov

Transition metal dichalcogenides (TMDs) combine interesting optical and spintronic properties in an atomically-thin material, where the light polarization can be used to control the spin and valley degrees-of-freedom for the development of…

Mesoscale and Nanoscale Physics · Physics 2021-03-10 Carmem M. Gilardoni , Freddie Hendriks , Caspar H. van der Wal , Marcos H. D. Guimarães

We present a new non-perturbative model to describe the stopping power by ionization of the $d$-electrons of transition metals. These metals are characterized by the filling of the d-subshell and the promotion of part of the electrons to…

Atomic Physics · Physics 2024-11-21 J. P. Peralta , A. M. P. Mendez , D. M. Mitnik , C. C. Montanari

Interest in the bulk transition metal dichalcogenides for their electronic, photovoltaic, and optical properties has grown and led to their use in many technological applications. We present a systematic investigation of their interlinked…

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