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The statistical mechanical description of small systems staying in thermal equilibrium with an environment can be achieved by means of the Hamiltonian of mean force. In contrast to the reduced density matrix of an open quantum system, or…

Statistical Mechanics · Physics 2020-10-28 Peter Talkner , Peter Hänggi

The nonequilibrium thermodynamics of an open (classical or quantum) system in strong contact with a single heat bath can be conveniently described in terms of the Hamiltonian of mean force. However, the conventional formulation is limited…

Statistical Mechanics · Physics 2020-05-20 Philipp Strasberg , Massimiliano Esposito

Based on the explicit knowledge of a Hamiltonian of mean force, the classical statistical mechanics and equilibrium thermodynamics of open systems in contact with a thermal environment at arbitrary interaction strength can be formulated.…

Statistical Mechanics · Physics 2016-09-14 Peter Talkner , Peter Hänggi

In a recent paper [P. Strasberg and M. Esposito, Phys. Rev. E {\bf 101}, 050101(R) (2020)] an attempt is presented to formulate the nonequilibrium thermodynamics of an open system in terms of the Hamiltonian of mean force. The purpose of…

Statistical Mechanics · Physics 2021-01-04 Peter Talkner , Peter Hänggi

We present a universal thermodynamic framework for quantum systems that may be strongly coupled to thermal environments. Unlike previous approaches, our method enables a clear definition of thermostatic properties while preserving the same…

Quantum Physics · Physics 2026-04-16 Ignacio González , Sagnik Chakraborty , Ángel Rivas

The thermodynamics framework of an interacting quantum gas trapped by an arbitrary external potential is reviewed. We show that for each confining potential, in the thermodynamic limit, there emerge "generalized" volume and pressure…

Statistical Mechanics · Physics 2016-08-14 Nadia Sandoval-Figueroa , Víctor Romero-Rochín

Assuming time-scale separation, a simple and unified theory of thermodynamics and stochastic thermodynamics is constructed for small classical systems strongly interacting with its environment in a controllable fashion. The total…

Statistical Mechanics · Physics 2022-08-16 Mingnan Ding , Zhanchun Tu , Xiangjun Xing

Three different approaches to derive mutual information via thermodynamics are presented where the temperature-dependent energy is given by: (a) $\beta \mathcal{E} = -\ln[P(X,Y)]$, (b) $\beta \mathcal{E} =-\ln[P(Y|X)]$ or (c) $\beta…

Statistical Mechanics · Physics 2010-03-24 Yitzhak Peleg , Hadar Efraim , Ori Shental , Ido Kanter

By solving the exact master equation of open quantum systems, we formulate the quantum thermodynamics from weak to strong couplings. The open quantum systems exchange matters, energies and information with their reservoirs through quantum…

Quantum Physics · Physics 2022-06-07 Wei-Ming Huang , Wei-Min Zhang

We develop the strong coupling quantum thermodynamics based on the solution of the exact master equation. We find that both the Hamiltonian and the temperature must be renormalized due to the system-reservoir couplings. With the…

Quantum Physics · Physics 2020-10-06 Wei-Ming Huang , Wei-Min Zhang

We investigate the thermodynamic behavior of open quantum systems through the Hamiltonian of Mean Force, focusing on two models: a two-qubit system interacting with a thermal bath and a Jaynes-Cummings Model without the rotating wave…

Quantum Physics · Physics 2025-09-03 Neha Pathania , Devvrat Tiwari , Subhashish Banerjee

Based on the observation that the thermodynamic equilibrium free energy of an open quantum system in contact with a thermal environment can be understood as the difference between the free energy of the total system and that of the bare…

Statistical Mechanics · Physics 2009-06-01 Michele Campisi , Peter Talkner , Peter Hänggi

Certain classes of strongly correlated systems promise high thermopower efficiency, but a full understanding of correlation effects on the Seebeck coefficient is lacking. This is partly due to limitations of Boltzmann-type approaches. One…

Strongly Correlated Electrons · Physics 2020-12-15 R. Nourafkan , A. -M. S. Tremblay

The interest in active matter stimulates the need to generalize thermodynamic description and relations to active matter systems, which are intrinsically out of equilibrium. One important example is the Jarzynski relation, which links the…

Statistical Mechanics · Physics 2023-05-31 Grzegorz Szamel

The Hamiltonian of mean force is a widely used concept to describe the modification of the usual canonical Gibbs state for a quantum system whose coupling strength with the thermal bath is non-negligible. Here we perturbatively derive…

Quantum Physics · Physics 2022-10-26 Grigorii Timofeev , Anton Trushechkin

We show that classical thermodynamics has a formulation in terms of Hamilton-Jacobi theory, analogous to mechanics. Even though the thermodynamic variables come in conjugate pairs such as pressure/volume or temperature/entropy, the phase…

High Energy Physics - Theory · Physics 2008-11-26 S. G. Rajeev

Two approaches to describe the thermodynamics of a subsystem that interacts with a thermal bath are considered. Within the first approach, the mean system energy $E_{S}$ is identified with the expectation value of the system Hamiltonian,…

Statistical Mechanics · Physics 2009-07-08 M. F. Gelin , M. Thoss

Thermodynamics is the phenomenological theory of heat and work. Here we analyze to what extent quantum thermodynamic relations are immune to the underlying mathematical formulation of quantum mechanics. As a main result, we show that the…

Quantum Physics · Physics 2016-04-21 Bartłomiej Gardas , Sebastian Deffner , Avadh Saxena

There are problems with defining the thermodynamic limit of systems with long-range interactions; as a result, the thermodynamic behavior of these types of systems is anomalous. In the present work, we review some concepts from both…

Statistical Mechanics · Physics 2009-11-13 L. A. del Pino , P. Troncoso , S. Curilef

We consider a quantum system linearly coupled to a reservoir of harmonic oscillators. For finite coupling strengths, the stationary distribution of the damped system is not of the Gibbs form, in contrast to standard thermodynamics. With the…

Statistical Mechanics · Physics 2013-05-29 Stefanie Hilt , Benedikt Thomas , Eric Lutz
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