Intrinsic Hamiltonian of Mean Force and Strong-Coupling Quantum Thermodynamics
Abstract
We present a universal thermodynamic framework for quantum systems that may be strongly coupled to thermal environments. Unlike previous approaches, our method enables a clear definition of thermostatic properties while preserving the same gauge freedoms as in the standard weak-coupling regime and retaining the von Neumann expression for thermodynamic entropy. Furthermore, it provides a formulation of general first and second laws using only variables accessible through microscopic control of the system, thereby enhancing experimental feasibility. We validate the framework by applying it to a paradigmatic model of strong coupling with a structured bosonic reservoir.
Cite
@article{arxiv.2506.02888,
title = {Intrinsic Hamiltonian of Mean Force and Strong-Coupling Quantum Thermodynamics},
author = {Ignacio González and Sagnik Chakraborty and Ángel Rivas},
journal= {arXiv preprint arXiv:2506.02888},
year = {2026}
}
Comments
RevTex4 File, Color Figures, Minor Errors Corrected, New Nonequilibrium Formalism