English

Stochastic thermodynamics in the strong coupling regime: An unambiguous approach based on coarse-graining

Statistical Mechanics 2017-06-07 v2

Abstract

We consider a classical and possibly driven composite system XYX \otimes Y weakly coupled to a Markovian thermal reservoir RR so that an unambiguous stochastic thermodynamics ensues for XYX \otimes Y. This setup can be equivalently seen as a system XX strongly coupled to a non-Markovian reservoir YRY \otimes R. We demonstrate that only in the limit where the dynamics of YY is much faster then XX, our unambiguous expressions for thermodynamic quantities such as heat, entropy or internal energy, are equivalent to the strong coupling expressions recently obtained in the literature using the Hamiltonian of mean force. By doing so, we also significantly extend these results by formulating them at the level of instantaneous rates and by allowing for time-dependent couplings between XX and its environment. Away from the limit where YY evolves much faster than XX, previous approaches fail to reproduce the correct results from the original unambiguous formulation, as we illustrate numerically for an underdamped Brownian particle coupled strongly to a non-Markovian reservoir.

Keywords

Cite

@article{arxiv.1703.05098,
  title  = {Stochastic thermodynamics in the strong coupling regime: An unambiguous approach based on coarse-graining},
  author = {Philipp Strasberg and Massimiliano Esposito},
  journal= {arXiv preprint arXiv:1703.05098},
  year   = {2017}
}

Comments

10 pages, 2 figures; slightly improved version: Eqs. (63), (64) are new, better comparison with the literature; accepted in Phys. Rev. E