Stochastic thermodynamics in the strong coupling regime: An unambiguous approach based on coarse-graining
Abstract
We consider a classical and possibly driven composite system weakly coupled to a Markovian thermal reservoir so that an unambiguous stochastic thermodynamics ensues for . This setup can be equivalently seen as a system strongly coupled to a non-Markovian reservoir . We demonstrate that only in the limit where the dynamics of is much faster then , our unambiguous expressions for thermodynamic quantities such as heat, entropy or internal energy, are equivalent to the strong coupling expressions recently obtained in the literature using the Hamiltonian of mean force. By doing so, we also significantly extend these results by formulating them at the level of instantaneous rates and by allowing for time-dependent couplings between and its environment. Away from the limit where evolves much faster than , previous approaches fail to reproduce the correct results from the original unambiguous formulation, as we illustrate numerically for an underdamped Brownian particle coupled strongly to a non-Markovian reservoir.
Keywords
Cite
@article{arxiv.1703.05098,
title = {Stochastic thermodynamics in the strong coupling regime: An unambiguous approach based on coarse-graining},
author = {Philipp Strasberg and Massimiliano Esposito},
journal= {arXiv preprint arXiv:1703.05098},
year = {2017}
}
Comments
10 pages, 2 figures; slightly improved version: Eqs. (63), (64) are new, better comparison with the literature; accepted in Phys. Rev. E