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Quantum systems used for metrology can offer enhanced precision over their classical counterparts. The design of quantum sensors can be optimized by maximizing the quantum Fisher information (QFI), which characterizes the precision of…

Quantum Physics · Physics 2025-08-26 George Mihailescu , Anthony Kiely , Andrew K. Mitchell

Hybrid quantum-classical algorithms have begun to leverage quantum devices to efficiently represent many-electron wavefunctions, enabling early demonstrations of molecular simulations on real hardware. A key prerequisite for scalable…

Quantum Physics · Physics 2026-04-28 Noah Garrett , Michael Rose , David A. Mazziotti

Estimating the ground-state energy of a quantum system is one of the most promising applications for quantum algorithms. Here we propose a variational quantum eigensolver (VQE) \emph{Ansatz} for finding ground state configuration…

Quantum Physics · Physics 2026-02-10 Koray Aydoğan , Anna R. Spak , Kade Head-Marsden , Anthony W. Schlimgen

The quantum mechanical transition amplitudes are calculated perturbatively on the basis of the stochastic quantization method of Parisi and Wu. It is shown that the stochastic scheme reproduces the ordinary result for the amplitude and…

High Energy Physics - Theory · Physics 2007-05-23 Kazuya Yuasa , Hiromichi Nakazato

Quantum Variational Circuits (QVCs) are often claimed as one of the most potent uses of both near term and long term quantum hardware. The standard approaches to optimizing these circuits rely on a classical system to compute the new…

Quantum Physics · Physics 2022-02-11 Owen Lockwood

The study and prediction of chemical reactivity is one of the most important application areas of molecular quantum chemistry. Large-scale, fully error-tolerant quantum computers could provide exact or near-exact solutions to the underlying…

Quantum Physics · Physics 2019-09-12 Michael Kühn , Sebastian Zanker , Peter Deglmann , Michael Marthaler , Horst Weiß

The full design of relevant systems for quantum applications, ranging from quantum simulation to sensing, is presented using a combination of atomistic methods. A prototypical system features a two-dimensional ordered distribution of spins…

Currently available noisy intermediate-scale quantum (NISQ) devices are limited by the number of qubits that can be used for quantum chemistry calculations on molecules. We show herein that the number of qubits required for simulations on a…

Quantum computing opens up new possibilities for the simulation of many-body nuclear systems. As the number of particles in a many-body system increases, the size of the space if the associated Hamiltonian increases exponentially. This…

Quantum Physics · Physics 2022-09-19 Isaac Hobday , Paul Stevenson , James Benstead

Quantum computing is viewed as a promising technology because of its potential for polynomial growth in complexity, in contrast to the exponential growth observed in its classical counterparts. In the current Noisy Intermediate-Scale…

Chemical Physics · Physics 2026-01-13 Maitreyee Sarkar , Lisa Roy , Akash Gutal , Atul Kumar , Manikandan Paranjothy

Perturbation theory (PT) might be one of the most powerful and fruitful tools for both physicists and chemists, which evoked an explosion of applications with the blooming of atomic and subatomic physics. Even though PT is well-used today,…

Quantum Physics · Physics 2023-05-16 Junxu Li , Barbara A. Jones , Sabre Kais

The computational cost of exact methods for quantum simulation using classical computers grows exponentially with system size. As a consequence, these techniques can only be applied to small systems. By contrast, we demonstrate that quantum…

Quantum Physics · Physics 2008-12-17 Ivan Kassal , Stephen P. Jordan , Peter J. Love , Masoud Mohseni , Alán Aspuru-Guzik

In this work, we present the integration of Qiskit Nature's quantum chemistry solvers into the Atomic Simulation Environment (ASE), enabling hybrid quantum-classical workflows for force-driven atomistic simulations. This coupling allows the…

Quantum Physics · Physics 2026-02-04 Wilke Dononelli

We present a novel method for determining gradients of parameterised quantum circuits (PQCs) in hybrid quantum-classical machine learning models by applying the multivariate version of the simultaneous perturbation stochastic approximation…

Quantum Physics · Physics 2022-11-28 Thomas Hoffmann , Douglas Brown

We investigate the quantum equation of motion (qEOM), a hybrid quantum-classical algorithm for computing excitation properties of a fermionic many-body system, with a particular emphasis on the strong-coupling regime. The method is designed…

Nuclear Theory · Physics 2023-09-20 Manqoba Q. Hlatshwayo , John Novak , Elena Litvinova

Quantum sensing can enhance imaging performance by reducing measurement noise below the classical limit, thereby improving the signal-to-noise ratio (SNR) of acquired data. In conventional quantum imaging schemes, squeezing is applied…

Quantum Physics · Physics 2026-04-21 Haowei Shi , Visuttha Manthamkarn , Christopher M. Jones , Zheshen Zhang , Quntao Zhuang

The quantum computing devices of today have tens to hundreds of qubits that are highly susceptible to noise due to unwanted interactions with their environment. The theory of quantum error correction provides a scheme by which the effects…

Quantum Physics · Physics 2022-08-02 Akshaya Jayashankar , Prabha Mandayam

Hybrid quantum-classical approaches offer potential solutions to quantum chemistry problems, yet they often manifest as constrained optimization problems. Here, we explore the interconnection between constrained optimization and generalized…

Quantum Physics · Physics 2025-03-27 Muqing Zheng , Bo Peng , Ang Li , Xiu Yang , Karol Kowalski

In this study, we extend the multicomponent heat-bath configuration interaction (HCI) method to excited states. Previous multicomponent HCI studies have been performed using only the variational stage of the HCI algorithm as they have…

Chemical Physics · Physics 2022-01-12 Naresh Alaal , Kurt R. Brorsen

Quantum computation promises to advance a wide range of computational tasks. However, current quantum hardware suffers from noise and is too small for error correction. Thus, accurately utilizing noisy quantum computers strongly relies on…

Optimization and Control · Mathematics 2024-12-16 Friedrich Wagner , Daniel J. Egger , Frauke Liers