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Quantum Selected Configuration Interaction (QSCI) and an extended protocol known as Sample-based Quantum Diagonalization (SQD) have emerged as promising algorithms to solve the electronic Schr\"odinger equation with noisy quantum computers.…

Quantum Physics · Physics 2025-08-26 Don Danilov , Javier Robledo-Moreno , Kevin J. Sung , Mario Motta , James Shee

Amidst the rapid advancements in experimental technology, noise-intermediate-scale quantum (NISQ) devices have become increasingly programmable, offering versatile opportunities to leverage quantum computational advantage. Here we explore…

Quantum Physics · Physics 2023-04-03 Wei Xia , Jie Zou , Xingze Qiu , Feng Chen , Bing Zhu , Chunhe Li , Dong-Ling Deng , Xiaopeng Li

Present atomic theory provides accurate and reliable results for atoms with a small number of valence electrons. However, most current methods of calculations fail when the number of valence electrons exceeds four or five. This means that…

Atomic Physics · Physics 2024-07-10 M. G. Kozlov , I. I. Tupitsyn , A. I. Bondarev , D. V. Mironova

We address the use of simple quantum probes for the spectral characterization of classical noisy environments. In our scheme a qubit interacts with a classical stochastic field describing environmental noise and is then measured after a…

Quantum Physics · Physics 2014-03-21 Claudia Benedetti , Fabrizio Buscemi , Paolo Bordone , Matteo G. A. Paris

The recent development of the density matrix renormalization group (DMRG) method in multireference quantum chemistry makes it practical to evaluate static correlation in a large active space, while dynamic correlation provides a critical…

Strongly Correlated Electrons · Physics 2020-08-20 Zhen Luo , Yingjin Ma , Xicun Wang , Haibo Ma

One of the primary challenges in quantum chemistry is the accurate modeling of strong electron correlation. While multireference methods effectively capture such correlation, their steep scaling with system size prohibits their application…

State preparation for quantum algorithms is crucial for achieving high accuracy in quantum chemistry and competing with classical algorithms. The localized active space unitary coupled cluster (LAS-UCC) algorithm iteratively loads a…

Quantum Physics · Physics 2023-06-08 Ruhee D'Cunha , Matthew Otten , Matthew R. Hermes , Laura Gagliardi , Stephen K. Gray

Quantum machine learning (QML) offers a promising avenue for advancing representation learning in complex signal domains. In this study, we investigate the use of parameterised quantum circuits (PQCs) for speech emotion recognition (SER) a…

Machine Learning · Computer Science 2025-06-26 Thejan Rajapakshe , Rajib Rana , Farina Riaz , Sara Khalifa , Björn W. Schuller

Machine learning has been increasingly utilized in the field of biomedical research to accelerate the drug discovery process. In recent years, the emergence of quantum computing has been followed by extensive exploration of quantum machine…

The development of tailored materials for specific applications is an active field of research in chemistry, material science and drug discovery. The number of possible molecules that can be obtained from a set of atomic species grow…

The multi-configurational self-consistent field theory is considered the standard starting point for almost all multireference approaches required for strongly-correlated molecular problems. The limitation of the approach is generally given…

Chemical Physics · Physics 2015-10-14 Robert E. Thomas , Qiming Sun , Ali Alavi , George H. Booth

We investigate configuration-interaction (CI) calculations on a basis of molecular orbitals generated by preliminary density-functional theory (DFT) calculations. We use this CI/DFT framework to improve the modeling of core-excited states…

Chemical Physics · Physics 2025-09-11 Giorgio Visentin , Francois Mauger

Quantum chemistry provides a target for quantum simulation of considerable scientific interest and industrial importance. The majority of algorithms to date have been based on a second-quantized representation of the electronic structure…

Quantum Physics · Physics 2013-12-17 Borzu Toloui , Peter J. Love

Quantum reservoir computing (QRC) is an emerging paradigm for harnessing the natural dynamics of quantum systems as computational resources that can be used for temporal machine learning tasks. In the current setup, QRC is difficult to deal…

Quantum Physics · Physics 2020-10-21 Quoc Hoan Tran , Kohei Nakajima

Quantum computers hold promise to circumvent the limitations of conventional computing for difficult molecular problems. However, the accumulation of quantum logic errors on real devices represents a major challenge, particularly in the…

Chemical Physics · Physics 2021-11-17 Michael A. Jones , Harish J. Vallury , Charles D. Hill , Lloyd C. L. Hollenberg

Quantum sensors driven into the quantum chaotic regime can have dramatically enhanced sensitivity, which, however, depends intricately on the details of the underlying classical phase space. Here, we develop an accurate semiclassical…

Quantum Physics · Physics 2026-01-26 Mahdi RouhbakhshNabati , Daniel Braun , Henning Schomerus

When noisy intermediate scalable quantum (NISQ) devices are applied in information processing, all of the stages through preparation, manipulation, and measurement of multipartite qubit states contain various types of noise that are…

Quantum Physics · Physics 2021-12-16 Hyeokjea Kwon , Joonwoo Bae

Classical optimizers play a crucial role in determining the accuracy and convergence of variational quantum algorithms. In literature, many optimizers, each having its own architecture, have been employed expediently for different…

Quantum Physics · Physics 2023-08-04 Harshdeep Singh , Sabyashachi Mishra , Sonjoy Majumder

This overview will give a glimpse into chemical design principles for exploiting quantum interference (QI) effects in molecular-scale devices. Direct observation of room temperature QI in single-molecule junctions has stimulated growing…

Mesoscale and Nanoscale Physics · Physics 2017-12-19 Colin J. Lambert , Shi-Xia Liu

Quantum secret sharing (QSS) enables secure distribution of information among multiple parties but remains vulnerable to noise. We analyze the effects of bit-flip, phase-flip, and amplitude damping noise on the multiparty QSS for classical…

Quantum Physics · Physics 2025-04-24 Nirupam Basak , Goutam Paul
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