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The dynamics of inertial particles in Rayleigh-B\'{e}nard convection, where both particles and fluid exhibit thermal expansion, is studied using direct numerical simulations (DNS). We consider the effect of particles with a thermal…

Soft Condensed Matter · Physics 2019-07-02 Kim M. J. Alards , Rudie P. J. Kunnen , Herman J. H. Clercx , Federico Toschi

The trace anomaly of dense matter, $\Delta \equiv 1/3 - P/\varepsilon$, defined through the ratio $w \equiv P/\varepsilon$ of pressure $P$ to energy density $\varepsilon$, quantifies deviations from conformal symmetry and provides a…

Nuclear Theory · Physics 2026-05-18 Bao-An Li

We use first-principles theory to show that the ingredients assumed to be essential to the occurrence of negative thermal expansion (NTE) -- rigid unit phonon modes with negative Gr\"{u}neisen parameters -- are neither sufficient nor…

Materials Science · Physics 2019-01-30 Ethan T. Ritz , Nicole A. Benedek

We explore the structural properties of anomalous fluids confined in a nanopore using Molecular Dynamics simulations. The fluid is modeled by core-softened (CS) potentials that have a repulsive shoulder and an attractive well at a further…

Soft Condensed Matter · Physics 2014-10-22 Leandro B. Krott , José Rafael Bordin , Marcia Barbosa

Using molecular dynamics simulations we investigate the structure of a system of particles interacting through a continuous core-softened interparticle potential. We found for the translational order parameter, t, a local maximum at a…

Soft Condensed Matter · Physics 2007-11-28 Alan B. de Oliveira , Paulo A. Netz , Thiago Colla , Marcia C. Barbosa

Pressure and temperature dependence of the negative thermal expansion in Zn(CN)$_2$ is fully investigated using molecular dynamics simulations with a built potential model. The advantage of this study allows us to reproduce all the exotic…

Materials Science · Physics 2014-07-02 Hong Fang , Martin T. Dove , Leila H. N. Rimmer , Alston J. Misquitta

We have investigated temperature dependence of the lattice parameters and the unit cell volume of ZnF$_2$ by neutron diffraction and have discovered negative thermal expansion (NTE) at low temperature. To understand why this simple compound…

Materials Science · Physics 2012-07-03 Tapan Chatterji , Mohamed Zbiri , Thomas C. Hansen

In this study, we report for the first time the occurrence and investigation of the negative thermal expansion (NTE) effect in rare-earth pyrochlores. It is found that the NTE originates from the migration of oxygen anions from 48f sites to…

Materials Science · Physics 2025-07-24 Yuxuan Wang , Guoqiang Lan , Jun Song

We investigate the thermal expansion and superconducting properties of a CuAl2-type (tetragonal) superconductor CoZr2 under high pressures. We perform high-pressure synchrotron X-ray diffraction in a pressure range of 2.9 GPa < P < 10.4 GPa…

We use variable-temperature (150--300\,K) single-crystal X-ray diffraction to re-examine the interplay between structure and dynamics in the ambient phase of the isotropic negative thermal expansion (NTE) material Cd(CN)$_2$. We find strong…

Materials Science · Physics 2015-06-05 Vanessa E. Fairbank , Amber L. Thompson , Richard I. Cooper , Andrew L. Goodwin

We have investigated the anisotropic thermal expansion of graphite using ab-initio calculation of lattice dynamics and anharmonicity of the phonons, which reveal that the negative thermal expansion (NTE) in the a-b plane below 600 K and…

Materials Science · Physics 2021-05-05 Ranjan Mittal , Mayanak K. Gupta , Baltej Singh , S. K. Mishra , Samrath L. Chaplot

The low-temperature normal-state specific heat and resistivity curves of various nonmagnetic intermetallic compounds manifest an anomalous thermal evolution. Such an anomaly is exhibited as a break in the slope of the linearized C/T versus…

Materials Science · Physics 2011-11-15 M. ElMassalami

The thermodynamic liquid-state anomalies and associated structural changes of the Stillinger-Weber family of liquids are mapped out as a function of the degree of tetrahedrality of the interaction potential, focusing in particular on…

Soft Condensed Matter · Physics 2011-09-09 Waldemar Hujo , B. Shadrack Jabes , Varun K. Rana , Charusita Chakravarty , Valeria Molinero

Molecular dynamic simulations for systems with $D=2,3$ Lennard-Jones-like interactions are studied. In the model, we assume that, at long distances, the two-body attractive potential decays as $r^{-\alpha}$. Thermodynamic extensivity…

Condensed Matter · Physics 2009-10-31 Sergio Curilef , Constantino Tsallis

Origin and composition dependence of the anisotropic thermomechanical properties are elucidated for Ba1-xSrxZn2Si2O7 (BZS) solid solutions. The high-temperature phase of BZS shows negative thermal expansion (NTE) along one crystallographic…

We investigated the equilibrium properties of a one-dimensional system of classical particles which interact in pairs through a bounded repulsive potential with a Gaussian shape. Notwithstanding the absence of a proper fluid-solid phase…

Soft Condensed Matter · Physics 2012-01-11 Cristina Speranza , Santi Prestipino , Paolo V. Giaquinta

We use a one-dimensional (1d) core-softened potential to develop a physical picture for some of the anomalies present in liquid water. The core-softened potential mimics the effect of hydrogen bonding. The interest in the 1d system stems…

Soft Condensed Matter · Physics 2009-10-31 M. Reza Sadr-Lahijany , Antonio Scala , Sergey~V. Buldyrev , H. Eugene Stanley

ZnNi(CN)$_4$ is a 3D framework material consisting of two interpenetrating PtS-type networks in which tetrahedral [ZnN$_4$] units are linked by square-planar [NiC$_4$] units. Both the parent compounds, cubic Zn(CN)$_2$ and layered…

We investigate the equation of state, diffusion coefficient, and structural order of a family of spherically-symmetric potentials consisting of a hard core and a linear repulsive ramp. This generic potential has two characteristic length…

Soft Condensed Matter · Physics 2007-05-23 Zhenyu Yan , Sergey V. Buldyrev , Nicolas Giovambattista , Pablo G. Debenedetti , H. Eugene Stanley

Al(110) has been studied for temperatures up to 900 K via ensemble density-functional molecular dynamics. The strong anharmonicity displayed by this surface results in a negative coefficient of thermal expansion, where the first interlayer…

Materials Science · Physics 2009-10-31 Nicola Marzari , David Vanderbilt , Alessandro De Vita , M. C. Payne