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In contrast to the original Kohn-Sham (KS) formalism, we propose a density functional theory (DFT) with fractional orbital occupations for the study of ground states of many-electron systems, wherein strong static correlation is shown to be…

Chemical Physics · Physics 2015-06-03 Jeng-Da Chai

We have formulated and implemented a fully charge-self-consistent density functional theory plus dynamical mean field theory methodology which enables an efficient calculation of the total energy of realistic correlated electron systems.…

Strongly Correlated Electrons · Physics 2015-06-22 Hyowon Park , Andrew J. Millis , Chris A. Marianetti

These brief comments on the article in Phys. Rev. B 93, 155116 (2016), address an inadvertent misrepresentation of the capabilities of density functional theory (DFT) and of its local density approximation (LDA) in describing electronic and…

Materials Science · Physics 2016-10-18 Diola Bagayoko , Yacouba Issa Diakité , Chinedu E. Ekuma , Lashounda Franklin

Multi-center transition metal complexes (MCTMs) with magnetically interacting ions have been proposed as components for information processing devices and storage units. For any practical application of MCTMs as magnetic units, it is…

Chemical Physics · Physics 2023-04-03 Henry C. Fitzhugh , James W. Furness , Mark R. Pederson , Juan E. Peralta , Jianwei Sun

The systematic underestimation of band gaps is one of the most fundamental challenges in semilocal density functional theory (DFT). In addition to hindering the application of DFT to predicting electronic properties, the band gap problem is…

Chemical Physics · Physics 2024-08-27 Kyle Bystrom , Stefano Falletta , Boris Kozinsky

The description of realistic strongly correlated systems has recently advanced through the combination of density functional theory in the local density approximation (LDA) and dynamical mean field theory (DMFT). This LDA+DMFT method is…

Strongly Correlated Electrons · Physics 2009-11-13 B. Amadon , F. Lechermann , A. Georges , F. Jollet , T. O. Wehling , A. I. Lichtenstein

The sensitivity of Density Functional Theory plus Dynamical Mean Field Theory calculations to different constructions of the correlated orbitals is investigated via a detailed comparison of results obtained for the quantum material…

Strongly Correlated Electrons · Physics 2021-05-12 Jonathan Karp , Alexander Hampel , Andrew J. Millis

Density functional theory (DFT) is one of the primary approaches to get a solution to the many-body Schrodinger equation. The essential part of the DFT theory is the exchange-correlation (XC) functional, which can not be obtained in…

Computational Physics · Physics 2021-12-10 Alexander Ryabov , Petr Zhilyaev

Heterogeneous interfaces are central to many energy-related applications in the nanoscale. From the first-principles electronic structure perspective, one of the outstanding problems is accurately and efficiently calculating how the…

Materials Science · Physics 2023-08-29 Zhen-Fei Liu

High-throughput DFT calculations are key to screening existing/novel materials, sampling potential energy surfaces, and generating quantum mechanical data for machine learning. By including a fraction of exact exchange (EXX), hybrid…

The classical-map hyper-netted-chain (CHNC) scheme, developed for treating fermion fluids at strong coupling and at finite temperatures, is applied to electron-electron and electron-hole double quantum wells. The pair distribution functions…

Mesoscale and Nanoscale Physics · Physics 2019-01-30 M. W. C. Dharma-wardana , D. Neilson , F. M. Peeters

We present the data-driven coupled-cluster deep network (DDCCNet), a family of multitask, physics-enhanced deep learning architectures designed to predict coupled-cluster singles and doubles (CCSD) amplitudes and correlation energies from…

Chemical Physics · Physics 2026-02-03 P. D. Varuna S. Pathirage , Konstantinos D. Vogiatzis

In this paper, we scrutinize the ability of seniority-zero wavefunction-based methods to model different types of non-covalent interactions, such as hydrogen bonds, dispersion, and mixed non-covalent interactions as well as prototypical…

Chemical Physics · Physics 2020-02-18 Filip Brzęk , Katharina Boguslawski , Paweł Tecmer , Piotr S. Żuchowski

The size-dependent structures and optical properties of CdSeS nanoclusters in water medium are investigated. The stability of different size-dependent Cd$_n$Se$_m$S$_p$ nanoclusters (up to n=6) is studied using density functional…

Materials Science · Physics 2020-11-10 Meenakshi Rana , Papia Chowdhury

A versatile method for combining density functional theory (DFT) in the local density approximation (LDA) with dynamical mean-field theory (DMFT) is presented. Starting from a general basis-independent formulation, we use Wannier functions…

Strongly Correlated Electrons · Physics 2009-11-11 F. Lechermann , A. Georges , A. Poteryaev , S. Biermann , M. Posternak , A. Yamasaki , O. K. Andersen

The density profile and the clustering of dark matter (DM) halos are two very important ingredients for understanding many observations of galaxies. In this talk, I present our new results for these two quantities from a large set of high…

Astrophysics · Physics 2007-05-23 Y. P. Jing

Electronic correlations in the Fe-pnictide BaFe2As2 are explored within LDA+DMFT, the combination of density functional theory with dynamical mean-field theory. While the correlated band structure is substantially renormalized there is only…

Accurate treatment of the electronic correlation in inhomogeneous electronic systems, combined with the ability to capture the correlation energy of the homogeneous electron gas, allows to reach high predictive power in the application of…

Strongly Correlated Electrons · Physics 2010-06-22 E. Rasanen , S. Pittalis , C. R. Proetto

The diffusion of electronic wave packets in one-dimensional systems with on-site, binary disorder is numerically investigated within the framework of a single-band tight-binding model. Fractal properties are incorporated by assuming that…

Disordered Systems and Neural Networks · Physics 2008-07-07 P. R. Wells , J. d'Albuquerque e Castro , S. L. A. de Queiroz

Correlations, highly important in low--dimensional systems, are known to decrease the plasmon dispersion of two-dimensional electron liquids. Here we calculate the plasmon properties, applying the 'Dynamic Many-Body Theory', accounting for…

Mesoscale and Nanoscale Physics · Physics 2017-12-06 Jürgen T. Drachta , Dominik Kreil , Raphael Hobbiger , Helga M. Böhm