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While structure refinement is routinely achieved for simple bulk materials, the accurate structural determination still poses challenges for thin films due on the one hand to the small amount of material deposited on the thicker substrate…

Designing and understanding functional electronic and magnetic properties in perovskite oxides requires controlling and tuning the underlying crystal lattice. Here we report the structure, including oxygen and cation positions, of a…

Rare earth perovskite oxides constitute a wide family of materials presenting functional proper- ties strongly coupled to their crystalline structure. Here, we report on the experimental results on epitaxial PrVO3 deposited on SrTiO3 single…

Lattice structure can dictate electronic and magnetic properties of a material. Especially, reconstruction at a surface or heterointerface can create properties that are fundamentally different from those of the corresponding bulk material.…

Materials Science · Physics 2021-06-21 Prahald Siwakoti , Zhen Wang , Mohammad Saghayezhian , David Howe , Zeeshan Ali , Yimei Zhu , Jiandi Zhang

The atomic configuration of phases and their interfaces is fundamental to materials design and engineering. Here, we unveil a transition metal oxide interface, whose formation is driven by energetic influences - epitaxial tensile strain…

Determining the 3-dimensional crystallography of a material with sub-nanometre resolution is essential to understanding strain effects in epitaxial thin films. A new scanning transmission electron microscopy imaging technique is…

The electronic and magnetic properties in ABO3 perovskite oxides are extremely sensitive to lattice structure but also the dimensionality, such as the thickness in thin film form. Here, we report the thickness-dependent electro-magnetic…

Materials Science · Physics 2022-12-26 Zeeshan Ali , Mohammad Saghayezhian , Prahald Siwakoti , Roshan Nepal , Jiandi Zhang

The first examples of single crystal epitaxial thin films of a high entropy perovskite oxide are synthesized. Pulsed laser deposition is used to grow the configurationally disordered ABO3 perovskite, Ba(Zr0.2Sn0.2Ti0.2Hf0.2Nb0.2)O3,…

Transition metal perovskite oxides display a variety of emergent phenomena which are tunable by tailoring the oxygen octahedral rotation. SrRuO$_3$, a ferromagnetic perovskite oxide, is well-known to have various atomic structures and…

Materials Science · Physics 2022-11-01 Byungmin Sohn , Changyoung Kim

Hexagonal perovskites are an attractive group of materials due to their various polymorph phases and rich structure-property relationships. BaRuO3 (BRO) is a prototypical hexagonal perovskite, in which the electromagnetic properties are…

Materials Science · Physics 2021-07-16 Sangmoon Yoon , Jong Mok Ok , Sang A Lee , Jegon Lee , Andrew R. Lupini , Woo Seok Choi , Ho Nyung Lee

Epitaxial strain is a proven route to enhancing the properties of complex oxides, however, the details of how the atomic structure accommodates strain are poorly understood due to the difficulty of measuring the oxygen positions in thin…

Materials Science · Physics 2015-05-18 S. J. May , J. -W. Kim , J. M. Rondinelli , E. Karapetrova , N. A. Spaldin , A. Bhattacharya , P. J. Ryan

Transition-metal oxides with an ABO$_3$ perovskite structure exhibit significant coupling between spin, orbital, and lattice degrees of freedom, highlighting the crucial role of lattice distortion in tuning the electronic and magnetic…

Materials Science · Physics 2025-02-26 M. Martirosyan , A. Gudima , J. Varignon , J. Ghanbaja , S. Migot , A. David , M. Guennou , O. Copie

Local configurational disorder can have a dominating role in the formation of macroscopic functional responses in strongly correlated materials. Here, we use entropy-stabilization synthesis to create single crystal epitaxial ABO3 perovskite…

The rich phase diagram of bulk Pr$_{1-x}$Ca$_{x}$MnO$_3$ resulting in a high tunability of physical properties gave rise to various studies related to fundamental research as well as prospective applications of the material. Importantly, as…

Layered perovskite La2CuO4+delta(LCO) thin films were epitaxially grown on SrTiO3 (STO) and LaSrAlO4 (LSAO) substrates by atomic-layer-by-layer molecular beam epitaxy. The lattice de-fects and residual strain in these films were…

Materials Science · Physics 2007-05-23 Jiaqing He , Robert F. Klie , Gennady Logvenov , Ivan Bozovic , Yimei Zhu

Understanding and controlling the growth of chalcogenide perovskite thin films through interface design is important for tailoring film properties. Here, the film and interface structure of BaZr(S,Se)$_3$ thin films grown on LaAlO$_3$ by…

Materials Science · Physics 2024-08-01 Michael Xu , Kevin Ye , Ida Sadeghi , Rafael Jaramillo , James M. LeBeau

A structural transition in an ABO$_{3}$ perovskite thin film involving the change of the BO$_{6}$ octahedral rotation pattern can be hidden under the global lattice symmetry imposed by the substrate and often easily overlooked. We carried…

Strongly Correlated Electrons · Physics 2019-11-04 W. T. Jin , H. Gretarsson , S. Y. Jang , Chang-Yong Kim , T. W. Noh , Young-june Kim

Controlling material properties by modulating the crystalline structure has been attempted using various techniques, e.g., hydrostatic pressure, chemical pressure, and epitaxy. These techniques succeed to improve properties and achieve…

Perovskite oxides hetero-structures are host to a large number of interesting phenomena such as ferroelectricity and 2D-superconductivity. Ferroelectric perovskite oxides have been of significant interest due to their possible use in…

Oxide electronics relies on the availability of epitaxial oxide thin films. The extreme flexibility of the chemical composition of ABO3 perovskites and the broad spectrum of properties they cover, inspire the creativity of scientists and…

Materials Science · Physics 2014-04-01 Florencio Sanchez , Carmen Ocal , Josep Fontcuberta
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