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We employed a machine-learning assisted approach to search for superconducting hydrides under ambient pressure within an extensive dataset comprising over 150 000 compounds. Our investigation yielded around 50 systems with transition…

Superconductivity · Physics 2024-03-21 Tiago F. T. Cerqueira , Yue-Wen Fang , Ion Errea , Antonio Sanna , Miguel A. L. Marques

The kagome lattice has emerged as a fertile ground for exotic quantum phenomena, including superconductivity, charge density waves, and topologically nontrivial states. While AV3Sb5 (A = K, Rb, Cs) compounds have been extensively studied in…

Materials Science · Physics 2026-05-22 Thalis H. B. da Silva , Tiago F. T. Cerqueira , Hai-Chen Wang , Miguel A. L. Marques

The discoveries of high-temperature superconductivity in H3S and LaH10 have excited the search for superconductivity in compressed hydrides. In contrast to rapidly expanding theoretical studies, high-pressure experiments on hydride…

Superconductivity · Physics 2021-09-15 Wuhao Chen , Dmitrii V. Semenok , Xiaoli Huang , Haiyun Shu , Xin Li , Defang Duan , Tian Cui , Artem R. Oganov

The spontaneous genesis of hydrocarbons which comprise natural petroleum have been analyzed by chemical thermodynamic stability theory. The constraints imposed upon chemical evolution by the second law of thermodynamics are briefly…

Chemical Physics · Physics 2009-11-11 J. F. Kenney , Vladimir G. Kutcherov , Nikolai A. Bendeliani , Vladimir A. Alekseev

Evolutionary structure searches revealed a plethora of stable and low-enthalpy metastable phases in the S-P-H ternary phase diagram under pressure. A wide variety of crystalline structure types were uncovered ranging from those possessing…

Superconductivity · Physics 2022-05-04 Nisha Geng , Tiange Bi , Eva Zurek

The alkali-doped fulleride Cs$_{3}$C$_{60}$, crystallized in the space group Fm$\overline 3$m or Pm$\overline 3$n, exhibits unconventional $s$-wave superconductivity under pressure with a maximum $T_c\sim 38$ K. Recently, a new…

Superconductivity · Physics 2024-03-08 Changming Yue , Yusuke Nomura , Kosmas Prassides , Philipp Werner

Novel superhard materials, especially those with superior thermal and chemical stability, are needed to replace diamond. Carbon nitrides (C-N), which are likely to possess these charac- teristics and have even been expected to be harder…

Materials Science · Physics 2015-06-29 Huafeng Dong , Artem R. Oganov , Qiang Zhu , Guang-Rui Qian

The lithium-carbon binary system possesses a broad range of chemical compounds, which exhibit fascinating chemical bonding characteristics that give rise diverse and technologically important properties. While lithium carbides with various…

Materials Science · Physics 2016-07-13 Yangzheng Lin , Timothy A. Strobel , R. E. Cohen

Through advanced experimental techniques on CrI$_{3}$ single crystals, we derive a previously not discussed pressure-temperature phase diagram. We find that $T_{c}$ increases to $\sim$ 66\,K with pressure up to $\sim$ 3\,GPa followed by a…

The discovery of superconductivity under high pressure with $T_c$ exceeding 80 K in a bilayer nickelate La$_3$Ni$_2$O$_7$ has led to a strong desire to realize similar high $T_c$ phenomena at ambient pressure. As one possible path toward…

Superconductivity · Physics 2025-02-20 Masayuki Ochi , Hirofumi Sakakibara , Hidetomo Usui , Kazuhiko Kuroki

Based on the unbiased structure prediction, we showed that the stable form of NiSi compound under the pressure of 100 and 200 GPa is the Pmmn-structure. Furthermore, we discovered a new stable phase - the deformed tetragonal CsCl-type…

Materials Science · Physics 2015-04-24 Pavel N. Gavryushkin , Zakhar I. Popov , Konstantin D. Litasov , Alex N. Gavryushkin

We report a theoretical study of Sb2S3, Sb2Se3 and Bi2S3 sesquichalcogenides at hydrostatic pressures up to 60 GPa. We explore the possibility that the R-3m, C2/m, C2/c and Im-3m phases observed in sesquichalcogenides with heavier cations,…

A new type of compositionally complex (medium- or high-entropy) M5Si3 silicides is synthesized. Both (V1/5Cr1/5Nb1/5Ta1/5W1/5)5Si3 and (Ti1/5Zr1/5Nb1/5Mo1/5Hf1/5)5Si3 form single-phase homogenous solid solutions. Notably,…

Materials Science · Physics 2021-12-16 Sashank Shivakumar , Mingde Qin , Dawei Zhang , Chongze Hu , Qizhang Yan , Jian Luo

Solid CS$_{2}$ is superficially similar to CO$_{2}$, with the same $Cmca$ molecular crystal structure at low pressures, which has suggested similar phases also at high pressures. We carried out an extensive first principles evolutionary…

Materials Science · Physics 2015-06-23 S. Shahab Naghavi , Yanier Crespo , Roman Martonak , Erio Tosatti

The kagome metals $A$V$_3$Sb$_5$ ($A=$ K, Rb, Cs) under ambient pressure exhibit an unusual charge order, from which superconductivity emerges. In this work, by applying hydrostatic pressure using a liquid pressure medium and carrying out…

Superconductivity · Physics 2022-06-22 Feng Du , Shuaishuai Luo , Rui Li , Brenden R. Ortiz , Ye Chen , Stephen D. Wilson , Yu Song , Huiqiu Yuan

Silicon carbide is a hard, semiconducting material presenting many polytypes, whose behavior under extreme conditions of pressure and temperature has attracted large interest. Here we study the mechanical properties of 3C-SiC over a wide…

Materials Science · Physics 2023-07-20 Carlos P. Herrero , Rafael Ramirez , Gabriela Herrero-Saboya

Understanding the high-pressure behavior of C-H system is of great importance due to its key role in organic, bio-, petroleum and planetary chemistry. We have performed a systematic investigation of the pressure-composition phase diagram of…

Materials Science · Physics 2020-01-07 Anastasia S. Naumova , Sergey V. Lepeshkin , Artem R. Oganov

Superatomic crystal is a class of hierarchical materials composed of atomically precise clusters assembled via van der Waals or covalent-like interactions. AuTe$_2$Se$_{4/3}$, an all-inorganic superatomic superconductor exhibiting…

Magnetic structures of metastable perovskites ScCrO3, InCrO3 and TlCrO3, stabilized under high-pressure and high-temperature conditions, have been studied by neutron powder diffraction. Similar to the other orthochromites LnCrO3…

Strongly Correlated Electrons · Physics 2021-01-13 Lei Ding , Pascal Manuel , Dmitry D. Khalyavin , Fabio Orlandi , Yu Kumagai , Fumiyasu Oba , Wei Yi , Alexei A. Belik

The pursuit of room-temperature superconductors has recently advanced with the discovery of high-temperature superconductivity in compressed hydrides, although sustaining the superconductivity of hydrides at ambient pressure remains…

Superconductivity · Physics 2025-01-28 Ying Sun , Li Zhu