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We develop a multi-threaded parallel coordinate descent full configuration interaction algorithm (mCDFCI), for the electronic structure ground-state calculation in the configuration interaction framework. The FCI problem is reformulated as…

Chemical Physics · Physics 2025-01-27 Yuejia Zhang , Weiguo Gao , Yingzhou Li

In this work, we develop a mathematical framework for a Selected Configuration Interaction (SCI) algorithm within a bi-orthogonal basis for transcorrelated (TC) calculations. The bi-orthogonal basis used here serves as the equivalent of the…

Chemical Physics · Physics 2023-06-22 Abdallah Ammar , Anthony Scemama , Emmanuel Giner

The development of polynomial cost solvers for correlated quantum impurity models, with controllable errors, is a central challenge in quantum many-body physics, where these models find applications ranging from nano-science to the…

Strongly Correlated Electrons · Physics 2012-12-21 Dominika Zgid , Emanuel Gull , Garnet Chan

The nuclear-electronic orbital (NEO) approach incorporates nuclear quantum effects into quantum chemistry calculations by treating specified nuclei quantum mechanically, equivalently to the electrons. Within the NEO framework, excited…

Chemical Physics · Physics 2025-03-19 Christopher L. Malbon , Sharon Hammes-Schiffer

Ab initio calculations face the challenge of describing a complex multiscale quantum many-body system. The nuclear wave function has both strong short-range correlations and long-range contributions. Natural orbitals provide a means of…

Nuclear Theory · Physics 2017-04-11 Chrysovalantis Constantinou

This paper presents a novel implicit scheme for the constraint resolution in real-time finite element simulations in the presence of contact and friction. Instead of using the standard motion correction scheme, we propose an iterative…

Distributed, Parallel, and Cluster Computing · Computer Science 2023-06-13 Ziqiu Zeng , Hadrien Courtecuisse

Despite the success of density functional approximations (DFAs) in describing the electronic properties of many-electron systems, the most widely used approximations suffer from self-interaction errors (SIE) that limit their predictive…

Chemical Physics · Physics 2020-01-08 Yoh Yamamoto , Carlos M. Diaz , Luis Basurto , Koblar A. Jackson , Tunna Baruah , Rajendra R. Zope

Physical human-robot interaction (pHRI) integrates the benefits of human operator and a collaborative robot in tasks involving physical interaction, with the aim of increasing the task performance. However, the design of interaction…

Robotics · Computer Science 2020-08-13 Yusuf Aydin , Ozan Tokatli , Volkan Patoglu , Cagatay Basdogan

By leveraging the waveform superposition property of the multiple access channel, over-the-air computation (AirComp) enables the execution of digital computations through analog means in the wireless domain, leading to faster processing and…

Information Theory · Computer Science 2025-08-22 Meng Hua , Chenghong Bian , Haotian Wu , Deniz Gündüz

We introduce the pCI software package for high-precision atomic structure calculations. The standard method of calculation is based on the configuration interaction (CI) method to describe valence correlations, but can be extended to attain…

We identify the dominant computational cost within the recently introduced stochastic and internally contracted FCIQMC-NEVPT2 method for large active space sizes. This arises from the contribution to the four-body intermediates arising from…

Chemical Physics · Physics 2020-10-05 James J. Halson , Robert J. Anderson , George H. Booth

We present a fully variational locally scaled self-interaction corrected (SIC) energy functional using complex optimal orbitals. This represents an important milestone for fully variational SIC energy functionals, which have been shown to…

Following our recent work on the benzene molecule [\href{https://doi.org/10.1063/5.0027617}{J.~Chem.~Phys.~\textbf{153}, 176101 (2020)}], itself motivated by the blind challenge of Eriksen \textit{et al.}…

Inverse optimal control (IOC) aims to estimate the underlying cost that governs the observed behavior of an expert system. However, in practical scenarios, the collected data is often corrupted by noise, which poses significant challenges…

Optimization and Control · Mathematics 2026-02-10 Ziliang Wang , Axel Ringh , Han Zhang

It has recently been shown that the SOiCI approach [J. Phys.: Condens. Matter 34 (2022) 224007], in conjunction with the spin-separated exact two-component relativistic Hamiltonian, can provide very accurate fine structures of systems…

Chemical Physics · Physics 2023-07-18 Yang Guo , Ning Zhang , Wenjian Liu

The semistochastic heat-bath configuration interaction (SHCI) method is a selected configuration interaction plus perturbation theory method that has provided near-full configuration interaction (FCI) levels of accuracy for many systems…

Chemical Physics · Physics 2021-11-30 Yuan Yao , Emmanuel Giner , Tyler A. Anderson , Julien Toulouse , C. J. Umrigar

Fermi-L\"owdin orbital self-interaction-correction (FLOSIC) method uses symmetric orthogonalized Fermi orbitals as localized orbitals in one-electron SIC schemes. In FLOSIC, a set of Fermi orbital descriptors (FOD) that define the FLOs is…

Chemical Physics · Physics 2025-08-08 Selim Romero , Yoh Yamamoto , Tunna Baruah , Rajendra R. Zope

We present a natural orbital-based implementation of the intermediate Hamiltonian Fock space coupled-cluster method for (1,1) sector of Fock space. The use of natural orbital significantly reduces the computational cost and can…

Chemical Physics · Physics 2021-09-07 Soumi Haldar , Achintya Kumar Dutta

High-precision atomic structure calculations require accurate modelling of electronic correlations typically addressed via the configuration interaction (CI) problem on a multiconfiguration wave function expansion. The latter can easily…

Atomic Physics · Physics 2023-06-22 Pavlo Bilous , Adriana Pálffy , Florian Marquardt

A zero-area four-blade perfect crystal neutron interferometer (NI) possess a decoherence-free subspace (DFS) for low-frequency mechanical vibrations and thus is easier to site. %has the potential to broaden the application of crystal-based…

Quantum Physics · Physics 2019-04-17 J. Nsofini , D. Sarenac , D. G. Cory , D. A. Pushin