Related papers: Bound on the Excess Charge of Generalized Thomas-F…
The purpose of this note is to give an elementary derivation of a lower bound on the relativistic Thomas-Fermi-Weizs\"acker-Dirac functional of Thomas-Fermi type and to apply it to get an upper bound on the excess charge of this model.
This paper establishes new bounds on the maximum number of electrons $ N_c(Z) $ that an atom with nuclear charge $Z$ can bind. Specifically, we show that \begin{equation*} N_c(Z) < 1.1185Z + O(Z^{1/3}) \end{equation*} with an explicit bound…
We prove that in Thomas-Fermi-Dirac-von Weizs\"acker theory, a nucleus of charge $Z>0$ can bind at most $Z+C$ electrons, where $C$ is a universal constant. This result is obtained through a comparison with Thomas-Fermi theory which, as a…
We consider an atom described by M\"uller theory, which is similar to Hartree-Fock theory, but with a modified exchange term. We prove that a nucleus of charge Z can bind at most Z+C electrons, where C is a universal constant. Our proof…
Recently, we have proposed the existence of a universal relation between the maximal electric charge and total mass of any weakly self-gravitating object: $Z\leq Z^*={\alpha}^{-1/3}A^{2/3}$, where $Z$ is the number of protons, $A$ is the…
The semi-classical approach leading to the Thomas-Fermi (TF) model provides a simple universal thermodynamic description of the electronic cloud surrounding the nucleus in an atom. This model is known to be exact at the limit of…
We prove an upper bound on the excess charge for non-relativistic atomic systems, independent of the particle statistics. This result improves Lieb's bound of 1984 for any $Z \ge 12$.
We prove that the maximum number $N_c$ of non-relativistic electrons that a nucleus of charge $Z$ can bind is less than $1.22Z+3Z^{1/3}$. This improves Lieb's upper bound $N_c<2Z+1$ [{\it Phys. Rev. A} {\bf 29}, 3018-3028 (1984)] when $Z\ge…
In this manuscript, using a technique introduced by P.~T.~Nam in 2012 and the {\it Coulomb Uncertainty Principle}, we prove new bounds on the excess charge for non relativistic atomic systems, independent of the particle statistics. These…
We give the asymptotic behavior of the ground state energy of Engel's and Dreizler's relativistic Thomas-Fermi-Weizs\"acker-Dirac functional for heavy atoms for fixed ratio of the atomic number and the velocity of light. Using a variation…
We will give a proof that the maximal excess charge for an atom described by a family of density-matrix-functionals, which includes Hartree-Fock and M\"uller theories, is bounded by an universal constant. We will use the new technique…
For a wide class of noninteracting tight-binding models in one dimension we present an analytical solution for all scattering and edge states on a half-infinite system. Without assuming any symmetry constraints we consider models with…
We analyze the convergence of the electron density and relative energy with respect to a perfect crystal of a class of volume defects that are compactly contained along one direction while being of infinite extent along the other two using…
We show that higher-order vacuum polarization would contribute a measureable net charge to atoms, if the charges of electrons and positrons do not balance precisely. We obtain the limit $|Q_e+Q_{\bar e}| < 10^{-18} e$ for the sum of the…
We prove quantitative upper bounds for the number of quadratic twists of a given elliptic curve $E/\Fp_q(C)$ over a function field over a finite field that have rank $\geq 2$, and for their average rank. The main tools are constructions and…
We prove an analytic bound on the excess charge for the Hartree equation in the atomic case.
In the absence of any symmetry constraints we address universal properties of the boundary charge $Q_B$ for a wide class of nearest-neighbor tight-binding models in one dimension with one orbital per site but generic modulations of on-site…
We show an atom of atomic number $Z$ described by the time-dependent Thomas-Fermi equation or the Vlasov equation cannot bind more than $4Z$ electrons.
By extrapolating the energies of non-relativistic atoms and their ions with up to 3000 electrons within Kohn-Sham density functional theory, we find that the ionization potential remains finite and increases across a row, even as…
The recently developed semiclassical variational Wigner-Kirkwood (VWK) approach is applied to finite nuclei using external potentials and self-consistent mean fields derived from Skyrme interactions and from relativistic mean field theory.…