Related papers: Bound on the Excess Charge of Generalized Thomas-F…
We prove that the ground state energy of an atom confined to two dimensions with an infinitely heavy nucleus of charge $Z>0$ and $N$ quantum electrons of charge -1 is $E(N,Z)=-{1/2}Z^2\ln Z+(E^{\TF}(\lambda)+{1/2}c^{\rm H})Z^2+o(Z^2)$ when…
The energy spectra of atomic ions are re-examined from the point of view of Thomas-Fermi scaling relations. For the first ionization potential, which sets the energy scale for the true discrete spectrum, Thomas-Fermi theory predicts the…
We show that for the straightforward quantized relativistic Coulomb Hamiltonian of a two-dimensional atom -- or the corresponding magnetic quantum dot -- the maximal number of electrons does not exceed twice the nuclear charge. It result is…
The atomic nucleus, viewed as a system of bound quarks, should, in principle, be described within an effective theory of low-energy quantum chromodynamics. This paper provides an overview of recently developed models that embody essential…
We consider a Thomas-Fermi mean-field model for large neutral atoms. That is, Schr\"odinger operators $H_Z^{\text{TF}}=-\Delta-\Phi_Z^{\text{TF}}$ in three-dimensional space, where $Z$ is the nuclear charge of the atom and…
A general approach to analyze the electrodynamics of nuclear matter in bulk is presented using the relativistic Thomas-Fermi equation generalizing to the case of $N \simeq (m_{\rm Planck}/m_n)^3$ nucleons of mass $m_n$ the approach well…
Due to $e^+e^-$-pair production in the field of supercritical $(Z \gg Z_{cr}\approx 170 $) nucleus an electron shell, created out of the vacuum, is formed. The distribution of the vacuum charge in this shell has been determined for…
Anions and radicals are important for many applications including environmental chemistry, semiconductors, and charge transfer, but are poorly described by the available approximate energy density functionals. Here we test an approximate…
Sequences of experimental ground-state energies are mapped onto concave patterns cured from convexities due to pairing and/or shell effects. The same patterns, completed by a list of excitation energies, can be used to give numerical…
Upper and lower bounds are derived for the ground-state energy of neutral atoms which for $Z\to\infty$ both involve the limits of exact Green's functions with one-body potentials. The limits of both bounds are shown to coincide with the…
Suggested non-linear, non-gauge modification of the Maxwell theory of electromagnetism based on correlation between electromagnetic potential, $A_a$, and metric, $g_{ab}$, such that tensor $G_{ab} = g_{ab} - l^2{A}_a{A}_b$ represents…
We give a necessary and sufficient condition for the existence of molecules in M\"uller theory. Furthermore, we show that if a system is stable in Born-Oppenheimer approximation, then the bound on the positive excess charge $ Z-N \le…
Let us consider some Coulomb systems of several infinitely massive centers of charge Z and one-two electrons: $(Z,e)$, $(2Z,e)$, $(3Z,e)$, $(4Z,e)$, $(2Z,e,e)$, $(3Z,e,e)$. It is shown that the physical, integer charges $Z=1,2,...$ do not…
Can collective quantum effects make a difference in a meaningful thermodynamic operation? Focusing on energy storage and batteries, we demonstrate that quantum mechanics can lead to an enhancement in the amount of work deposited per unit…
It was recently shown that charged AdS boson stars can reproduce the universal structure of the lowest scaling dimension in the subsector of a CFT with fixed large global $U(1)$ charge $Q$. Using the model consisting of Einstein-Maxwell…
The Lieb-Oxford bound is a constraint upon approximate exchange-correlation functionals. We explore a non-empirical tightening of that bound in both universal and electron-number-dependent form. The test functional is PBE. Regarding both…
Sequences of experimental ground-state energies for both odd and even $A$ are mapped onto concave patterns cured from convexities due to pairing and/or shell effects. The same patterns, completed by a list of excitation energies, give…
We review some results on the ionization conjecture, which says that a neutral atom can bind at most one or two extra electrons.
We prove within the Hartree-Fock theory of pseudo-relativistic atoms that the maximal negative ionization charge and the ionization energy of an atom remain bounded independently of the nuclear charge Z and the fine structure constant…
Based on the Thomas-Fermi approach, we describe and distinguish the electron distributions around extended nuclear cores: (i) in the case that cores are neutral for electrons bound by protons inside cores and proton and electron numbers are…