Related papers: Single-molecule phosphorescence and intersystem cr…
Singlet fission is a spin-allowed exciton multiplication process in organic semiconductors that converts one spin-singlet exciton to two triplet excitons. It offers the potential to enhance solar energy conversion by circumventing the…
The subwavelength confinement of surface plasmon polaritons (SPPs) makes them attractive for various applications such as sensing, light generation and solar energy conversion. Near-field microscopy associated with interferometric detection…
Hybrid systems of excitons strongly coupled to localized surface plasmons supported by metallic nanoparticles define a new approach to control light-matter interactions. Here, we report exciton-plasmon coupling in two-dimensional (2D)…
A variety of different graphene plasmonic structures and devices have been proposed and demonstrated experimentally. Plasmon modes in graphene microstructures interact strongly via the depolarization fields. An accurate quantitative…
We present optical absorption spectra of mixed films of pentacene (PEN) and perfluoropentacene (PFP) grown on SiO2. We investigated the influence of intermolecular coupling between PEN and PFP on the optical spectra by analyzing samples…
The strong coupling of a dense layer of molecular excitons with surface-plasmon modes in a metal gives rise to polaritons (hybrid light-matter states) called plexcitons. Surface plasmons cannot directly emit into (or be excited by)…
Tip-enhanced Raman spectroscopy (TERS) typically relies on high-NA excitation to generate a strong axial field at the tip apex, which shortens the working distance and constrains sample geometries. We show that a plasmonic bi-cavity tip,…
Transverse-electric (TE) surface plasmon polaritons are unique eigenmodes of a homogeneous graphene layer that are tunable with the chemical potential and temperature. However, as their dispersion curve spectrally lies just below the light…
The ongoing miniaturization in nanoscience and -technology challenges the sensitivity and selectivity of experimental analysis methods to the ultimate level of single atoms and molecules. A promising new approach, addressed here, focuses on…
Singlet fission, a process that splits a singlet exciton into a biexciton, has promise in quantum information. We report time-resolved electron paramagnetic resonance measurements on a molecule, TIPS-BP1$'$, designed to exhibit strongly…
Strong coupling of molecular vibrations with light creates polariton states, enabling control over many optical and chemical properties. However, the near-field signatures of strong coupling are difficult to map as most cavities are closed…
The electromagnetic response of subwavelength wires coated with a graphene monolayer illuminated by a linearly polarized plane waves is investigated. The results show that the scattering and extintion cross-sections of the coated wire can…
We reveal new aspects of the interaction between plasmons and phonons in 2D materials that go beyond a mere shift and increase in plasmon width due to coupling to either intrinsic vibrational modes of the material or phonons in a supporting…
Plasmonic cavities can be used to control the atom-photon coupling process at the nanoscale, since they provide ultrahigh density of optical states in an exceptionally small mode volume. Here we demonstrate strong coupling between molecular…
In this work, we present a novel technique to directly measure the phase shift of the optical signal scattered by single plasmonic nanoparticles in a diffraction-limited laser focus. We accomplish this by equipping an inverted confocal…
Electromagnetic (EM) coupling between molecular exciton and plasmon has been studied using in Rayleigh scattering or extinction spectroscopy. However, evaluating EM coupling involving subradiant plasmon is challenging because this resonance…
We analyze theoretically the single-photon excitation and transmission spectra of a strong-coupling hybrid optomechanics, where a two-level system (TLS) is coupled to the mechanical resonator (MR), generating the Jaynes-Cummings-type…
Biluminescent organic emitters show simultaneous fluorescence and phosphorescence at room temperature. So far, the optimization of the room temperature phosphorescence (RTP) in these materials has drawn the attention of research. However,…
Fluorescence Correlation Spectroscopy (FCS) is a powerful single-molecule technique which allows for measuring motion (diffusion, flow), concentration, and molecular interaction kinetics of fluorescent molecules from picomolar to micromolar…
Electronic Energy Transfer (EET) between chromophores is fundamental in many natural light-harvesting complexes, serving as a critical step for solar energy funneling in photosynthetic plants and bacteria. The complicated role of the…