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One of the most effective methods to enhance the strength of aluminum alloys involves modifying grain boundaries (GBs) through solute segregation. However, the fundamental mechanisms of solute segregation and their impacts on material…

Materials Science · Physics 2024-04-23 Keke Song , Jiahui Liu , Shunda Chen , Zheyong Fan , Yanjing Su , Ping Qian

In magnesium alloys with multiple substitutional elements, solute segregation at grain boundaries (GBs) has a strong impact on many important material characteristics, such as GB energy and mobility, and therefore, texture. Although it is…

Materials Science · Physics 2023-03-22 Risheng Pei , Zhuocheng Xie , Sangbong Yi , Sandra Korte-Kerzel , Julien Guénolé , Talal Al-Samman

The structure and energy of grain boundaries (GBs) are essential for predicting the properties of polycrystalline materials. In this work, we use high-throughput density functional theory calculations workflow to construct the Grain…

Solute segregation in alloys is a key phenomenon which affects various material characteristics such as embrittlement, grain growth and precipitation kinetics. In this work, the segregation energies of Y, Zr, and Nb to a \textgreek{S}5…

Materials Science · Physics 2025-03-06 Hariharan Umashankar , Daniel Scheiber , Vsevolod I. Razumovskiy , Matthias Militzer

Understanding the composition evolution of grain boundaries and grain boundary precipitation at near-atomic scale in aluminum alloys is crucial to tailor mechanical properties and to increase resistance to corrosion and stress corrosion…

This paper studies how solute segregation and its relationship to grain boundary energy in binary alloys is captured in the phase field crystal (PFC) formalism, a continuum method that incorporates atomic scale elasto-plastic effects on…

Materials Science · Physics 2013-04-10 Jonathan Stolle , Nikolas Provatas

Grain boundaries dramatically affect the properties of polycrystalline materials because of differences in atomic configuration. To fully understand the relationship between grain boundaries and materials properties, systematic studies of…

Materials Science · Physics 2021-01-19 Shin Kiyohara , Tomohiro Miyata , Teruyasu Mizoguchi

Grain boundaries (GBs) are planar lattice defects that govern the properties of many types of polycrystalline materials. Hence, their structures have been investigated in great detail. However, much less is known about their chemical…

Solute segregation at grain boundaries (GBs) of polycrystals strongly impacts the mechanical properties of metals including strength, fracture, embrittlement, and corrosion. However, the complexity of GB structures and the large chemical…

Materials Science · Physics 2024-12-24 Hao Wu , Xin Li , Wang Gao , Qing Jiang

The macroscopic behavior of polycrystalline materials is influenced by the local variation of properties caused by the presence of impurities and defects. The effect of these impurities at the atomic scale can either embrittle or strengthen…

Materials Science · Physics 2014-01-23 M. Rajagopalan , M. A. Tschopp , K. N. Solanki

Recent advances in the numerical representation of materials opened the way for successful machine learning of grain boundary (GB) energies and the classification of GB mobility and shear coupling. Two representations were needed for these…

Materials Science · Physics 2018-08-17 Conrad W. Rosenbrock , Jonathan L. Priedeman , Gus L. W. Hart , Eric R. Homer

Owing to the excellent catalysis properties of Ag-Au binary nanoalloy, nanostructured Ag-Au, such as Ag-Au nanoparticles and nanopillars, have been under intense investigation. To achieve high accuracy in molecular simulations of the Ag-Au…

Materials Science · Physics 2021-08-16 Yinan Wang , Xiaoyang Wang , Linfeng Zhang , Ben Xu , Han Wang

First-principles calculations were carried out to study the segregation behavior of Mg, and Cu and their effect on the energy and mechanical properties of different Al grain boundaries (GBs). Four symmetrical tilt GBs were selected for…

Materials Science · Physics 2023-05-29 Xuan Zhang , Liang Zhang , Zhihui Zhang , Xiaoxu Huang

Computing the grain boundary (GB) counterparts to bulk phase diagrams represents an emerging research direction. Using a classical embrittlement model system Ga-doped Al alloy, this study demonstrates the feasibility of computing…

Materials Science · Physics 2022-01-20 Chongze Hu , Yanwen Li , Zhiyang Yu , Jian Luo

Grain boundary engineering via dopant segregation can dramatically change the properties of a material. For metallic systems, most current studies concerning interfacial segregation and subsequent transitions of grain boundary structure are…

Materials Science · Physics 2018-12-26 Yang Hu , Timothy J. Rupert

Light elements play an important role in influencing the macroscale properties of engineering alloys through grain boundary (GB) segregation phenomena. However, the scarcity and scattered nature of ab initio datasets for light elements in…

Materials Science · Physics 2026-05-05 Han Lin Mai , Xiang-Yuan Cui , Tilmann Hickel , Simon P. Ringer , Jörg Neugebauer

Compositionally complex alloys or concentrated solid solutions are the latest frontier in catalyst design, but mixing different elements in one catalyst may result in surface segregation. Atomistic simulations can predict segregation…

Materials Science · Physics 2022-12-12 Alberto Ferrari , Vadim Sotskov , Alexander V. Shapeev , Fritz Körmann

Elements with low thermal neutron absorption cross-sections are ideal for enhancing structural materials in nuclear systems. In this study, We systematically investigate the segregation and co-segregation behaviors of eleven elements at the…

Materials Science · Physics 2025-11-26 Guanlin Lyu , Yuguo Sun , Panpan Gao , Ping Qian

Segregation of impurities to grain boundaries plays an important role in both the stability and macroscopic behavior of polycrystalline materials. The research objective in this work is to better characterize the energetics and length…

Materials Science · Physics 2013-09-02 N. R. Rhodes , M. A. Tschopp , K. N. Solanki

Grain boundary (GB) segregation models are derived for multi-principal element and high-entropy alloys (MPEAs and HEAs). Differing from classical models where one component is taken as solvent and others are considered solutes, these models…

Materials Science · Physics 2024-03-05 Jian Luo