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It has recently been proposed that Na4Ir3O8 is a weak Mott insulator at ambient pressure, supporting a three-dimensional spin liquid phase with a spinon Fermi surface. This proposal is consistent with recent experimental findings that the…

Strongly Correlated Electrons · Physics 2013-05-29 Daniel Podolsky , Yong Baek Kim

The electronic structure of Sr$_3$CuIrO$_6$, a model system for the 5d Ir ion in an octahedral environment, is studied through a combination of resonant inelastic x-ray scattering (RIXS) and theoretical calculations. RIXS spectra at the Ir…

SrIrO3, the three-dimensional member of the Ruddlesden-Popper iridates, is a paramagnetic semimetal characterised by a the delicate interplay between spin-orbit coupling and Coulomb repulsion. In this work, we study the anisotropic…

Transition metal oxides, in particular, 3d or 4d perovskites have provided diverse emergent physics that originates from the coupling of various degrees of freedom such as spin, lattice, charge, orbital, and also disorder. 5d perovskites…

Strongly Correlated Electrons · Physics 2016-04-19 Abhijit Biswas , Ki-Seok Kim , Yoon Hee Jeong

In the context of correlated insulators, where electron-electron interactions (U) drive the localization of charge carriers, the metal-insulator transition (MIT) is described as either bandwidth (BC) or filling (FC) controlled. Motivated by…

The complex iridium oxide Na3Ir3O8 with a B-site ordered spinel structure was synthesized in single crystalline form, where the chiral hyper-kagome lattice of Ir atoms, as observed in the spin-liquid candidate Na4Ir3O8, was identified. The…

Strongly Correlated Electrons · Physics 2013-11-15 T. Takayama , A. Matsumoto , J. Nuss , A. Yaresko , K. Ishii , M. Yoshida , J. Mizuki , H. Takagi

We study the structural evolution of Sr$_3$Ir$_2$O$_7$ as a function of pressure using x-ray diffraction. At a pressure of 54 GPa at room temperature, we observe a first-order structural phase transition, associated with a change from…

Hyperhoneycomb iridate $\beta$-Li$_2$IrO$_3$ is a three-dimensional analogue of two-dimensional honeycomb iridates, such as $\alpha$-Li$_2$IrO$_3$, which recently appeared as another playground for the physics of Kitaev-type spin liquid.…

Strongly Correlated Electrons · Physics 2019-03-27 T. Takayama , A. Krajewska , A. S. Gibbs , A. N. Yaresko , H. Ishii , H. Yamaoka , K. Ishii , N. Hiraoka , N. P. Funnell , C. L. Bull , H. Takagi

The orthorhombic perovskite SrIrO3 is a semimetal, an intriguing exception in iridates where the strong spin-orbit interaction coupled with electron correlations tends to impose a novel insulating state. We report results of our…

Strongly Correlated Electrons · Physics 2016-07-06 H. Zheng , J. Terzic , Feng Ye , X. G. Wan , D. Wang , Jinchen Wang , Xiaoping Wang , P. Schlottmann , S. J. Yuan , G. Cao

Given that energy scales associated with crystal field splitting, spin orbit coupling and coulomb correlations in iridates are comparable, hence leading to exotic properties, we investigate the physical properties of orthorhombic SrIrO3…

Materials Science · Physics 2015-07-23 Vijeta Singh , J. J. Pulikkotil

There has been a rapidly growing interest on the interplay between spin-orbit coupling (SOC) and Hubbard interaction U in correlated materials. A current consensus is that the stronger the SOC, the smaller is the critical interaction Uc…

Strongly Correlated Electrons · Physics 2013-05-30 M. Ahsan Zeb , Hae-Young Kee

The Ruddlesden-Popper (RP) series of iridates (Srn+1IrnO3n+1) have been the subject of much recent attention due to the anticipation of emergent physics arising from the cooperative action of spin-orbit (SO) driven band splitting and…

We investigate the electronic and magnetic structures and the character and direction of spin and orbital moments of the recently synthesized quadruple perovskite cobaltovanadate CaCo3V4O12 using a selection of methods from density…

Strongly Correlated Electrons · Physics 2014-11-19 H. B. Rhee , W. E. Pickett

Recent theoretical predictions of "unprecedented proximity" of the electronic ground state of iridium fluorides to the SU(2) symmetric $j_{\mathrm{eff}}=1/2$ limit, relevant for superconductivity in iridates, motivated us to investigate…

Strongly Correlated Electrons · Physics 2017-09-27 M. Rossi , M. Retegan , C. Giacobbe , R. Fumagalli , A. Efimenko , T. Kulka , K. Wohlfeld , A. I. Gubanov , M. Moretti Sala

Strong spin-orbit coupled 5d transition metal based ABO3 oxides, especially iridates, allow tuning parameters in the phase diagram and may demonstrate important functionalities, for example, by means of strain effects and symmetry-breaking,…

Strongly Correlated Electrons · Physics 2015-05-22 Abhijit Biswas , Yoon Hee Jeong

We report neutron scattering experiments which reveal a large spin gap in the magnetic excitation spectrum of weakly-monoclinic double perovskite Sr2ScOsO6. The spin gap is demonstrative of appreciable spin-orbit-induced anisotropy, despite…

Strongly Correlated Electrons · Physics 2016-07-06 A. E. Taylor , R. Morrow , R. S. Fishman , S. Calder , A. I. Kolesnikov , M. D. Lumsden , P. M. Woodward , A. D. Christianson

The electronic, magnetic and optical properties of the double perovskite Sr$_2$CoIrO$_6$ (SCIO) under biaxial strain are explored in the framework of density functional theory (DFT) including a Hubbard $U$ term and spin-orbit coupling (SOC)…

Strongly Correlated Electrons · Physics 2021-11-24 Jiongyao Wu , Marcel Ney , Sebastian Esser , Vijaya Begum , Günther Prinz , Axel Lorke , Philipp Gegenwart , Rossitza Pentcheva

Spin-orbit coupling (SOC) plays a crucial role in magnetic and electronic properties of 5$d$ iridates. In this paper we have experimentally investigated the structural and physical properties of a series of Ir-based double perovskite…

Strongly Correlated Electrons · Physics 2019-10-02 Abhisek Bandyopadhyay , I. Carlomagno , L. Simonelli , M. Moretti Sala , A. Efimenko , C. Meneghini , Sugata Ray

The effect of isoelectronic substitution within single crystals of (Sr1-xCax)2-yIrO4+z is explored. The nominal n=1 Ruddlesden-Popper phase with y=0, z=0 remains stable from x=0 until x=0.11, where the antiferromagnet spin-orbit Mott…

Materials Science · Physics 2016-11-23 Xiang Chen , Stephen D. Wilson

We performed resonant x-ray diffraction experiments at the $L$ absorption edges for the post-perovskite-type compound CaIrO$_{3}$ with $(t_{2g})^5$ electronic configuration. By observing the magnetic signals, we could clearly see that the…