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Transition metal oxides such as vanadium dioxide (VO$_2$), niobium dioxide (NbO$_2$), and titanium sesquioxide (Ti$_2$O$_3$) are known to undergo a temperature-dependent metal-insulator transition (MIT) in conjunction with a structural…

The insulator-to-metal transition (IMT) in strongly correlated materials, such as vanadium dioxide (VO2), offers a transformative platform for next-generation adaptive electronics and neuromorphic computing. However, harnessing this…

Materials Science · Physics 2026-04-22 Siyuan Huang , Shuaishuai Sun , Yin Shi , Wentao Wang , Chunhui Zhu , Huanfang Tian , Huaixin Yang , Jun Li , Jianqi Li

In order to study the origin of metallization of VO$_2$ induced by electron injection, we deposit K atoms onto the surface of VO$_2$ films grown on TiO$_2$ (001) substrates, and we investigate the change in the electronic and crystal…

Strongly Correlated Electrons · Physics 2019-03-27 Daisuke Shiga , Makoto Minohara , Miho Kitamura , Ryu Yukawa , Koji Horiba , Hiroshi Kumigashira

Neuromorphic functionalities in memristive devices are commonly associated with the ability to electrically create local conductive pathways by resistive switching. The archetypal correlated material, VO2, has been intensively studied for…

The insulator-to-metal transition (IMT) of the simple binary compound of vanadium dioxide VO$_2$ at $\sim 340$ K has been puzzling since its discovery more than five decades ago. A wide variety of photon and electron probes have been…

Strongly Correlated Electrons · Physics 2014-12-18 Brian T. O'Callahan , Joanna M. Atkin , Andrew C. Jones , Jae Hyung Park , David Cobden , Markus B. Raschke

The metal insulator transition of nano-scaled $VO_2$ devices is drastically different from the smooth transport curves generally reported. The temperature driven transition occurs through a series of resistance jumps ranging over 2 decades…

Mesoscale and Nanoscale Physics · Physics 2008-10-31 Amos Sharoni , Juan Gabriel Ramírez , Ivan K. Schuller

Controlling electronic population through chemical doping is one way to tip the balance between competing phases in materials with strong electronic correlations. Vanadium dioxide exhibits a first-order phase transition at around 338 K…

Vanadium dioxide is of broad interest as a spin-1/2 electron system that realizes a metal-insulator transition near room temperature, due to a combination of strongly correlated and itinerant electron physics. Here, resonant inelastic X-ray…

The electronic structure of VO$_2$ is studied in the frameworks of local density approximation (LDA) and LDA+$U$ to give a quantitative description of the metal-insulator (MI) transition in this system. It is found that, both structural…

Materials Science · Physics 2007-05-23 Xiangyang Huang , Weidong Yang , Ulrich Eckern

We discuss a metal-insulator transition caused by random couplings of magnetic moments in itinerant systems. An analytic solution for the single particle Green function is derived from dynamical self consistency equations, the corresponding…

Strongly Correlated Electrons · Physics 2007-05-23 B. Rosenow , R. Oppermann

The vanadates VO$_2$ and V$_2$O$_3$ are prototypical examples of strongly correlated materials that exhibit a metal-insulator transition. While the phase transitions in these materials have been studied extensively, there is a limited…

Materials Science · Physics 2019-06-12 Darshana Wickramaratne , Noam Bernstein , I. I. Mazin

Through ${in~situ}$ photoemission spectroscopy, we investigated the change in the electronic and crystal structures of dimensionality-controlled VO$_2$ films coherently grown on TiO$_2$(001) substrates. In the nanostructured films, the…

Strongly Correlated Electrons · Physics 2021-05-28 D. Shiga , B. E. Yang , N. Hasegawa , T. Kanda , R. Tokunaga , K. Yoshimatsu , R. Yukawa , M. Kitamura , K. Horiba , H. Kumigashira

Metal-insulator transitions (MIT),an intriguing correlated phenomenon induced by the subtle competition of the electrons' repulsive Coulomb interaction and kinetic energy, is of great potential use for electronic applications due to the…

Materials Science · Physics 2021-10-13 Kun Han , Hanyu Wang , Liang Wu , Yu Cao , Dong-Chen Qi , Changjian Li , Zhen Huang , Xiao Li , X. Renshaw Wang

Vanadium dioxide is a correlated electron system that features a metal-insulator phase transition (MIT) above room temperature and is of interest in high speed switching devices. Here, we integrate VO2 into two-terminal coplanar waveguides…

Materials Science · Physics 2013-06-04 Sieu D. Ha , You Zhou , Christopher J. Fisher , Shriram Ramanathan , Jacob P. Treadway

We directly trace the near- and mid-infrared transmission change of a VO$_2$ thin film during an ultrafast insulator-to-metal transition triggered by high-field multi-terahertz transients. Non-thermal switching into a metastable metallic…

Strongly Correlated Electrons · Physics 2015-06-11 B. Mayer , C. Schmidt , A. Grupp , J. Bühler , J. Oelmann , R. E. Marvel , R. F. Haglund , T. Oka , D. Brida , A. Leitenstorfer , A. Pashkin

We found direct experimental evidence for an orbital switching in the V 3d states across the metal-insulator transition in VO$_{2}$. We have used soft-x-ray absorption spectroscopy at the V $L_{2,3}$ edges as a sensitive local probe, and…

VO2 is well known for its dual phase transitions; electrical as well as structural, at a single temperature of 340K. The low temperature structural phases of VO2 are different from its high temperature counterpart by means of structural…

Materials Science · Physics 2021-09-16 Raktima Basu , G. Mangamma , Sandip Dhara

We investigated optical absorption coefficient spectra of an epitaxial VO2 film in wide photon energy (0.5 - 5.0 eV) and temperature (100 - 380 K) regions. In its insulating phase, we observed two d-d transition peaks around 1.3 eV and 2.7…

Strongly Correlated Electrons · Physics 2007-05-23 C. H. Koo , J. S. Lee , M. W. Kim , Y. J. Chang , T. W. Noh , J. H. Jung B. G. Chae , H. -T. Kim

Spatial phase inhomogeneity at the nano- to microscale is widely observed in strongly-correlated electron materials. The underlying mechanism and possibility of artificially controlling the phase inhomogeneity are still open questions of…

Strongly Correlated Electrons · Physics 2015-05-13 J. Cao , E. Ertekin , V. Srinivasan , W. Fan , S. Huang , H. Zheng , J. W. L. Yim , D. R. Khanal , D. F. Ogletree , J. C. Grossman , J. Wu

Synchrotron X-ray diffraction experiment shows that the metal-insulator transition occurring in a ferromagnetic state of a hollandite K$_2$Cr$_8$O$_{16}$ is accompanied by a structural distortion from the tetragonal $I4/m$ to monoclinic…

Strongly Correlated Electrons · Physics 2011-12-30 T. Toriyama , A. Nakao , Y. Yamaki , H. Nakao , Y. Murakami , K. Hasegawa , M. Isobe , Y. Ueda , A. V. Ushakov , D. I. Khomskii , S. V. Streltsov , T. Konishi , Y. Ohta