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Soft x-ray spectroscopy is used to investigate the strain dependence of the metal-insulator transition of VO2. Changes in the strength of the V 3d - O 2p hybridization are observed across the transition, and are linked to the structural…

Strongly Correlated Electrons · Physics 2012-02-13 J. Laverock , L. F. J. Piper , A. R. H. Preston , B. Chen , J. McNulty , K. E. Smith , S. Kittiwatanakul , J. W. Lu , S. A. Wolf , P. -A. Glans , J. -H. Guo

We determine the electronic structure and phase stability of paramagnetic V$_2$O$_3$ at the Mott-Hubbard metal-insulator phase transition, by employing a combination of an ab initio method for calculating band structures with dynamical…

Strongly Correlated Electrons · Physics 2015-06-11 I. Leonov , V. I. Anisimov , D. Vollhardt

Materials that undergo reversible metal-insulator transitions are obvious candidates for new generations of devices. For such potential to be realised, the underlying microscopic mechanisms of such transitions must be fully determined. In…

Vanadium dioxide (VO2) exhibits a hysteretic insulator-to-metal transition near room temperature, forming the foundation for various forms of resistive switching devices. Usually, these are realized in the form of two-terminal bridge-like…

Magnetic fluctuations in transition metal oxides are a subject of intensive research because of the key role they are expected to play in the transition from the Mott insulator to the unconventional metallic phase of these materials, and…

Strongly Correlated Electrons · Physics 2016-01-06 J. Gunasekera , L. Harriger , A. Dahal , T. Heitmann , G. Vignale , D. K. Singh

The metal insulator transition (MIT) in VO2 has been an important topic for recent years. It has been generally agreed that the mechanism of the MIT in bulk VO2 is considered to be a collaborative Mott-Peierls transition, however the effect…

Materials Science · Physics 2015-06-09 Salinporn Kittiwatanakul , Stuart A. Wolf , Jiwei Lu

Vanadium dioxide (VO2) undergoes a phase transition at a temperature of 340 K between an insulating monoclinic M1 phase and a conducting rutile phase. Accurate measurements of possible anisotropy of the electronic properties and phonon…

Strongly Correlated Electrons · Physics 2013-07-24 T. J. Huffman , Peng Xu , M. M. Qazilbash , E. J. Walter , H. Krakauer , Jiang Wei , D. H. Cobden , H. A. Bechtel , M. C. Martin , G. L. Carr , D. N. Basov

Results of first principles augmented spherical wave electronic structure calculations for niobium dioxide are presented. Both metallic rutile and insulating low-temperature NbO2, which crystallizes in a distorted rutile structure, are…

Strongly Correlated Electrons · Physics 2009-11-07 V. Eyert

VO$_2$ is a unique phase change material with strongly anisotropic electronic properties. Recently, samples have been prepared that present a co-existence of phases and thus form metal-insulator junctions of the same chemical compound.…

Materials Science · Physics 2018-03-14 Miller Eaton , Alessandra Catellani , Arrigo Calzolari

We present a coordinated study of the paramagnetic-to-antiferromagnetic, rhombohedral-to-monoclinic, and metal-to-insulator transitions in thin-film specimens of the classic Mott insulator V$_2$O$_3$ using low-energy muon spin relaxation,…

The metal-insulator transition (MIT) in correlated oxide systems opens up a new paradigm to trigger the abruption in multiple physical functionalities, enabling the possibility in unlocking exotic quantum states beyond conventional phase…

Strongly Correlated Electrons · Physics 2025-10-23 Xiaohui Yao , Jiahui Ji , Xuanchi Zhou

New calculations for vanadium dioxide, one of the most controversely discussed materials for decades, reveal that band theory as based on density functional theory is well capable of correctly describing the electronic and magnetic…

Strongly Correlated Electrons · Physics 2011-07-07 V. Eyert

Insulator-to-metal (MI) phase transition in vanadium dioxide (VO2) thin films with controlled lattice distortion was investigated by thermopower measurements. VO2 epitaxial films with different crystallographic orientations, grown on (0001)…

Strongly Correlated Electrons · Physics 2015-07-15 Takayoshi Katase , Kenji Endo , Hiromichi Ohta

The debate about whether the insulating phases of vanadium dioxide (VO2) can be described by band theory or must be described by a theory of strong electron correlations remains unresolved even after decades of research. Energy-band…

Materials Science · Physics 2017-03-15 Sheng Xu , Xiao Shen , Kent A. Hallman , Richard F. Haglund , Sokrates T. Pantelides

Electron transport through amorphous monatomic metallic structures generated earlier by molecular dynamics simulations is studied numerically. The interference of electronic trajectories backscattered by the structural disorder probes the…

Disordered Systems and Neural Networks · Physics 2009-10-31 V. I. Kozub , C. Oligschleger

The electronic structure of the vanadium dioxide VO_2 in the tetragonal R and two monocinic M_1 and M_2 structural modifications was calculated in frames of the local-density functional (LDA) approach and the LSDA + U formalism of…

Strongly Correlated Electrons · Physics 2007-05-23 M. A. Korotin , N. A. Skorikov , V. I. Anisimov

The conductance fluctuations of a metallic wire which is interrupted by a small tunnel junction has been explored experimentally. In this system, the bias voltage V, which drops almost completely inside the tunnel barrier, is used to probe…

Mesoscale and Nanoscale Physics · Physics 2009-10-30 Alexander van Oudenaarden , M. H. Devoret , E. H. Visscher , Yu. V. Nazarov , J. E. Mooij

We have investigated the charge dynamics of VO2 by optical reflectivity measurements. Optical conductivity clearly shows a metal-insulator transition. In the metallic phase, a broad Drude-like structure is observed. On the other hand, in…

Strongly Correlated Electrons · Physics 2009-11-11 K. Okazaki , S. Sugai , Y. Muraoka , Z. Hiroi

The recent experimental observation of a metal-insulator transition in two dimensions prompts a re-examination of the theory of disordered interacting systems. We argue that the existing theory permits the existence of a metallic phase and…

Condensed Matter · Physics 2009-10-31 C. Castellani , C. Di Castro , P. A. Lee

Using light to control transient phases in quantum materials is an emerging route to engineer new properties and functionality, with both thermal and non-thermal phases observed out of equilibrium. Transient phases are expected to be…