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The development of a quadratic unitary coupled-cluster singles and doubles (qUCCSD) based self-consistent polarization propagator method is reported. We present a simple strategy for truncating the commutator expansion of the UCC…

Chemical Physics · Physics 2024-06-19 Junzi Liu , Lan Cheng

We briefly summarize some recent theoretical developments in perturbative QCD, emphasizing new ideas which have led to widening the domain of applicability of perturbation theory. In particular, it is now possible to calculate efficiently…

High Energy Physics - Phenomenology · Physics 2009-10-30 Stefano Forte

Cluster dynamics and single-particle correlation are simultaneously treated for the description of the ground state of ${}^{12} \mathrm{C} $. The recent development of the antisymmetrized quasi cluster model (AQCM) makes it possible to…

Nuclear Theory · Physics 2021-04-06 Naoyuki Itagaki , Tomoya Naito

We consider first order perturbation theory for a non-minimally coupled inflaton field without assuming an adiabatic equation of state. In general perturbations in non-minimally coupled theory may be non-adiabatic. However under the…

High Energy Physics - Phenomenology · Physics 2013-01-10 Abhishek Basak , Jitesh R. Bhatt

Background: Cluster states in $^{13}$N are extremely difficult to measure due to the unavailability of $^{9}$B+$\alpha$ elastic scattering data. Purpose: Using $\beta$-delayed charged-particle spectroscopy of $^{13}$O, clustered states in…

An externally corrected coupled cluster (CC) method, where an adaptive configuration interaction (ACI) wave function provides the external cluster amplitudes, named ACI-CC, is presented. By exploiting the connection between configuration…

Chemical Physics · Physics 2023-09-27 Gustavo J. R. Aroeira , Madeline M. Davis , Justin M. Turney , Henry F. Schaefer

In this paper we extend the rank-reduced coupled-cluster formalism to the calculation of non-iterative energy corrections due to quadruple excitations. There are two major components of the proposed formalism. The first is an approximate…

Chemical Physics · Physics 2022-11-11 Michał Lesiuk

Theory of one-electron transition density matrices has been formulated within the time-independent coupled cluster method for the polarization propagator [R. Moszynski, P. S. \.Zuchowski, and B. Jeziorski, Coll. Czech. Chem. Commun. {\bf…

Chemical Physics · Physics 2014-09-25 Aleksandra M. Tucholska , Marcin Modrzejewski , Robert Moszynski

Coupled-cluster theory with single, double, and perturbative triple excitations (CCSD(T)) -- often considered the "gold standard" of main-group quantum chemistry -- is inapplicable to three-dimensional metals due to an infrared divergence,…

Materials Science · Physics 2023-03-21 Verena A. Neufeld , Timothy C. Berkelbach

The perturbative consistency of coherent states within interacting quantum field theory requires them to be altered beyond the simple non-squeezed form. Building on this point, we perform explicit construction of consistent squeezed…

High Energy Physics - Theory · Physics 2023-12-01 Lasha Berezhiani , Giordano Cintia , Michael Zantedeschi

The distinguishable cluster approximation applied to coupled cluster doubles equations greatly improves absolute and relative energies. We apply the same approximation to the triples equations and demonstrate that it can also improve…

Chemical Physics · Physics 2019-05-01 Daniel Kats , Andreas Köhn

The unitary coupled cluster (UCC) approximation is one of the more promising wave-function ans\"atze for electronic structure calculations on quantum computers via the variational quantum eigensolver algorithm. However, for large systems…

Quantum Physics · Physics 2021-09-30 Jia Chen , Hai-Ping Cheng , James K. Freericks

We investigate the basis-set convergence of electronic correlation energies calculated using coupled cluster theory and a recently proposed finite basis-set correction technique. The correction is applied to atomic and molecular systems and…

Chemical Physics · Physics 2019-10-03 Andreas Irmler , Andreas Grüneis

We study a systematic improvement of perturbation theory for gauge fields on the lattice [hep-lat/0606001]; the improvement entails resumming, to all orders in the coupling constant, a dominant subclass of tadpole diagrams. This method,…

High Energy Physics - Lattice · Physics 2008-11-26 Martha Constantinou , Haralambos Panagopoulos , Apostolos Skouroupathis

We introduce a simple definition of the weight of any given Slater determinant in the coupled-cluster state, namely as the expectation value of the projection operator onto that determinant. The definition can be applied to any…

Chemical Physics · Physics 2025-03-05 Håkon Emil Kristiansen , Håkon Kvernmoen , Simen Kvaal , Thomas Bondo Pedersen

We present excitation energies for molecular doublets from a spin-adapted formulation of coupled cluster singles and doubles theory. The entanglement coupled cluster approach represents an unconventional take on the notorious problem of…

Chemical Physics · Physics 2025-04-08 Sarai Dery Folkestad , Kristine Lauvstad Kruken , Henrik Koch

While providing a highly accurate framework for simulating laser-induced many-electron dynamics in atom and molecules, including linear and nonlinear steady-state and transient absorption spectra, time-dependent coupled-cluster theory does…

It is well known that quantum-mechanical perturbation theory often give rise to divergent series that require proper resummation. Here I discuss simple ways in which these divergences can be avoided in the first place. Using the elementary…

Quantum Physics · Physics 2022-12-19 Matteo Smerlak

A variant of coupled-cluster theory is described here, wherein the degrees of freedom are fluctuations of fragments between internally correlated states. The effects of intra-fragment correlation on the inter-fragment interaction are…

Chemical Physics · Physics 2019-05-24 Yuhong Liu , Anthony D. Dutoi

We extend the single-site coherent potential approximation (CPA) to include the effects of non-local disorder correlations (alloy short-range order) on the electronic structure of random alloy systems. This is achieved by mapping the…

Strongly Correlated Electrons · Physics 2009-11-10 M. S. Laad , L. Craco