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Long-range metastable molecules consisting of two cesium atoms in high Rydberg states have been observed in an ultracold gas. A sequential three-photon two-color photoassociation scheme was employed to form these molecules in states which…

Atomic Physics · Physics 2016-11-17 Heiner Saßmannshausen , Johannes Deiglmayr

Competing short- and long-range interactions represent distinguished ingredients for the formation of complex quantum many-body phases. Their study is hard to realize with conventional quantum simulators. In this regard, Rydberg atoms…

Quantum Gases · Physics 2024-02-06 Zeki Zeybek , Rick Mukherjee , Peter Schmelcher

In this work we report ab initio calculations for the $H_2^+$ molecule interacting with ultrashort intense laser pulses. We analyse several observables that can, in principle, be available experimentally, in order to get a deeper…

Atomic Physics · Physics 2017-05-25 R. E. F. Silva

Rydberg molecules, often exemplified by long-range "trilobite" molecules, are a subject of much recent interest at high principal quantum number $n$. States that use the same bonding mechanism can exist at much lower $n$ and less-extreme…

Atomic Physics · Physics 2017-05-01 R. A. Carollo , J. L. Carini , E. E. Eyler , P. L. Gould , W. C. Stwalley

A remarkable property of Rydberg atoms is the possibility to create molecules formed by one highly excited atom and another atom in the ground state. The first realisation of such a Rydberg molecule has opened an active field of physical…

Atomic Physics · Physics 2013-04-02 Andrej Junginger , Jörg Main , Günter Wunner

We observe the formation of long-range Cs$_2$ Rydberg molecules consisting of a Rydberg and a ground-state atom by photoassociation spectroscopy in an ultracold Cs gas near 6s$_{1/2}$($F$=3,4)$\rightarrow$np$_{3/2}$ resonances (n=26-34).…

Atomic Physics · Physics 2015-06-23 Heiner Saßmannshausen , Frédéric Merkt , Johannes Deiglmayr

We have experimentally demonstrated both heating and cooling of electrons in an ultracold neutral plasma (UNP) by embedding Rydberg atoms into the plasma soon after its creation. We have determined the relationship between the initial…

Atomic Physics · Physics 2018-10-31 E. V. Crockett , R. C. Newell , F. Robicheaux , D. A. Tate

We investigate triatomic molecules that consist of two ground state atoms and a highly excited Rydberg atom, bound at large internuclear distances of thousands of \AA ngstroms. In the molecular state the Rydberg electron is in a…

Atomic Physics · Physics 2019-02-27 Christian Fey , Frederic Hummel , Peter Schmelcher

Matter-wave interferometry has been performed with helium atoms in high Rydberg states. In the experiments the atoms were prepared in coherent superpositions of Rydberg states with different electric dipole moments. Upon the application of…

Atomic Physics · Physics 2019-07-18 J. E. Palmer , S. D. Hogan

We review Rydberg aggregates, assemblies of a few Rydberg atoms exhibiting energy transport through collective eigenstates, considering isolated atoms or assemblies embedded within clouds of cold ground-state atoms. We classify Rydberg…

Atomic Physics · Physics 2018-02-14 S. Wüster , J. -M. Rost

Rydberg atoms are used in a wide range of applications due to their peculiar properties like strong dipolar and van der Waals interactions. The choice of Rydberg state has a huge impact on the strength and angular dependence of the…

Atomic Physics · Physics 2025-11-04 Karen Wadenpfuhl , C. Stuart Adams

We present photo-excitation of ultra-long-range Rydberg molecules as a probe of spatial correlations in quantum gases. Rydberg molecules can be created with well-defined internuclear spacing, set by the radius of the outer lobe of the…

We present a new approach to investigating Rydberg molecules by demonstrating the formation and characterization of individual Rb$^{*}$Cs Rydberg molecules using optical tweezers. By employing single-atom detection of Rb and Cs, we observe…

The giant electro-optical response of Rydberg atoms manifests itself in the emergence of sidebands in the Rydberg excitation spectrum if the atom is exposed to a radio-frequency (RF) electric field. Here we report on the study of RF-dressed…

Determining the vibrational structure of a molecule is central to fundamental applications in several areas, from atmospheric science to catalysis, fuel combustion modeling, biochemical imaging, and astrochemistry. However, when significant…

Quantum Physics · Physics 2021-12-22 Nicolas P. D. Sawaya , Francesco Paesani , Daniel P. Tabor

Stability achieved by large angular momentum is ubiquitous in nature, with examples ranging from classical mechanics, over optics and chemistry, to nuclear physics. In atoms, angular momentum can protect excited electronic orbitals from…

We have calculated long-range molecular potentials of the $0_g^{+}$, $0_u^{-}$ and $1_u$ symmetries between highly-excited rubidium atoms. Strong $np+np$ potentials characterized by these symmetries are important in describing…

Atomic Physics · Physics 2009-11-13 J. Stanojevic , R. Côté , D. Tong , E. E. Eyler , P. L. Gould

Rydberg atoms provide a powerful platform for exploring strongly interacting quantum systems, both in free space and in structured electromagnetic environments, with growing applications in quantum technology. Accurately modeling their…

The theory is developed for one and two atom interactions when the atom has a Rydberg electron attached to a hyperfine split core state. This situation is relevant for some of the rare earth and alkaline earth atoms that have been proposed…

Atomic Physics · Physics 2018-02-21 F. Robicheaux , D. W. Booth , M. Saffman

Studying the complex quantum dynamics of interacting many-body systems is one of the most challenging areas in modern physics. Here, we use machine learning (ML) models to identify the symmetrized base states of interacting Rydberg atoms of…

Quantum Physics · Physics 2021-08-13 Daryl Ryan Chong , Minhyuk Kim , Jaewook Ahn , Heejeong Jeong
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