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A detailed theoretical framework for highly excited Rydberg molecules is developed based on the generalized local frame transformation. Our approach avoids the use of pseudopotentials and yields analytical expressions for the body-frame…

Atomic Physics · Physics 2020-09-16 P. Giannakeas , Matthew T. Eiles , F. Robicheaux , Jan-Michael Rost

Rydberg molecules, Rydberg-atom or Rydberg-molecule, are an essential ingredient of cold molecular sciences. However, due to the richness of Rydberg-neutral interactions, new kinds of Rydberg molecules and binding mechanisms are still to be…

Atomic Physics · Physics 2025-02-18 Mateo Londoño , Vanessa C. Olaya-Agudelo , Felipe Herrera , Jesús Pérez-Ríos

Radioactive molecules provide a powerful new platform in the search for new physics at energy scales complementary to high-energy particle colliders. By combining enhancements from nuclear properties with the sensitivity and control offered…

Atomic Physics · Physics 2026-05-14 A. Jadbabaie , S. Ebadi , R. F. Garcia Ruiz , N. R. Hutzler , A. M. Jayich , J. T. Singh

We unravel some peculiar properties of ultralong-range Rydberg molecules formed by an $s$-state $^{87}$Rb Rydberg atom and a corresponding ground-state atom whose electronic orbitals are spherically symmetric and therefore should not be…

Atomic Physics · Physics 2019-02-06 Frederic Hummel , Christian Fey , Peter Schmelcher

Ultralong-range Rydberg molecules provide an exciting testbed for molecular physics at exaggerated scales. In the so-called trilobite and butterfly Rydberg molecules, the Born-Oppenheimer approximation can fail due to strong non-adiabatic…

Atomic Physics · Physics 2023-02-23 Frederic Hummel , Peter Schmelcher , Matthew T. Eiles

We report on the formation of ultralong-range Rydberg D-state molecules via photoassociation in an ultracold cloud of rubidium atoms. By applying a magnetic offset field on the order of 10 G and high resolution spectroscopy, we are able to…

Optically trapped Rydberg atoms are a suitable platform to explore quantum many-body physics mediated by long-range atom--atom interactions that can be engineered through externally applied light fields. However, this approach is limited to…

For many-electron systems, the second-order reduced density matrix (2-RDM) provides sufficient information for characterizing their properties of interests in physics and chemistry, ranging from total energy, magnetism, quantum correlation…

Quantum Physics · Physics 2021-05-12 Yimin Li

We predict the existence of a class of ultracold giant molecules formed from trapped ultracold Rydberg atoms and polar molecules. The interaction which leads to the formation of such molecules is the anisotropic charge-dipole interaction…

Atomic Physics · Physics 2015-05-18 Seth T. Rittenhouse , H. R. Sadeghpour

Rydberg excitons, the solid-state counterparts of Rydberg atoms, have sparked considerable interest in harnessing their quantum application potentials, whereas a major challenge is realizing their spatial confinement and manipulation.…

Controlling strongly interacting many-body systems enables the creation of tailored quantum matter, with properties transcending those based solely on single particle physics. Atomic ensembles which are optically driven to a Rydberg state…

Atoms in highly excited Rydberg states exhibit remarkable properties and constitute a powerful tool for studying quantum phenomena in strongly interacting many-particle systems. We investigate alkali atoms that are held in a ring lattice…

Atomic Physics · Physics 2017-09-13 Beatriz Olmos , Igor Lesanovsky

We propose an experimentally realizable scheme to produce triatomic ultralong-range Rydberg molecules (TURM), formed in ultracold KRb traps. A near resonant coupling of the non-zero quantum defect Rydberg levels with the KRb molecule in N=0…

We introduce a computational method developed for study of long-range molecular Rydberg states of such systems that can be approximated by two electrons in a model potential of the atomic cores. Only diatomic molecules are considered. The…

Chemical Physics · Physics 2016-01-26 Michal Tarana , Roman Čurík

Since their first experimental observation, ultralong-range Rydberg molecules consisting of a highly excited Rydberg atom and a ground state atom have attracted the interest in the field of ultracold chemistry. Especially the intriguing…

Ensembles of atoms interacting via their Rydberg levels, known as "superatoms" for their ability to encode qubits and to emit single photons, attract increasing attention as building blocks for quantum network nodes. Assessing their…

Quantum Physics · Physics 2026-01-27 Valentin Magro , Sébastien Garcia , Alexei Ourjoumtsev

Spectroscopic measurements of the rotational distribution of $^{84}$Sr and $^{86}$Sr 5sns $^1S_0$ ultralong-range Rydberg molecular dimers created via photoassociation in a cold gas are reported. The dimers are produced by two-photon…

Atomic Physics · Physics 2024-06-14 C. Wang , Y. Lu , S. K. Kanungo , F. B. Dunning , T. C. Killian , S. Yoshida

Cold Rydberg atoms exposed to strong magnetic fields possess unique properties which open the pathway for an intriguing many-body dynamics taking place in Rydberg gases consisting of either matter or anti-matter systems. We review both the…

Atomic Physics · Physics 2015-05-14 T. Pohl , H. R. Sadeghpour , P. Schmelcher

Rydberg blockade of ultracold atoms is considered now as one of the most promising tools for the implementation of quantum computing, but its fidelity can be substantially compromised by detrimental excitation of the neighbouring atoms.…

Atomic Physics · Physics 2017-05-05 Yurii V. Dumin

Dense atom ensembles with Rydberg excitations display intriguing collective effects mediated by their strong, long-range dipole-dipole interactions. These collective effects, often modeled using Rydberg superatoms, have gained significant…

Quantum Physics · Physics 2024-08-26 Xiao-Qiang Shao , Shi-Lei Su , Lin Li , Rejish Nath , Jin-Hui Wu , Weibin Li