Related papers: Chemistry in a Cryogenic Buffer Gas Cell
Cooling is the main process leading to the condensation of gas in the dark matter potential wells and consequently to star and structure formation. In a metal-free environment, the main available coolants are H, He, H$_2$ and HD; once the…
Cooling molecules in the gas phase is important for precision spectroscopy, cold molecule physics, and physical chemistry. Measurements of conformational relaxation cross sections shed important light on potential energy surfaces and energy…
We propose a method for controlling a class of low temperature chemical reactions. Specifically, we show the hydrogen abstraction channel in the reaction of formaldehyde (H$_{2}$CO) and the hydroxyl radical (OH) can be controlled through…
A combination of experiments and extensive modelling, including a chemical kinetics analysis, was performed for a CO$_2$/H$_2$O plasma in a dielectric barrier discharge. This provides a better understanding of the mechanisms related to the…
The understanding of complex and/or large vacuum systems operating at cryogenic temperatures requires a specific knowledge of the vacuum science at such temperatures. At room temperature, molecules with a low binding energy to a surface are…
Joule heat generated by resistive elements of cryogenic micro- and nanodevices often originates boiling of the cooling cryogenic liquids (helium, nitrogen). The article proposes an experimental method to explore the dynamics of the…
A cryogenic buffer gas beam, an electrostatic hexapole lens, and 2D transverse Doppler laser cooling are combined to produce a bright beam of barium monofluoride ($^{138}$Ba$^{19}$F) molecules. Experimental results and trajectory…
We present a method which delivers a continuous, high-density beam of slow and internally cold polar molecules. In our source, warm molecules are first cooled by collisions with a cryogenic helium buffer gas. Cold molecules are then…
The surface processes on interstellar dust grains have an important role in the chemical evolution in molecular clouds. Hydrogenation reactions on ice surfaces have been extensively investigated and are known to proceed at low temperatures…
A bubble chamber has been developed to be used as an active target system for low energy nuclear astrophysics experiments. Adopting ideas from dark matter detection with superheated liquids, a detector system compatible with gamma-ray beams…
We present a cryogenic source of periodic streams of micrometer-sized hydrogen and argon droplets as ideal mass-limited target systems for fundamental intense laser-driven plasma applications. The highly compact design combined with a high…
The modelling of emission spectra of molecules seen in interstellar clouds requires the knowledge of collisional rate coefficients. Among the commonly observed species, N$_2$H$^+$ is of particular interest since it was shown to be a good…
Context: Hydrogenation reactions are expected to be among the most important surface reactions on interstellar ices. However, solid state astrochemical laboratory data on reactions of H-atoms with common interstellar ice constituents are…
Molecular beam experiments that use low-temperature bolometers as (energy-) detectors are well suited to the study of physisorption and recombination of hydrogen on low-temperature surfaces. Experiments where this technique is combined with…
Direct nuclear reactions with radioactive ion beams represent an extremely powerful tool to extend the study of fundamental nuclear properties far from stability. These measurements require pure and dense targets to cope with the low beam…
Radiative emission during cold collisions between trapped laser-cooled Rb atoms and alkaline-earth ions (Ca$^+$, Sr$^+$, Ba$^+$) and Yb$^+$, and between Li and Yb$^+$, are studied theoretically, using accurate effective-core-potential based…
A model of a multilayer device with non-trivial geometrical structure and nonlinear dependencies of thermodynamic material properties at cryogenic temperatures is suggested. A considered device, called cryogenic cell, is intended for use in…
Atomic oxygen in its first excited singlet state, O(1 D), is an important species in the photochemistry of several planetary atmospheres and has been predicted to be a potentially important reactive species on interstellar ices. Here, we…
Through density functional theory and molecular dynamics calculations, we have analysed various metal polyhydrides to understand whether hydrogen is present in its molecular or atomic form - tetrahydrides of Ba,Sr,Ra, Cs and La;…
Gas-grain and gas-phase reactions dominate the formation of molecules in the interstellar medium (ISM). Gas-grain reactions require a substrate (e.g. a dust or ice grain) on which the reaction is able to occur. The formation of molecular…