Related papers: Ab initio calculations of erbium crystal field spl…
Rare-earth ions doped in crystals with low nuclear-spin densities are highly promising candidates for quantum technology applications. In this study, we investigated the spectroscopic properties of the 7F0 - 5 D0 optical and the hyperfine…
The upconversion process for the $Er^{3+}$ ion, when irradiated with IR photons at 980 nm, strongly depends upon the presence of the sensitizer $Yb^{3+}$ ions. There are many studies analyzing the properties of the upconversion process for…
Due to the complex interactions between rare-earth elements and transition metals, as well as/or themselves, rare-earth transition-metal oxides are likely to exhibit highly intriguing and novel magnetic structures and dynamic behaviours.…
Calculated energy levels from recent \emph{ab initio} studies of the electronic structure of SrCl$_{2}$:Yb$^{2+}$ and CsCaBr$_{3}$:Yb$^{2+}$ are fitted with a semi-empirical "crystal-field" Hamiltonian, which acts within the model space…
We discuss the calculation of crystal field splittings using Wannier functions and show how the ligand field contributions can be separated from the bare Coulomb contribution to the crystal field by constructing sets of Wannier functions…
Erbium ions doped into crystals have unique properties for quantum information processing, because of their optical transition at 1.5 $\mu$m and of the large magnetic moment of their effective spin-1/2 electronic ground state. Most…
The ability to distribute quantum entanglement over long distances is a vital ingredient for quantum technologies. Single atoms and atom-like defects in solids are ideal quantum light sources and quantum memories to store entanglement.…
Single quantum emitters embedded in solid-state hosts are an ideal platform for realizing quantum information processors and quantum network nodes. Among the currently-investigated candidates, Er$^{3+}$ ions are particularly appealing due…
We calculate accurate potential energy curves for a ground-state He$^+$ ion interacting with a He atom in the lowest-energy metastable $^3\!S$ electronic state. We employ the full configuration interaction method, equivalent to exact…
Efficient storage of telecom-band quantum optical information represents a crucial milestone for establishing distributed quantum optical networks. Erbium ions in crystalline hosts provide a promising platform for telecom quantum memories;…
We assess the local symmetry and crystal environment of trivalent terbium ions embedded in an indium tin oxide (ITO) matrix with bixbyite structure. The \mbox{Tb$^{3+}$} ions tend to substitute \mbox{In$^{3+}$} ions in two different…
Low-temperature electronic properties of rare-earth intermetallics are substantially influenced by the symmetry and magnitude of the crystal electric field. The direct spectroscopic analysis of crystal field splitting can be challenging,…
Hexagonal LuFeO$_3$ films have been studied using x-ray absorption and optical spectroscopy. The crystal splittings of Fe$^{3+}$ are extracted as $E_{e'}-E_{e"}$=0.7 eV and $E_{a_1'}-E_{e'}$=0.9 eV and a 2.0 eV optical band gap is…
Cubic Y$_{2}$Ti$_{2}$O$_{7}$ single crystals doped with Er$^{3+}$ and Yb$^{3+}$ ions have been studied by the methods of electron spin resonance (ESR) and selective laser spectroscopy. ESR spectra exhibit signals from rare-earth ions that…
On the basis of the point charge model, we formulate the crystalline electronic field (CEF) Hamiltonian $H_{\rm CEF}$ in the rare-earth based quasicrystal (QC) and approximant crystal (AC) with ligand ions located at pseudo 5-fold…
We present a first-principles study of defect formation and electronic structure of erbium (Er)-doped yttria (Y$_2$O$_3$). This is an emerging material for spin-photon interfaces in quantum information science due to the narrow linewidth…
High resolution low-temperature absorption spectra of 0.2% Pr^3+ doped CsCdBr_3 were measured in the spectral region 2000--7000 cm-1. Positions and widths of the crystal field levels within the 3H5, 3H4, 3F2, and 3F3 multiplets of the Pr^3+…
High-resolution absorption and laser spectroscopy are used to determine electronic energy levels for Ho$^{3+}$ ions in K$_2$YF$_5$ microparticles. A total of 72 crystal-field energy levels, distributed among 8 multiplets, are assigned. This…
The band gap of alkali halides, alkaline-earth oxides, Al2O3 and SiO2 crystals has been calculated using the Perturbed-Ion model supplemented with some assumptions for the treatment of excited states. The gap is calculated in several ways:…
Solid-state emitters with atom-like optical and magnetic transitions are highly desirable for efficient and scalable quantum state engineering and information processing. Quantum dots, color centers and impurities embedded in inorganic…